Citation: Cheng Youdong, Ravi Sai Kishore, Wang Yuxiang, Tao Jifang, Gu Yuandong, Tan Swee Ching, Zhao Dan. Covalent organic nanosheets with large lateral size and high aspect ratio synthesized by Langmuir-Blodgett method[J]. Chinese Chemical Letters, ;2018, 29(6): 869-872. doi: 10.1016/j.cclet.2017.09.002 shu

Covalent organic nanosheets with large lateral size and high aspect ratio synthesized by Langmuir-Blodgett method

a.
Department of Chemical & Biomolecular Engineering, National University of Singapore, Singapore 117585, Singapore
b.
Department of Materials Science and Engineering, National University of Singapore, Singapore 117575, Singapore
c.
Institute of Microelectronics, A^*STAR(Agency for Science, Technology and Research), Singapore 138634, Singapore

Corresponding author: Zhao Dan, chezhao@nus.edu.sg
Received Date: 7 July 2017
Revised Date: 11 August 2017
Accepted Date: 1 September 2017
Available Online: 5 June 2017

Figures(4)

Two-dimensional (2D) materials have attracted increasing attentions recently due to their unique physical and chemical properties. We herein report the synthesis of four chemically stable 2D covalent organic nanosheets (CONs) with large lateral sizes (up to 200 μm) and high aspect ratios (> 20 000) at the air-water interface through the Langmuir-Blodgett method. These CONs exhibit good crystallinity proved by high resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED). In addition, the hydrophobicity of these CONs can be systematically adjusted by the introduction of various functional groups, making them suitable as functional coating and membrane materials.
- Two dimensional materials,
- Covalent organic nanosheets,
- Schiff base chemistry,
- Langmuir-Blodgett,
- Functional surface coating
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1.
沈阳化工大学材料科学与工程学院沈阳 110142