Citation: Zhang Na, Hong Luying, Geng Aifang, Yan Jinghui, Yao Shuang, Zhang Zhiming. Extended structural materials constructed from sulfate-centered Preyssler-type polyoxometalate with excellent electrocatalytic property[J]. Chinese Chemical Letters, ;2018, 29(9): 1409-1412. doi: 10.1016/j.cclet.2017.12.003 shu

Extended structural materials constructed from sulfate-centered Preyssler-type polyoxometalate with excellent electrocatalytic property

Zhang Na ^a,b ,
Hong Luying ^a ,
Geng Aifang ^a,, ,
Yan Jinghui ^a ,
Yao Shuang ^a,b,, ,
Zhang Zhiming ^b

a.
College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China
b.
Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China

Corresponding author: Geng Aifang, gengaf0687@sina.com Yao Shuang, shuangyao@email.tjut.edu.cn
Received Date: 24 September 2017
Revised Date: 17 November 2017
Accepted Date: 4 December 2017
Available Online: 11 September 2017

Figures(5)

Sulfate-centered Preyssler-type polyoxometalate was used as the precursor to react with transition metal cations and organic ligand for constructing inorganic-organic hybrid materials {H[Ni₂(H₂O)₄(Htrz)₃]₂(KS₅W₃₀O₁₁₀)}·18H₂O (trz=1, 2, 4-triazole) (1), which was characterized by single crystal X-ray diffraction analysis, energy-dispersive X-ray (EDX), power X-ray diffraction (PXRD), IR spectra and thermogravimetric (TG) analyses. In 1, the cylindrical vacancy of the inorganic crown-type anion {S₅W₃₀O₁₁₀} captures a K⁺ ion resulting in the anion {KS₅W₃₀O₁₁₀}^9-, which was further connected by dimeric[Ni₂(H₂O)₄(Htrz)₃]₂ metal-organic units into an one-dimensional (1D) chain-like structure. These 1D chains are further packed to form a three-dimensional (3D) supramolecular structure via Hbonding interactions. Here, the sulfate-centered Preyssler-typepolyoxometalate was firstly used to coordinate with transition metal cations and introduced into the inorganic-organic hybrid materials. Electrocatalytic study indicates that compound 1 exhibits good electrocatalytic activity toward reduction of H₂O₂ and NO₂^-.
- Preyssler-type,
- Polyoxometalate,
- Transition metal,
- Supramolecular structure,
- Electrocatalytic activity
1. [1]
  H.J. Lv, Y.V. Geletii, C.C. Zhao, et al., Chem. Soc. Rev. 41(2012) 7572-7589. doi: 10.1039/c2cs35292c
2. [2]
  C.H. Zhan, J.M. Cameron, D. Gabb, et al., Nat. Commun. 8(2017) 14185. doi: 10.1038/ncomms14185
3. [3]
  S. Yao, H.L. Wu, Z.Q. Lei, J.H. Yan, E.B. Wang, Chin. Chem. Lett. 24(2013) 283-286. doi: 10.1016/j.cclet.2013.02.008
4. [4]
  J. Cai, X.Y. Zheng, J. Xie, et al., Inorg. Chem. 56(2017) 8439-8445. doi: 10.1021/acs.inorgchem.7b01104
5. [5]
  Y. Zhang, X.B. Han, Z.M. Zhang, Z.J. Liu, E.B. Wang, Chin. Chem. Lett. 24(2013) 581-584. doi: 10.1016/j.cclet.2013.04.034
6. [6]
  S.B. Li, L. Zhang, K.P. O'Halloranb, H.Y. Ma, H.J. Pang, Dalton Trans. 44(2015) 2062-2065. doi: 10.1039/C4DT03625E
7. [7]
  W.J. Luo, J. Hu, H.L. Diao, et al., Angew. Chem. Int. Ed. 56(2017) 4941-4944. doi: 10.1002/anie.201612232
8. [8]
  D.Y. Du, J.S. Qin, S.L. Li, Z.M. Su, Y.Q. Lan, Chem. Soc. Rev. 43(2014) 4615-4632. doi: 10.1039/C3CS60404G
9. [9]
  J. Yu, Y. Cui, C.D. Wu, et al., J. Am. Chem. Soc. 137(2015) 4026-4029. doi: 10.1021/ja512552g
10. [10]
  J. Berzelius, J. Pogg. Ann. 6(1826) 369-371.
11. [11]
  J.F. Keggin, Proc. R. Soc. London Ser. A 144(1934) 75-100. doi: 10.1098/rspa.1934.0035
12. [12]
  J.S. Anderson, Nature 140(1937) 850.
13. [13]
  B. Dawson, Acta Cryst. 6(1953) 113-126. doi: 10.1107/S0365110X53000466
14. [14]
  Z. Li, X.X. Li, T. Yang, Z.W. Cai, S.T. Zheng, Angew. Chem. Int. Ed. 56(2017) 2664-2669. doi: 10.1002/anie.201612046
15. [15]
  J. Dong, J.F. Hu, Y.N. Chi, et al., Angew. Chem. Int. Ed. 56(2017) 4473-4477. doi: 10.1002/anie.201700159
16. [16]
  S.T. Zheng, J. Zhang, J.M. Clemente-Juan, D.Q. Yuan, G.Y. Yang, Angew. Chem. Int. Ed. 48(2009) 7176-7179. doi: 10.1002/anie.v48:39
17. [17]
  J.C. Liu, J. Yu, Q. Han, et al., Dalton Trans. 45(2016) 16471-16484. doi: 10.1039/C6DT03148J
18. [18]
  Q.X. Han, B. Qi, W.M. Ren, et al., Nat. Commun. 6(2015) 10007. doi: 10.1038/ncomms10007
19. [19]
  Y.W. Liu, S.M. Liu, D.F. He, et al., J. Am. Chem. Soc. 137(2015) 12697-12703. doi: 10.1021/jacs.5b08273
20. [20]
  Z.M. Zhang, T. Zhang, C. Wang, et al., J. Am. Chem. Soc. 137(2015) 3197-3200. doi: 10.1021/jacs.5b00075
21. [21]
  C. Preyssler, Bull. Soc. Chim. Fr (1970) 30-36.
22. [22]
  M.H. Alizadeh, S.P. Harmalker, Y. Jeannin, J. Martin-Frère, M.T. Pope, J. Am. Chem. Soc. 107(1985) 2662-2669. doi: 10.1021/ja00295a019
23. [23]
  K.C. Kim, M.T. Pope, G.J. Gama, M.H. Dickman, J. Am. Chem. Soc. 121(1999) 11164-11170. doi: 10.1021/ja992105b
24. [24]
  J.A. Fernández, X. López, C. Bo, et al., J. Am. Chem. Soc. 129(2007) 12244-12253. doi: 10.1021/ja0737321
25. [25]
  I. Creaser, M.C. Heckel, R.J. Neitz, M.T. Pope, Inorg. Chem. 32(1993) 1573-1578. doi: 10.1021/ic00061a010
26. [26]
  C.W. Williams, M.R. Antonio, L. Soderholm, J. Alloys Compd. 303-304(2000) 509-513. doi: 10.1016/S0925-8388(00)00637-X
27. [27]
  M.H. Dickman, G.J. Gama, K.C. Kim, M.T. Pope, J. Cluster Sci. 7(1996) 567-583. doi: 10.1007/BF01165802
28. [28]
  M.R. Antonio, M.H. Chiang, Inorg. Chem. 47(2008) 8278-8285. doi: 10.1021/ic8008893
29. [29]
  L. Huang, L. Cheng, S.S. Wang, W.H. Fang, G.Y. Yang, Eur. J. Inorg. Chem. 2013(2013) 1639-1643.
30. [30]
  X.L. Wang, J. Li, A.X. Tian, et al., Inorg. Chem. Commun. 14(2011) 103-106. doi: 10.1016/j.inoche.2010.09.042
31. [31]
  Y. Lu, Y.G. Li, E.B. Wang, X.X. Xu, Y. Ma, Inorg. Chim. Acta 360(2007) 2063-2070. doi: 10.1016/j.ica.2006.10.045
32. [32]
  M.X. Liang, C.Z. Ruan, D. Sun, et al., Inorg. Chem. 53(2014) 897-902. doi: 10.1021/ic4022596
33. [33]
  Y.Q. Yu, K. Zhao, L.W. Wang, et al., Inorg. Chem. 53(2014) 11046-11050. doi: 10.1021/ic501567s
34. [34]
  T.P. Hu, Y.Q. Zhao, Z. Jaglicic, et al., Inorg. Chem. 54(2015) 7415-7423. doi: 10.1021/acs.inorgchem.5b00962
35. [35]
  A. Hayashi, H. Ota, X. Lopez, et al., Inorg. Chem. 55(2016) 11583-11592. doi: 10.1021/acs.inorgchem.6b02116
36. [36]
  Z.M. Zhang, S. Yao, Y.G. Li, et al., Chem. Eur. J. 18(2012) 9184-9188. doi: 10.1002/chem.v18.30
37. [37]
  G. M. Sheldrick, SHELXS 97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.
38. [38]
  G. M. Sheldrick, SHELXL 97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
39. [39]
  D.D. Zhang, Z.J. Liang, S.Q. Xie, et al., Inorg. Chem. 53(2014) 9917-9922. doi: 10.1021/ic501575x
40. [40]
  X.L. Wang, R. Zhang, X. Wang, et al., Dalton Trans. 46(2017) 1965-1974. doi: 10.1039/C6DT04185J
1. [1]
  Bowen Li , Ting Wang , Ming Xu , Yuqi Wang , Zhaoxing Li , Mei Liu , Wenjing Zhang , Ming Feng . Structuring MoO₃-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(2): 110467-. doi: 10.1016/j.cclet.2024.110467
2. [2]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
3. [3]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
6. [6]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
7. [7]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
8. [8]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
9. [9]
  Yuchen Wang , Zhenhao Xu , Kai Yan . Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules. Chinese Journal of Structural Chemistry, 2025, 44(1): 100418-100418. doi: 10.1016/j.cjsc.2024.100418
10. [10]
  Boqiang Wang , Yongzhuo Xu , Jiajia Wang , Muyang Yang , Guo-Jun Deng , Wen Shao . Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines. Chinese Chemical Letters, 2024, 35(9): 109502-. doi: 10.1016/j.cclet.2024.109502
11. [11]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
12. [12]
  Jian Song , Shenghui Wang , Qiuge Liu , Xiao Wang , Shuo Yuan , Hongmin Liu , Saiyang Zhang . N-Benzyl arylamide derivatives as novel and potent tubulin polymerization inhibitors against gastric cancers: Design, structure–activity relationships and biological evaluations. Chinese Chemical Letters, 2025, 36(2): 109678-. doi: 10.1016/j.cclet.2024.109678
13. [13]
  Zhu Shu , Xin Lei , Yeye Ai , Ke Shao , Jianliang Shen , Zhegang Huang , Yongguang Li . ATP-induced supramolecular assembly based on chromophoric organic molecules and metal complexes. Chinese Chemical Letters, 2024, 35(11): 109585-. doi: 10.1016/j.cclet.2024.109585
14. [14]
  Yaxin Sun , Huiyu Li , Shiquan Guo , Congju Li . Metal-based cathode catalysts for electrocatalytic ORR in microbial fuel cells: A review. Chinese Chemical Letters, 2024, 35(5): 109418-. doi: 10.1016/j.cclet.2023.109418
15. [15]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
16. [16]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
17. [17]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361
18. [18]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
19. [19]
  Changyuan Bao , Yunpeng Jiang , Haoyin Zhong , Huaizheng Ren , Junhui Wang , Binbin Liu , Qi Zhao , Fan Jin , Yan Meng Chong , Jianguo Sun , Fei Wang , Bo Wang , Ximeng Liu , Dianlong Wang , John Wang . Synergizing 3D-printed structure and sodiophilic interface enables highly efficient sodium metal anodes. Chinese Chemical Letters, 2024, 35(11): 109353-. doi: 10.1016/j.cclet.2023.109353
20. [20]
  Tao Zhou , Jing Zhou , Yunyun Liu , Jie-Ping Wan , Fen-Er Chen . Transition metal-free tunable synthesis of 3-(trifluoromethylthio) and 3-trifluoromethylsulfinyl chromones via domino C–H functionalization and chromone annulation of enaminones. Chinese Chemical Letters, 2024, 35(11): 109683-. doi: 10.1016/j.cclet.2024.109683

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1503)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142