Citation: Dai Yimin, Niu Lanli, Zou Jiaqi, Chen Tianxiao, Liu Hui, Zhou Yi. Preparation of core-shell magnetic Fe₃O₄@SiO₂-dithiocarbamate nanoparticle and its application for the Ni²⁺, Cu²⁺ removal[J]. Chinese Chemical Letters, ;2018, 29(6): 887-891. doi: 10.1016/j.cclet.2017.11.029 shu

Preparation of core-shell magnetic Fe₃O₄@SiO₂-dithiocarbamate nanoparticle and its application for the Ni²⁺, Cu²⁺ removal

School of Chemistry and Biological Engineering, Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China

Corresponding author: Dai Yimin, yimindai@csust.edu.cn
Received Date: 6 July 2017
Revised Date: 10 November 2017
Accepted Date: 21 November 2017
Available Online: 24 June 2017

Figures(6)

A novel magnetic nanoparticles-based dithiocarbamate absorbent (Fe₃O₄@SiO₂-DTC) with core-shell structure was synthesized under mild conditions and used in aqueous solution Ni²⁺ and Cu²⁺ ions treatment. The structure, morphology and magnetic properties of the adsorbent were characterized by Xray diffraction (XRD), fourier transformed infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). Fe₃O₄@SiO₂-DTC exhibited a typical superparamagnetic with a saturation magnetization value of 52.7 emu/g, which could be rapidly separated from aqueous solution under external magnetic field. We investigated the effects of solution pH, adsorption time, and the initial concentration of heavy metal ions on the adsorption of Ni²⁺ and Cu²⁺. The adsorption equilibrium times of Ni²⁺ and Cu²⁺ on Fe₃O₄@SiO₂-DTC were reached at 15 min and 90 min, respectively. The adsorption kinetic data were fitted to the pseudo-second-order model, and the adsorption data were consistent with the Frenudlich isotherm model. When the initial concentration of heavy metal ions was 250 mg/L, the maximum adsorption capacity of Ni²⁺ and Cu²⁺ at room temperature was 235.23 mg/g and 230.49 mg/g, respectively. In addition, we discussed the plausible adsorption mechanism. The results indicated that the adsorption was mainly dominated by chelation.
- Core-shell,
- Magnetic nanoparticle,
- Dithiocarbamate,
- Adsorption,
- Heavy metals removal
1. [1]
  L. Xu, J.N. Wang, Y. Meng, A.M. Li, Chin. Chem. Lett. 23(2012) 105-108. doi: 10.1016/j.cclet.2011.09.029
2. [2]
  P. Panneerselvam, N. Morad, K.A. Tan, J. Hazard. Mater. 186(2011) 160-168. doi: 10.1016/j.jhazmat.2010.10.102
3. [3]
  A.Z.M. Badruddoza, Z.B.Z. Shawon, W.J.D. Tay, K. Hidajat, M.S. Uddin, Carbohyd. Polym. 91(2013) 322-332. doi: 10.1016/j.carbpol.2012.08.030
4. [4]
  F. Ge, M.M. Li, H. Ye, B.X. Zhao, J. Hazard. Mater. 211(2012) 366-372.
5. [5]
  Y. Liu, M. Chen, H. Yongmei, J. Chem. Eng. 218(2013) 46-54. doi: 10.1016/j.cej.2012.12.027
6. [6]
  X. Zhang, Q. Huang, M. Liu, et al., Appl. Surf. Sci. 343(2015) 19-27. doi: 10.1016/j.apsusc.2015.03.081
7. [7]
  S.Y. Zhu, H.Y. Guo, F.F. Yang, Z.S. Wang, Chin. Chem. Lett. 26(2015) 1091-1095. doi: 10.1016/j.cclet.2015.03.031
8. [8]
  C.E. Barrera-Diaz, V. Lugo-Lugo, B. Bilyeu, J. Hazard. Mater. 223(2012) 1-12.
9. [9]
  M. Bhaumik, A. Maity, V.V. Srinivasu, M.S. Onyango, J. Hazard. Mater. 190(2011) 381-390. doi: 10.1016/j.jhazmat.2011.03.062
10. [10]
  H. Zhang, F. Huang, D.L. Liu, P. Shi, Chin. Chem. Lett. 26(2015) 1137-1143. doi: 10.1016/j.cclet.2015.05.026
11. [11]
  J. Zhu, S.A. Baig, T. Sheng, et al., J. Hazard. Mater. 286(2015) 220-228. doi: 10.1016/j.jhazmat.2015.01.004
12. [12]
  K. Zargoosh, H. Abedini, A. Abdolmaleki, M.R. Molavian, Ind. Eng. Chem. Res. 52(2013) 14944-14954. doi: 10.1021/ie401971w
13. [13]
  M. Hassan, E. Haque, K.R. Reddy, et al., Nanoscale 6(2014) 11988-11994. doi: 10.1039/C4NR02365J
14. [14]
  H. Karami, J. Chem. Eng. 219(2013) 209-216. doi: 10.1016/j.cej.2013.01.022
15. [15]
  T. Wang, L. Zhang, H. Wang, et al., ACS Appl. Mater. Interfaces 5(2013) 12449-12459. doi: 10.1021/am403533v
16. [16]
  T. Lü, S. Zhang, D. Qi, et al., Appl. Surf. Sci. 396(2017) 1604-1612. doi: 10.1016/j.apsusc.2016.11.223
17. [17]
  G. Yang, L. Tang, X. Lei, et al., Appl. Surf. Sci. 292(2014) 710-716. doi: 10.1016/j.apsusc.2013.12.038
18. [18]
  J.F. Liu, Z.S. Zhao, G.B. Jiang, Environ. Sci. Technol. 42(2008) 6949-6954. doi: 10.1021/es800924c
19. [19]
  K.R. Reddy, K.P. Lee, A.G. Iyengar, J. Appl. Polym. Sci. 104(2007) 4127-4134. doi: 10.1002/(ISSN)1097-4628
20. [20]
  K.R. Reddy, K.P. Lee, A.I. Gopalan, Colloid. Surface A 320(2008) 49-56. doi: 10.1016/j.colsurfa.2007.12.057
21. [21]
  C. Hui, C. Shen, J. Tian, et al., Nanoscale 3(2011) 701-705. doi: 10.1039/C0NR00497A
22. [22]
  H.L. Ding, Y.X. Zhang, S. Wang, et al., Chem. Mater. 24(2012) 4572-4580. doi: 10.1021/cm302828d
23. [23]
  J. Zou, Y.G. Peng, Y.Y. Tang, RSC Adv. 4(2014) 9693-9700. doi: 10.1039/c3ra47043a
24. [24]
  F. Zhang, Y. Shi, Z. Zhao, et al., J. Mater. Sci. 49(2014) 3478-3483. doi: 10.1007/s10853-014-8060-3
25. [25]
  W. Zhao, B. Cui, H. Peng, H. Qiu, Y. Wang, J. Phys. Chem. C 119(2015) 4379-4386. doi: 10.1021/jp512447s
26. [26]
  K.R. Reddy, V.G. Gomes, M. Hassan, Mater. Res. Exp. 1(2014) 015012. doi: 10.1088/2053-1591/1/1/015012
27. [27]
  Y.P. Zhang, S.H. Lee, K.R. Reddy, A.I. Gopalan, K.P. Lee, J. Appl. Polym. Sci. 104(2007) 2743-2750. doi: 10.1002/(ISSN)1097-4628
28. [28]
  L. Bai, H. Hua, W. Fu, et al., J. Hazard. Mater. 195(2011) 261-275. doi: 10.1016/j.jhazmat.2011.08.038
29. [29]
  A. Farrukh, A. Akram, A. Ghaffar, et al., ACS Appl. Mater. Interfaces 5(2013) 3784-3793. doi: 10.1021/am400427n
30. [30]
  D.J. Halls, Microchim. Acta 57(1969) 62-77. doi: 10.1007/BF01216666
31. [31]
  N. Azizi, E. Gholibeglo, RSC Adv. 2(2012) 7413-7416. doi: 10.1039/c2ra20615c
32. [32]
  A. Hulanicki, Talanta 14(1967) 1371-1392. doi: 10.1016/0039-9140(67)80159-0
33. [33]
  Z. Li, J. Ind. Eng. Chem. 20(2014) 586-590. doi: 10.1016/j.jiec.2013.05.018
34. [34]
  L. Liu, J. Wu, X. Li, Y. Ling, Sep. Purif. Technol. 103(2013) 92-100. doi: 10.1016/j.seppur.2012.10.028
35. [35]
  P. Yan, M. Ye, S. Sun, et al., J. Clean. Prod. 122(2016) 308-314. doi: 10.1016/j.jclepro.2016.02.037
36. [36]
  K.R. Reddy, K.V. Karthik, S.B. Prasad, et al., Polyhedron 120(2016) 169-174. doi: 10.1016/j.poly.2016.08.029
37. [37]
  L. Zhou, H. Deng, J. Wan, J. Shi, T. Su, Appl. Surf. Sci. 283(2013) 1024-1031. doi: 10.1016/j.apsusc.2013.07.063
38. [38]
  A.M. Showkat, Y.P. Zhang, M.S. Kim, et al., Bull. Korean Chem. Soc. 28(2007) 1985-1992. doi: 10.5012/bkcs.2007.28.11.1985
39. [39]
  Y.S. Ho, G. McKay, Process Biochem. 34(1999) 451-465. doi: 10.1016/S0032-9592(98)00112-5
40. [40]
  B. Xiang, W. Fan, X. Yi, et al., Carbohyd. Polym. 136(2016) 30-37. doi: 10.1016/j.carbpol.2015.08.065
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Preparation of core-shell magnetic Fe3O4@SiO2-dithiocarbamate nanoparticle and its application for the Ni2+, Cu2+ removal

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通讯作者: 陈斌, bchen63@163.com

Preparation of core-shell magnetic Fe₃O₄@SiO₂-dithiocarbamate nanoparticle and its application for the Ni²⁺, Cu²⁺ removal