Citation: Du Weishi, Lv Yaokang, Lu Hongliang, Chen Zaihua, Wright Dominic S., Zhang Cheng. Surface modification by graphene oxide:An efficient strategy to improve the performance of activated carbon based supercapacitors[J]. Chinese Chemical Letters, ;2017, 28(12): 2285-2289. doi: 10.1016/j.cclet.2017.10.031 shu

Surface modification by graphene oxide:An efficient strategy to improve the performance of activated carbon based supercapacitors

a.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
b.
Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, United Kingdom
c.
State Key Laboratory of ASIC and System, Institute of Advanced Nanodevices, School of Microelectronics, Fudan University, Shanghai 200433, China
d.
Zhejiang Forasen Energy Technology Co., Shuige Industrial Estate, Lishui 323000, China

Corresponding author: Lv Yaokang, yaokanglv@zjut.edu.cn Zhang Cheng, czhang@zjut.edu.cn

Received Date: 21 July 2017
Revised Date: 20 September 2017
Accepted Date: 25 October 2017
Available Online: 26 December 2017

Figures(4)

We demonstrate an efficient and cost-effective strategy to improve electrochemical properties of AC based electrode materials. A series of graphene oxide (GO)-modified activated carbon (AC) composites (GO@ACs) have been prepared as electrode materials for supercapacitors (SCs). In GO@ACs, AC particles anchored on the surface of GO sheets which were synchronously reduced during charge/discharge process, and formed a 3D-conductive network. Electrochemical analyses revealed that 2.5 wt% GO@AC, which exhibited improved electrical conductivity and high specific capacitance at large current density in organic electrolyte, is a promising electrode material for high-performance SCs. At 6 A/g, the specific capacitance of 2.5 wt% GO@AC increased by 249.5% in comparison with that of AC.
- Electrode materials,
- Activated carbon,
- Graphene oxide,
- Supercapacitor
1. [1]
  M. Salanne, B. Rotenberg, K. Naneko, et al., Nat. Energy 70(2016) 16070.
2. [2]
  Y. Lv, W. Du, Y. Ren, et al., Inorg. Chem. Front. 3(2016) 1119-1123. doi: 10.1039/C6QI00114A
3. [3]
  H. Cong, X. Ren, P. Wang, S. Yu, Energy Environ. Sci. 6(2013) 1185-1191. doi: 10.1039/c2ee24203f
4. [4]
  D. Zhu, K. Cheng, Y. Wang, et al., Electrochim. Acta 224(2017) 17-24. doi: 10.1016/j.electacta.2016.12.023
5. [5]
  Z. Xu, J. Wang, Z. Hu, R. Geng, L. Gan, Electrochim. Acta 231(2017) 601-608. doi: 10.1016/j.electacta.2016.12.179
6. [6]
  N. Li, T. Lv, Y. Yao, et al., J. Mater. Chem. A 5(2017) 3267-3273. doi: 10.1039/C6TA10165H
7. [7]
  W. Lu, S. Huang, L. Miao, et al., Chin. Chem. Lett. 28(2017) 1324-1329. doi: 10.1016/j.cclet.2017.04.007
8. [8]
  Y. Lv, L. Gan, M. Liu, et al., J. Power Sources 209(2012) 152-157. doi: 10.1016/j.jpowsour.2012.02.089
9. [9]
  J. Yan, T. We, B. Shao, et al., Carbon 48(2010) 487-493. doi: 10.1016/j.carbon.2009.09.066
10. [10]
  A.V. Murugan, T. Muraliganth, A. Manthiram, Chem. Mater. 21(2009) 5004-5006. doi: 10.1021/cm902413c
11. [11]
  D. Wang, F. Li, J. Zhao, et al., ACS Nano 3(2009) 1745-1752. doi: 10.1021/nn900297m
12. [12]
  S. Chen, J. Zhu, X. Wu, Q. Han, X. Wang, ACS Nano 4(2010) 2822-2830. doi: 10.1021/nn901311t
13. [13]
  L. Miao, D. Zhu, Y. Zhao, et al., Microporous Mesoporous Mater. 253(2017) 1-9. doi: 10.1016/j.micromeso.2017.06.032
14. [14]
  J. Liu, Z. Cai, Y. Lv, et al., J. Mater. Chem. A 3(2015) 1837-1840. doi: 10.1039/C4TA05441E
15. [15]
  W. Du, Y. Lv, Z. Cai, C. Zhang, Acta Phys. Chim. Sin. 33(9) (2017) 1828-1837.
16. [16]
  D. Yang, C. Bock, J. Power Sources 337(2017) 73-81. doi: 10.1016/j.jpowsour.2016.10.108
17. [17]
  L. Zhang, T.J. Huang, H. Gong, Phys. Chem. Chem. Phys. 19(2017) 10462-10469. doi: 10.1039/C7CP01234A
18. [18]
  F. Kuok, C. Liao, T. Wan, et al., J. Alloys Compd. (2017) 558-562.
19. [19]
  Y. Dai, H. Jiang, Y. Hu, Y. Fu, C. Li, Ind. Eng. Chem. Res. 53(2014) 3125-3130. doi: 10.1021/ie403950t
20. [20]
  Y. Dai, L. Chen, V. Babayan, et al., J. Mater. Chem. A 3(2015) 21337-21342. doi: 10.1039/C5TA06958K
21. [21]
  D. Qu, H. Shi, J. Power Sources 74(1998) 99-107. doi: 10.1016/S0378-7753(98)00038-X
22. [22]
  M. Endo, T. Maeda, T. Takeda, et al., J. Electrochem. Soc. 148(2001) A910-A914. doi: 10.1149/1.1382589
23. [23]
  E.R. Pinero, K. Kierzek, J. Machnikowski, F. Beguin, Carbon 44(2006) 2498-2507. doi: 10.1016/j.carbon.2006.05.022
24. [24]
  O. Barbieri, M. Hahn, A. Herzog, R. Kotz, Carbon 43(2005) 1303-1310. doi: 10.1016/j.carbon.2005.01.001
25. [25]
  K. Kierzek, E. Frackowiak, G. Lota, G. Gryglewicz, J. Machnikowski, Electrochim. Acta 49(2004) 515-523. doi: 10.1016/j.electacta.2003.08.026
26. [26]
  G. Salitra, A. Soffer, L. Eliad, Y. Cohen, D. Aurbach, J. Electrochem. Soc. 147(2000) 2486-2493. doi: 10.1149/1.1393557
27. [27]
  E.R. Pinero, F. Leroux, F. Beguin, Adv. Mater. 18(2006) 1877-1882. doi: 10.1002/(ISSN)1521-4095
28. [28]
  C. Zheng, X.F. Zhou, H.L. Cao, G.H. Wang, Z.P. Liu, J. Power Sources 258(2014) 290-296. doi: 10.1016/j.jpowsour.2014.01.056
29. [29]
  J.C. Meyer, A.K. Geim, M.I. Katsnelson, et al., Nature 446(2007) 60-63. doi: 10.1038/nature05545
30. [30]
  R.R. Nair, P. Blake, A.N. Grigorenko, et al., Science 320(2008) 1308. doi: 10.1126/science.1156965
31. [31]
  Q.X. Xie, A.R. Zheng, S.B. Zhai, et al., J. Solid State Electrochem. 20(2016) 449-457. doi: 10.1007/s10008-015-3061-y
32. [32]
  Y.W. Zhu, S. Murali, W.W. Cai, et al., Adv. Mater. 22(2010) 3906-3924. doi: 10.1002/adma.201001068
33. [33]
  M. Deraman, N.S.M. Nor, N.H. Basri, et al., Adv. Mater. Res.1112(2015) 231-235. doi: 10.4028/www.scientific.net/AMR.1112
34. [34]
  M.A. Azam, N. Dorah, R.N.A.R. Seman, N.S.A. Manaf, T.I.T. Kudin, Mater. Technol. 30(2015) A14-A17. doi: 10.1179/1753555714Y.0000000229
35. [35]
  L. Jiang, J. Yan, Y. Zhou, et al., J. Solid State Electrochem. 17(2013) 2949-2958. doi: 10.1007/s10008-013-2217-x
36. [36]
  C. Zheng, X. Zhou, H. Cao, G. Wang, Z. Liu, J. Power Sources 258(2014) 290-296. doi: 10.1016/j.jpowsour.2014.01.056
37. [37]
  H. Wang, H.S. Casalongue, Y. Liang, H. Dai, J. Am. Chem. Soc. 132(2010) 7472-7477. doi: 10.1021/ja102267j
38. [38]
  Y. Huang, J. Liang, Y. Chen, Small 8(2012) 1805-1834. doi: 10.1002/smll.201102635
39. [39]
  Y. Chen, C. Chiu, H. Lin, et al., Solid State Sci. 3(2014) 80-85.
40. [40]
  B.G. Choi, H.S. Park, T.J. Park, et al., ACS Nano 4(2010) 2910-2918. doi: 10.1021/nn100145x
41. [41]
  J. Kauppila, P. Kunnas, P. Damlin, A. Viinikanoja, C. Kvarnström, Electrochim. Acta 89(2013) 84-89. doi: 10.1016/j.electacta.2012.10.153
42. [42]
  K. Krishnamoorthy, M. Veerapandian, K. Yun, S.J. Kim, Carbon 53(2013) 38-49. doi: 10.1016/j.carbon.2012.10.013
43. [43]
  L. Tang, Y. Wang, Y. Li, H. Feng, J. Lu, Adv. Funct. Mater. 19(2009) 2782-2789. doi: 10.1002/adfm.v19:17
44. [44]
  Y.K. Lv, M.X. Liu, L.H. Gan, et al., Chem. Lett. 40(2011) 236-238. doi: 10.1246/cl.2011.236
45. [45]
  R.H. Bradley, M.W. Smith, A. Andreu, M. Falco, Appl. Surf. Sci. 257(2011) 2912-2919. doi: 10.1016/j.apsusc.2010.10.089
46. [46]
  M. Liu, X. Ma, L. Gan, et al., J. Mater. Chem. A 2(2014) 17107-17114. doi: 10.1039/C4TA02888K
47. [47]
  A. Balakrishnan, K. R. V. Subramanian, Nanostructured ceramic oxides for supercapacitor applications, CRC Press, Boca Raton, 2014.
48. [48]
  K. Deng, J. Zhou, X. Li, et al., Colloid Surf. B 101(2013) 183-188. doi: 10.1016/j.colsurfb.2012.06.007
49. [49]
  H. Guo, X. Wang, Q. Qian, F. Wang, X. Xia, ACS Nano 3(2009) 2653-2659. doi: 10.1021/nn900227d
50. [50]
  Y.Y. Shao, J. Wang, M. Engelhard, C.M. Wang, Y.H. Lin, J. Mater. Chem. 20(2010) 743-748. doi: 10.1039/B917975E
51. [51]
  Y.Y. Shao, G.P. Yin, J. Zhang, Y.Z. Gao, Electrochim. Acta 51(2006) 5853-5857. doi: 10.1016/j.electacta.2006.03.021
52. [52]
  K. Krishnamoorthy, M. Veerapandian, K. Yun, S.J. Kim, Carbon 53(2013) 38-49. doi: 10.1016/j.carbon.2012.10.013
53. [53]
  K. Deng, J. Zhou, X. Li, Colloids Surf. B Biointerfaces 101(2013) 183-188. doi: 10.1016/j.colsurfb.2012.06.007
54. [54]
  H. Jiang, P.S. Lee, C. Lee, Energy Environ. Sci. 6(2013) 41-53. doi: 10.1039/C2EE23284G
55. [55]
  J.T. Zhang, X.S. Zhao, J. Phys. Chem. C 116(2012) 5420-5426.
56. [56]
  M.D. Stoller, S. Park, Y. Zhu, J. An, R.S. Ruoff, Nano Lett. 8(2008) 3498-3502. doi: 10.1021/nl802558y
57. [57]
  M.B. Lim, M. Hu, S. Manandhar, et al., Carbon 95(2015) 616-624. doi: 10.1016/j.carbon.2015.08.037
1. [1]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
2. [2]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
3. [3]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
4. [4]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
5. [5]
  Yuanyi Zhou , Ke Ma , Jinfeng Liu , Zirun Zheng , Bo Hu , Yu Meng , Zhizhong Li , Mingshan Zhu . Is reactive oxygen species the only way for cancer inhibition over single atom nanomedicine? Autophagy regulation also works. Chinese Chemical Letters, 2024, 35(6): 109056-. doi: 10.1016/j.cclet.2023.109056
6. [6]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
7. [7]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
8. [8]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
9. [9]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
10. [10]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
11. [11]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
12. [12]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
13. [13]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
14. [14]
  Xinyu Huai , Jingxuan Liu , Xiang Wu . Cobalt-Doped NiMoO4 Nanosheet for High-performance Flexible Supercapacitor. Chinese Journal of Structural Chemistry, 2023, 42(10): 100158-100158. doi: 10.1016/j.cjsc.2023.100158
15. [15]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
16. [16]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
17. [17]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
18. [18]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
19. [19]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
20. [20]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(633)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142