Citation: He Weiwei, Li Na, Wang Xi, Hu Tongliang, Bu Xianhe. A cationic metal-organic framework based on {Zn₄} cluster for rapid and selective adsorption of dyes[J]. Chinese Chemical Letters, ;2018, 29(6): 857-860. doi: 10.1016/j.cclet.2017.10.003 shu

A cationic metal-organic framework based on {Zn₄} cluster for rapid and selective adsorption of dyes

He Weiwei ^a ,
Li Na ^b ,
Wang Xi ^b ,
Hu Tongliang ^b,c,, ,
Bu Xianhe ^a,b,c

a.
Department of Chemistry, Nankai University, Tianjin 300071, China
b.
School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, China
c.
Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China

Corresponding author: Hu Tongliang, tlhu@nankai.edu.cn
Received Date: 17 August 2017
Revised Date: 30 September 2017
Accepted Date: 10 October 2017
Available Online: 13 June 2017

Figures(4)

Until now, to remove the harmful organic dyes from effluents is an outstanding challenge. The design and synthesis of new porous materials capable of selectively adsorbing dyes are critical to the environment and human health. Here, a unique cluster-based cationic metal-organic framework, named {[Zn₈(BTA)₆(L)₅Cl₂] ·(NO₃)₃}·5DMF (NUM-4) was synthesized, which displays one-dimensional (1D) open channels along a axis in its 3D supramolecular stacking structure. Benefiting from the nature of cationic framework and high surface area/pore volume, NUM-4 shows rapid and selective adsorption of anionic dyes (MO, AO, CR and MB) based on the charge-exclusive effect. Besides, the adsorbed dyes can be easily released in NH₄Cl saturated solution of ethanol.
- Metal-organic framework,
- Supermolecule,
- Anionic dyes,
- Adsorption and separation,
- Charge-exclusive effect
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A cationic metal-organic framework based on {Zn4} cluster for rapid and selective adsorption of dyes

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通讯作者: 陈斌, bchen63@163.com

A cationic metal-organic framework based on {Zn₄} cluster for rapid and selective adsorption of dyes