Citation: Liu Jianguo, Zhang Ailing, Song Heng, Tong Qingxiao, Tung Chen-Ho, Wang Wenguang. Iron(Ⅱ) hydrides bearing a tetradentate PSNP ligand[J]. Chinese Chemical Letters, ;2018, 29(6): 949-953. doi: 10.1016/j.cclet.2017.09.059 shu

Iron(Ⅱ) hydrides bearing a tetradentate PSNP ligand

a.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
b.
Department of Chemistry, Shantou University, Shantou 515063, China

Corresponding author: Tong Qingxiao, qxtong@stu.edu.cn Wang Wenguang, wwg@sdu.edu.cn
Received Date: 6 August 2017
Revised Date: 28 September 2017
Accepted Date: 28 September 2017
Available Online: 4 June 2017

Figures(10)

A new class of iron(Ⅱ) hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron(Ⅱ) complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron complex[2H(NCMe)](BF₄) is capable of catalyzing aldehyde hydroboration by pinacolborane (HBpin) and with extremely high efficiency at room temperature. Aldehydes with various functional groups are compatible.
- Iron(Ⅱ) hydride,
- Iron catalysis,
- Tetradentate ligand,
- Hydroboration,
- Aldehydes
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1.
沈阳化工大学材料科学与工程学院沈阳 110142