Citation: Song Wuqiong, Cai Juntao, Zou Xiaopeng, Wang Xiaoli, Hu Jing, Yin Jian. Applications of controlled inversion strategies in carbohydrate synthesis[J]. Chinese Chemical Letters, ;2018, 29(1): 27-34. doi: 10.1016/j.cclet.2017.09.061 shu

Applications of controlled inversion strategies in carbohydrate synthesis

Song Wuqiong ^a ,
Cai Juntao ^a ,
Zou Xiaopeng ^a ,
Wang Xiaoli ^a ,
Hu Jing ^b,, ,
Yin Jian ^a,,

a.
Key Laboratory of Carbohydrate Chemistry and Biotechnology, Ministry of Education, School of Biotechnology, Jiangnan University, Wuxi 214122, China
b.
Wuxi School of Medicine, Jiangnan University, Wuxi 214122, China

Corresponding author: Hu Jing, Yin Jian,
Received Date: 30 June 2017
Revised Date: 26 September 2017
Accepted Date: 29 September 2017
Available Online: 4 January 2018

Figures(6)

Carbohydrates play critical roles in mediating many biological processes, such as cell growth, migration, cell-cell adhesion, fertilization, signal transduction and immune response. The increasing demands for the study of these molecules greatly facilitate the development of carbohydrate synthesis. Inversion strategies via sulfonyl groups, selective reductions, etc. have been used to synthesize corresponding inverted configurations. This review focuses on the mechanisms of these inversion methods and their applications in constructing amino sugars, rare sugars and β-configurations in glycosylations.
- Inversion strategy,
- S_N2 displacement,
- Stereoselective reduction,
- Epimerase
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沈阳化工大学材料科学与工程学院沈阳 110142