Citation: Zhao Shiyong, Xu Bolian, Yu Lei, Fan Yining. Catalytic dehydrogenation of propane to propylene over highly active PtSnNa/γ-Al₂O₃ catalyst[J]. Chinese Chemical Letters, ;2018, 29(3): 475-478. doi: 10.1016/j.cclet.2017.09.020 shu

Catalytic dehydrogenation of propane to propylene over highly active PtSnNa/γ-Al₂O₃ catalyst

Zhao Shiyong ^a ,
Xu Bolian ^a,b ,
Yu Lei ^a,b,c,*,, ,
Fan Yining ^a,b,**,,

a.
Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
b.
Nanjing University-Yangzhou Chemistry and Chemical Engineering Institute, Yangzhou 211400, China
c.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Corresponding author: Yu Lei, yulei@yzu.edu.cn Fan Yining, ynfan@nju.edu.cn

^**

Received Date: 22 June 2017
Revised Date: 9 August 2017
Accepted Date: 5 September 2017
Available Online: 8 March 2017

Figures(4)

PtSnNa/γ-Al₂O₃ catalyst is widely used in the dehydrogenation of light alkane. This paper reports a new fabrication method of the catalyst. In the work, γ-Al₂O₃, SnCl₄ and NaCl were ball milled to upload Sn and Na⁺ onto the support instead of the conventionally used immersion method. The subsequent baking procedures frimly fixed Sn onto the support, which could disperse Pt introduced by immersion. The effects of Sn and Na⁺ additives on the catalytic performance of PtSnNa/γ-Al₂O₃ catalyst were investigated. It was found that the appropriate molar ratio of Sn/Pt was 6:1 while the favorable weight percentage of Na⁺ was 0.90%. Compared with the reaction catalyzed by the industrially employed PtSnNa/γ-Al₂O₃ catalyst, the conversion of propane and the selectivity of propylene had been greatly improved, which were 26.97% and 99.18% respectively after 12 h reaction.
- Propane,
- Propylene,
- Dehydrogenation,
- Platinum,
- Aluminum oxide
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic dehydrogenation of propane to propylene over highly active PtSnNa/γ-Al2O3 catalyst

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通讯作者: 陈斌, bchen63@163.com

Catalytic dehydrogenation of propane to propylene over highly active PtSnNa/γ-Al₂O₃ catalyst