Citation: Sun Yi, Liang Xin, Xiang Hongfa, Yu Yan. Free-standing vanadium pentoxide nanoribbon film as a high-performance cathode for rechargeable sodium batteries[J]. Chinese Chemical Letters, ;2017, 28(12): 2251-2253. doi: 10.1016/j.cclet.2017.11.028 shu

Free-standing vanadium pentoxide nanoribbon film as a high-performance cathode for rechargeable sodium batteries

Sun Yi ^a ,
Liang Xin ^a ,
Xiang Hongfa ^a,, ,
Yu Yan ^b

a.
Anhui Provincial Key Laboratory of Advanced Functional Materials and Devices, School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China
b.
Key Laboratory of Materials for Energy Conversion Chinese Academy of Sciences, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Xiang Hongfa, hfxiang@hfut.edu.cn
Received Date: 12 October 2017
Revised Date: 15 November 2017
Accepted Date: 20 November 2017
Available Online: 22 December 2017

Figures(4)

Vanadium pentoxide (V₂O₅·nH₂O) nanoribbons are synthesized via a hydrothermal process. These ribbons are 20 nm thick, 200 nm to 1 μm wide and several tens of micrometers long. Free-standing binder-free films are prepared by using these nanoribbons with multi-walled carbon nanotubes (MWCNTs) and used as the cathode for rechargeable sodium batteries. The large interlayer space between the V₂O₅ bilayers can enhance the kinetics of sodium ion intercalation/deintercalation. In addition, the intertwining network of the V₂O₅·0.34H₂O film provides efficient electron conduction pathways and shortens diffusion distances of sodium ion. The electrochemical tests prove that the freestanding V₂O₅·0.34H₂O film cathode delivers high reversible specific capacities (190 mAh/g) and good cycling stabilities (170 mAh/g after 150 cycles) in the voltage range between 1.5 V and 3.5 V.
- Vanadium pentoxide,
- Cathode,
- Free-standing electrode,
- Rechargeable sodium batteries
1. [1]
  S.W. Kim, D.H. Seo, X.H. Ma, et al., Adv. Energy Mater. 2(2012) 710-721. doi: 10.1002/aenm.201200026
2. [2]
  N. Yabuuchi, K. Kubota, M. Dahbi, et al., Chem. Rev. 114(2014) 11636-11682. doi: 10.1021/cr500192f
3. [3]
  D. Kundu, E. Talaie, V. Duffort, et al., Angew. Chem. Int. Ed. 54(2015) 3431-3448. doi: 10.1002/anie.201410376
4. [4]
  Y.M. Li, Y.S. Hu, M.M. Titirici, et al., Adv. Energy Mater. 6(2016) 1600659. doi: 10.1002/aenm.201600659
5. [5]
  M. Sathiya, K. Hemalatha, K. Ramesha, et al., Chem. Mater. 24(2012) 1846-1853. doi: 10.1021/cm300466b
6. [6]
  Y.J. Fang, L.F. Xiao, X.P. Ai, et al., Adv. Mater. 27(2015) 5895-5900. doi: 10.1002/adma.201502018
7. [7]
  D.D. Yuan, W. He, F. Pei, et al., J. Mater. Chem. A 1(2013) 3895-3899. doi: 10.1039/c3ta01430d
8. [8]
  D.D. Yuan, X.H. Hu, J.F. Qian, et al., Electrochim. Acta 116(2014) 300-305. doi: 10.1016/j.electacta.2013.10.211
9. [9]
  M.D. Slater, D. Kim, E. Lee, et al., Adv. Funct. Mater. 23(2013) 947-958. doi: 10.1002/adfm.v23.8
10. [10]
  S.Y. Hong, Y. Kim, Y. Park, et al., Energy Environ. Sci. 6(2013) 2067-2081. doi: 10.1039/c3ee40811f
11. [11]
  H.L. Pan, Y.S. Hu, L.Q. Chen, Energy Environ. Sci. 6(2013) 2338-2360. doi: 10.1039/c3ee40847g
12. [12]
  Y.S. Hu, X. Liu, J.O. Muller, et al., Angew. Chem. Int. Ed. 48(2008) 210-214.
13. [13]
  C.K. Chan, H.L. Peng, R.D. Twesten, et al., Nano Lett. 7(2007) 490-495. doi: 10.1021/nl062883j
14. [14]
  S.T. Song, P.H. Ma, S.Y. Li, et al., Chin. Chem. Lett. 19(2008) 337-341. doi: 10.1016/j.cclet.2008.01.001
15. [15]
  X.H. Rui, Z.Y. Lu, H. Yu, et al., Nanoscale 5(2013) 556-560. doi: 10.1039/C2NR33422D
16. [16]
  X. Rocquefelte, F. Boucher, P. Gressier, et al., Chem. Mater.15(2003) 1812-1819. doi: 10.1021/cm021254h
17. [17]
  W. Tang, X. Gao, Y. Zhu, et al., J. Mater. Chem. 22(2012) 20143-20145. doi: 10.1039/c2jm34563c
18. [18]
  X.D. Zhao, X. Zhang, D.H. Wu, et al., J. Mater. Chem. A 4(2016) 16606-16611. doi: 10.1039/C6TA04986A
19. [19]
  X.M. Shi, J.C. Li, X.Y. Lang, et al., J. Phys. Chem. C 121(2017) 5974-5982. doi: 10.1021/acs.jpcc.7b00481
20. [20]
  D.W. Su, S.X. Dou, G.X. Wang, et al., J. Mater. Chem. A 2(2014) 11185-11194. doi: 10.1039/c4ta01751j
21. [21]
  A. Moretti, S. Passerini, Adv. Energy Mater. 6(2016) 1600868. doi: 10.1002/aenm.201600868
22. [22]
  S. Tepavcevic, H. Xiong, V.R. Stamenkovic, et al., ACS Nano 6(2012) 530-538. doi: 10.1021/nn203869a
23. [23]
  D.W. Su, G.X. Wang, ACS Nano 7(2013) 11218-11226. doi: 10.1021/nn405014d
24. [24]
  E. Uchaker, Y.Z. Zheng, S. Li, et al., J. Mater. Chem. A 2(2014) 18208-18214. doi: 10.1039/C4TA03788J
25. [25]
  Y. Sun, S.B. Yang, L.P. Lv, et al., J. Power Sources 241(2013) 168-172. doi: 10.1016/j.jpowsour.2013.04.093
26. [26]
  D. Nan, Z.H. Huang, R.T. Lv, et al., J. Mater. Chem. A 2(2014) 19678-19684. doi: 10.1039/C4TA03868A
27. [27]
  S.Q. Wang, L. Xia, L. Yu, et al., Adv. Energy Mater. 6(2016) 1502217. doi: 10.1002/aenm.201502217
28. [28]
  L. David, R. Bhandavat, G. Singh, ACS Nano 8(2014) 1759-1770. doi: 10.1021/nn406156b
29. [29]
  N. Sa, T.L. Kinnibrugh, H. Wang, et al., Chem. Mater. 28(2016) 2962-2969. doi: 10.1021/acs.chemmater.6b00026
30. [30]
  V.M. Mohan, B. Hu, W.L. Qiu, et al., J. Appl. Electrochem. 39(2009) 2001-2006. doi: 10.1007/s10800-009-9910-6
31. [31]
  L.Y. Su, J. Winnick, P. Kohl, J. Power Sources 101(2001) 226-230. doi: 10.1016/S0378-7753(01)00787-X
1. [1]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
2. [2]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
3. [3]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
4. [4]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
5. [5]
  Runjing Xu , Xin Gao , Ya Chen , Xiaodong Chen , Lifeng Cui . Research status and prospect of rechargeable magnesium ion batteries cathode materials. Chinese Chemical Letters, 2024, 35(11): 109852-. doi: 10.1016/j.cclet.2024.109852
6. [6]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
7. [7]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
8. [8]
  Xianping Du , Ying Huang , Chen Chen , Zhenhe Feng , Meng Zong . Encapsulating Si particles in multiple carbon shells with pore-rich for constructing free-standing anodes of lithium storage. Chinese Chemical Letters, 2024, 35(12): 109990-. doi: 10.1016/j.cclet.2024.109990
9. [9]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
10. [10]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
11. [11]
  Haiying Lu , Weijie Li . The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(11): 100334-100334. doi: 10.1016/j.cjsc.2024.100334
12. [12]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
13. [13]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
14. [14]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
15. [15]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536
16. [16]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
17. [17]
  Yun Wei , Lei Zhou , Wenbin Hu , Liming Yang , Guang Yang , Chaoqiang Wang , Hui Shi , Fei Han , Yufa Feng , Xuan Ding , Penghui Shao , Xubiao Luo . Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries: Process analysis and evaluation. Chinese Chemical Letters, 2024, 35(7): 109172-. doi: 10.1016/j.cclet.2023.109172
18. [18]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
19. [19]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
20. [20]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(622)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142