Citation: Cheng Youdong, Ravi Sai Kishore, Wang Yuxiang, Tao Jifang, Gu Yuandong, Tan Swee Ching, Zhao Dan. Covalent organic nanosheets with large lateral size and high aspect ratio synthesized by Langmuir-Blodgett method[J]. Chinese Chemical Letters, ;2018, 29(6): 869-872. doi: 10.1016/j.cclet.2017.09.002 shu

Covalent organic nanosheets with large lateral size and high aspect ratio synthesized by Langmuir-Blodgett method

a.
Department of Chemical & Biomolecular Engineering, National University of Singapore, Singapore 117585, Singapore
b.
Department of Materials Science and Engineering, National University of Singapore, Singapore 117575, Singapore
c.
Institute of Microelectronics, A^*STAR(Agency for Science, Technology and Research), Singapore 138634, Singapore

Corresponding author: Zhao Dan, chezhao@nus.edu.sg
Received Date: 7 July 2017
Revised Date: 11 August 2017
Accepted Date: 1 September 2017
Available Online: 5 June 2017

Figures(4)

Two-dimensional (2D) materials have attracted increasing attentions recently due to their unique physical and chemical properties. We herein report the synthesis of four chemically stable 2D covalent organic nanosheets (CONs) with large lateral sizes (up to 200 μm) and high aspect ratios (> 20 000) at the air-water interface through the Langmuir-Blodgett method. These CONs exhibit good crystallinity proved by high resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED). In addition, the hydrophobicity of these CONs can be systematically adjusted by the introduction of various functional groups, making them suitable as functional coating and membrane materials.
- Two dimensional materials,
- Covalent organic nanosheets,
- Schiff base chemistry,
- Langmuir-Blodgett,
- Functional surface coating
1. [1]
  K.S. Novoselov, A.K. Geim, S.V. Morozov, et al., Science 306(2004) 666-669. doi: 10.1126/science.1102896
2. [2]
  M. Chhowalla, Z. Liu, H. Zhang, Chem. Soc. Rev. 44(2015) 2584-2586. doi: 10.1039/C5CS90037A
3. [3]
  J. Zhang, Y. Chen, X. Wang, Energy Environ. Sci. 8(2015) 3092-3108. doi: 10.1039/C5EE01895A
4. [4]
  Z. Huang, A. Zhou, J. Wu, et al., Adv. Mater. 28(2016) 1703-1708. doi: 10.1002/adma.201504484
5. [5]
  M. Xu, T. Liang, M. Shi, H. Chen, Chem. Rev. 113(2013) 3766-3798. doi: 10.1021/cr300263a
6. [6]
  Y. Zhu, S. Murali, M.D. Stoller, et al., Science 332(2011) 1537-1541. doi: 10.1126/science.1200770
7. [7]
  J.H. Chen, C. Jang, S. Xiao, M. Ishigami, M.S. Fuhrer, Nat. Nanotechnol. 3(2008) 206-209. doi: 10.1038/nnano.2008.58
8. [8]
  Q. Li, B. Guo, J. Yu, et al., J. Am. Chem. Soc. 133(2011) 10878-10884. doi: 10.1021/ja2025454
9. [9]
  P.J. Waller, F. Gándara, O.M. Yaghi, Acc. Chem. Res. 48(2015) 3053-3063. doi: 10.1021/acs.accounts.5b00369
10. [10]
  S. Chandra, S. Kandambeth, B.P. Biswal, et al., J. Am. Chem. Soc. 135(2013) 17853-17861. doi: 10.1021/ja408121p
11. [11]
  M.A. Khayum, S. Kandambeth, S. Mitra, et al., Angew. Chem. Int. Ed. 55(2016) 15604-15608. doi: 10.1002/anie.201607812
12. [12]
  A.P. Côté, A.I. Benin, N.W. Ockwig, et al., Science 310(2005) 1166-1170. doi: 10.1126/science.1120411
13. [13]
  N.A.A. Zwaneveld, R. Pawlak, M. Abel, et al., J. Am. Chem. Soc. 130(2008) 6678-6679. doi: 10.1021/ja800906f
14. [14]
  W. Liu, X. Luo, Y. Bao, et al., Nat. Chem. 9(2017) 563-570. doi: 10.1038/nchem.2696
15. [15]
  D.J. Murray, D.D. Patterson, P. Payamyar, et al., J. Am. Chem. Soc. 137(2015) 3450-3453. doi: 10.1021/ja512018j
16. [16]
  W. Dai, F. Shao, J. Szczerbiński, et al., Angew. Chem. Int. Ed. 128(2016) 221-225. doi: 10.1002/ange.201508473
17. [17]
  H. Sahabudeen, H. Qi, B.A. Glatz, et al., Nat. Commun. 7(2016) 13461. doi: 10.1038/ncomms13461
18. [18]
  S. Kandambeth, A. Mallick, B. Lukose, et al., J. Am. Chem. Soc. 134(2012) 19524-19527. doi: 10.1021/ja308278w
19. [19]
  Z. Kang, Y. Peng, Y. Qian, et al., Chem. Mater. 28(2016) 1277-1285. doi: 10.1021/acs.chemmater.5b02902
20. [20]
  I. Berlanga, M.L. Ruiz-González, J.M. González-Calbet, et al., Small 7(2011) 1207-1211. doi: 10.1002/smll.v7.9
21. [21]
  B. Lukose, A. Kuc, T. Heine, Chem. Eur. J. 17(2011) 2388-2392. doi: 10.1002/chem.201001290
22. [22]
  H. Zhou, Z. Zhang, C. Jiang, et al., Anal. Chem. 83(2011) 6913-6917. doi: 10.1021/ac201407z
23. [23]
  D. Mullangi, S. Shalini, S. Nandi, B. Choksi, V. Ramanathan, J. Mater. Chem. A 5(2017) 8376-8384. doi: 10.1039/C7TA01302G
24. [24]
  P.K. Chow, E. Singh, B.C. Viana, et al., ACS Nano 9(2015) 3023-3031. doi: 10.1021/nn5072073
1. [1]
  Jiahao Li , Guinan Chen , Chunhong Chen , Yuanyuan Lou , Zhihao Xing , Tao Zhang , Chengtao Gong , Yongwu Peng . Modulated synthesis of stoichiometric and sub-stoichiometric two-dimensional covalent organic frameworks for enhanced ethylene purification. Chinese Chemical Letters, 2025, 36(1): 109760-. doi: 10.1016/j.cclet.2024.109760
2. [2]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
3. [3]
  Yuting Wu , Haifeng Lv , Xiaojun Wu . Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective. Chinese Journal of Structural Chemistry, 2024, 43(11): 100375-100375. doi: 10.1016/j.cjsc.2024.100375
4. [4]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
5. [5]
  Chao Liu , Chao Jia , Shi-Xian Gan , Qiao-Yan Qi , Guo-Fang Jiang , Xin Zhao . A luminescent one-dimensional covalent organic framework for organic arsenic sensing in water. Chinese Chemical Letters, 2024, 35(11): 109750-. doi: 10.1016/j.cclet.2024.109750
6. [6]
  Xinghong Cai , Qiang Yang , Yao Tong , Lanyin Liu , Wutang Zhang , Sam Zhang , Min Wang . AlO₂: A novel two-dimensional material with a high negative Poisson's ratio for the adsorption of volatile organic compounds. Chinese Chemical Letters, 2025, 36(2): 109586-. doi: 10.1016/j.cclet.2024.109586
7. [7]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
8. [8]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
9. [9]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
10. [10]
  Xin Li , Zhen Xu , Donglei Bu , Jinming Cai , Huamei Chen , Qi Chen , Ting Chen , Fang Cheng , Lifeng Chi , Wenjie Dong , Zhenchao Dong , Shixuan Du , Qitang Fan , Xing Fan , Qiang Fu , Song Gao , Jing Guo , Weijun Guo , Yang He , Shimin Hou , Ying Jiang , Huihui Kong , Baojun Li , Dengyuan Li , Jie Li , Qing Li , Ruoning Li , Shuying Li , Yuxuan Lin , Mengxi Liu , Peinian Liu , Yanyan Liu , Jingtao Lü , Chuanxu Ma , Haoyang Pan , JinLiang Pan , Minghu Pan , Xiaohui Qiu , Ziyong Shen , Shijing Tan , Bing Wang , Dong Wang , Li Wang , Lili Wang , Tao Wang , Xiang Wang , Xingyue Wang , Xueyan Wang , Yansong Wang , Yu Wang , Kai Wu , Wei Xu , Na Xue , Linghao Yan , Fan Yang , Zhiyong Yang , Chi Zhang , Xue Zhang , Yang Zhang , Yao Zhang , Xiong Zhou , Junfa Zhu , Yajie Zhang , Feixue Gao , Yongfeng Wang . Recent progress on surface chemistry Ⅰ: Assembly and reaction. Chinese Chemical Letters, 2024, 35(12): 110055-. doi: 10.1016/j.cclet.2024.110055
11. [11]
  Xin Li , Zhen Xu , Donglei Bu , Jinming Cai , Huamei Chen , Qi Chen , Ting Chen , Fang Cheng , Lifeng Chi , Wenjie Dong , Zhenchao Dong , Shixuan Du , Qitang Fan , Xing Fan , Qiang Fu , Song Gao , Jing Guo , Weijun Guo , Yang He , Shimin Hou , Ying Jiang , Huihui Kong , Baojun Li , Dengyuan Li , Jie Li , Qing Li , Ruoning Li , Shuying Li , Yuxuan Lin , Mengxi Liu , Peinian Liu , Yanyan Liu , Jingtao Lü , Chuanxu Ma , Haoyang Pan , JinLiang Pan , Minghu Pan , Xiaohui Qiu , Ziyong Shen , Qiang Sun , Shijing Tan , Bing Wang , Dong Wang , Li Wang , Lili Wang , Tao Wang , Xiang Wang , Xingyue Wang , Xueyan Wang , Yansong Wang , Yu Wang , Kai Wu , Wei Xu , Na Xue , Linghao Yan , Fan Yang , Zhiyong Yang , Chi Zhang , Xue Zhang , Yang Zhang , Yao Zhang , Xiong Zhou , Junfa Zhu , Yajie Zhang , Feixue Gao , Li Wang . Recent progress on surface chemistry Ⅱ: Property and characterization. Chinese Chemical Letters, 2025, 36(1): 110100-. doi: 10.1016/j.cclet.2024.110100
12. [12]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
13. [13]
  Yujuan Zhao , Zaiwang Zhao . Monolayer mesoporous nanosheets with surface asymmetry via a dual-emulsion-directed monomicelle assembly. Chinese Journal of Structural Chemistry, 2024, 43(2): 100238-100238. doi: 10.1016/j.cjsc.2024.100238
14. [14]
  Yingxiao Zong , Yangfei Wei , Xiaoqing Liu , Junke Wang , Huanfang Guo , Junli Wang , Zhuangzhi Shi , Tao Tu , Cheng Yang , Chongyang Wang , Leyong Wang . The 4^th CCL Organic Chemistry Forum held in Zhangye. Chinese Chemical Letters, 2024, 35(8): 109743-. doi: 10.1016/j.cclet.2024.109743
15. [15]
  Shaohua Zhang , Liyao Liu , Yingqiao Ma , Chong-an Di . Advances in theoretical calculations of organic thermoelectric materials. Chinese Chemical Letters, 2024, 35(8): 109749-. doi: 10.1016/j.cclet.2024.109749
16. [16]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
17. [17]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
18. [18]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
19. [19]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
20. [20]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(656)
HTML views(45)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142