Citation: Xia Tifeng, Wang Jintong, Jiang Ke, Cui Yuanjing, Yang Yu, Qian Guodong. A Eu/Gd-mixed metal-organic framework for ultrasensitive physiological temperature sensing[J]. Chinese Chemical Letters, ;2018, 29(6): 861-864. doi: 10.1016/j.cclet.2017.10.038 shu

A Eu/Gd-mixed metal-organic framework for ultrasensitive physiological temperature sensing

State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, School of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Cui Yuanjing, cuiyj@zju.edu.cn Qian Guodong, gdqian@zju.edu.cn
Received Date: 9 August 2017
Revised Date: 27 October 2017
Accepted Date: 30 October 2017
Available Online: 2 June 2017

Figures(3)

A series of Eu/Gd-mixed metal-organic frameworks Eu_xGd_1-xNDC (x=0.0005, 0.001, 0.003, 0.01; H₂NDC=1, 4-naphthalene dicarboxylic acid) utilizing back energy transfer have been developed for physiological temperature sensing. The suitable high triplet level of H₂NDC allows an efficient back energy transfer from Eu³⁺ ions to ligands. The back energy transfer efficiency is further enhanced by the Eu³⁺/Gd³⁺-mixed strategy. As a consequence, the emission of Eu³⁺ dramatically weakens when temperature arises. The resultant Eu_0.0005Gd_0.9995NDC exhibits exceptional stability and good biocompatibility, and can detect physiological temperature in single-emission, dual-emission, and colorimetric models with ultra-high sensitivity.
- Metal-organic frameworks,
- Thermometer,
- Physiological temperature,
- Ratiometric,
- Back energy transfer
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