Citation: Wang Ying, Li Liangjun, Yan Liting, Cao Lei, Dai Pengcheng, Gu Xin, Zhao Xuebo. Continuous synthesis for zirconium metal-organic frameworks with high quality and productivity via microdroplet flow reaction[J]. Chinese Chemical Letters, ;2018, 29(6): 849-853. doi: 10.1016/j.cclet.2017.09.057 shu

Continuous synthesis for zirconium metal-organic frameworks with high quality and productivity via microdroplet flow reaction

Wang Ying ^a,b,1 ,
Li Liangjun ^a,1 ,
Yan Liting ^a,b ,
Cao Lei ^a ,
Dai Pengcheng ^a ,
Gu Xin ^a ,
Zhao Xuebo ^a,,

a.
Research Center of New Energy Science and Technology, Research Institute of Unconventional Oil & Gas and Renewable Energy, China University of Petroleum(East China), Qingdao 266580, China
b.
College of Science, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: Zhao Xuebo, zhaoxuebo@upc.edu.cn, zhaoxb@qibebt.ac.cn

Received Date: 12 August 2017
Revised Date: 20 September 2017
Accepted Date: 26 September 2017
Available Online: 2 June 2017

Figures(5)

Zirconium metal-organic frameworks (Zr-MOFs) represent the most promising candidates among MOFs for industrial utilizations owing to their high porosity and excellent stability. However, the efficient synthesis of Zr-MOFs combining with continuous production, high productivity and good product quality still remains a critical issue for practical applications. Herein, we report an efficient method of synthesizing a series of Zr-MOFs through a microdroplet flow reaction, which is more accommodate the requirements of industrial production. Four types of Zr-based MOFs with different ligands and topologies (MOF-801, MOF-804, DUT-67 and MOF-808) were produced as a pure phase of high quality crystalline with uniform morphologies. Furthermore, this series of Zr-MOFs were obtained in a continuous way and at a space-time yield (STY) highly up to 367.2 kg m^-3 d^-1. These MOFs exhibit the similar pore structure and thermal stability with that prepared from conventional solvothermal synthesis. CO₂ sorption studies on these MOFs demonstrate that the hydroxyl groups on ligand can render MOFs with high CO₂/N₂ selectivity.
- Zirconium metal-organic frameworks,
- Microdroplet flow reaction,
- Continuous synthesis,
- Space-time yield,
- CO₂ adsorption
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