Citation: Yang Guogang, Wu Hao, Wei Junying, Zheng Jueting, Chen Zhaobin, Liu Junyang, Shi Jia, Yang Yang, Hong Wenjing. Quantum interference effect in the charge transport through single-molecule benzene dithiol junction at room temperature: An experimental investigation[J]. Chinese Chemical Letters, ;2018, 29(1): 147-150. doi: 10.1016/j.cclet.2017.06.015 shu

Quantum interference effect in the charge transport through single-molecule benzene dithiol junction at room temperature: An experimental investigation

State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, China

Corresponding author: Liu Junyang, jyliu@xmu.edu.cn Yang Yang, yangyang@xmu.edu.cn Hong Wenjing, whong@xmu.edu.cn
Received Date: 9 May 2017
Revised Date: 25 May 2017
Accepted Date: 9 June 2017
Available Online: 12 January 2017

Figures(4)

The quantum interference effect in the charge transport through single-phenyl molecules received intensive interests from theory but remained as an experimental challenge. In this paper, we investigated the charge transport through single-molecule benzene dithiol (BDT) junction with different connectivities using mechanically controllable break junction (MCBJ) technique. By further improving the mechanical stability and the electronic measuring component of the MCBJ set-up, we obtained the conductance histograms of BDT molecules (BDTs) from the statistical analysis of conductance-distance traces without data selection. By tuning the connectivity, the conductance of BDTs is determined to be 10^-1.2 G₀, 10^-2.2 G₀ and 10^-1.0 G₀ for para, meta, and ortho connectivity, following the trend that ortho-BDT > para-BDT > meta-BDT. Furthermore, the displacements of the junctions followed the trend that para > meta > ortho, suggesting the charge transport through the molecules via the gold-thiol bond. The different trends between conductance and displacement for different connectivities suggests the presence of destructive quantum interference effect on meta-BDT, which provides the experimental evidence for the quantum interference effect through single-phenyl molecular junctions.
- Quantum interference,
- Single-molecule conductance,
- Benzene dithiol,
- Different connectivity,
- Mechanically controllable break junction
1. [1]
  T.A. Su, M. Neupane, M.L. Steigerwald, L. Venkataraman, C. Nuckolls, Nat. Rev. Mater. 1(2016) 16002. doi: 10.1038/natrevmats.2016.2
2. [2]
  C.J. Lambert, Chem. Soc. Rev. 44(2015) 875-888. doi: 10.1039/C4CS00203B
3. [3]
  S.V. Aradhya, L. Venkataraman, Nat. Nanotechnol. 8(2013) 399-410. doi: 10.1038/nnano.2013.91
4. [4]
  T. Markussen, R. Stadler, K.S. Thygesen, Nano Lett. 10(2010) 4260-4265. doi: 10.1021/nl101688a
5. [5]
  W. Hong, H. Valkenier, G. Mészáros, et al., Beilstein J. Nanotechnol. 2(2011) 699-713. doi: 10.3762/bjnano.2.76
6. [6]
  A. Saraiva-Souza, M. Smeu, L. Zhang, et al., J. Am. Chem. Soc.136(2014) 15065-15071. doi: 10.1021/ja508537n
7. [7]
  V. Kaliginedi, P. Moreno-García, H. Valkenier, et al., J. Am. Chem. Soc.134(2012) 5262-5275. doi: 10.1021/ja211555x
8. [8]
  C.M. Guedon, H. Valkenier, T. Markussen, et al., Nat. Nanotechnol. 7(2012) 305-309. doi: 10.1038/nnano.2012.37
9. [9]
  H. Vazquez, R. Skouta, S. Schneebeli, et al., Nat. Nanotechnol. 7(2012) 663-667. doi: 10.1038/nnano.2012.147
10. [10]
  S. Ballmann, R. Härtle, P.B. Coto, et al., Phys. Rev. Lett. 109(2012) 056801. doi: 10.1103/PhysRevLett.109.056801
11. [11]
  D.Z. Manrique, C. Huang, M. Baghernejad, et al., Nat. Commun. 6(2015) 6389. doi: 10.1038/ncomms7389
12. [12]
  C.R. Arroyo, S. Tarkuc, R. Frisenda, et al., Angew. Chem. Int. Ed. 52(2013) 3152-3155. doi: 10.1002/anie.201207667
13. [13]
  S.V. Aradhya, J.S. Meisner, M. Krikorian, et al., Nano Lett. 12(2012) 1643-1647. doi: 10.1021/nl2045815
14. [14]
  J. Xia, B. Capozzi, S. Wei, et al., Nano Lett. 14(2014) 2941-2945. doi: 10.1021/nl5010702
15. [15]
  F. Schwarz, M. Koch, G. Kastlunger, et al., Angew. Chem. Int. Ed. 55(2016) 11781-11786. doi: 10.1002/anie.201605559
16. [16]
  X. Liu, S. Sangtarash, D. Reber, et al., Angew. Chem. Int. Ed. 56(2017) 173-176. doi: 10.1002/anie.v56.1
17. [17]
  R. Frisenda, V.A.E.C. Janssen, F.C. Grozema, H.S.J. van der Zant, N. Renaud, Nat. Chem. 8(2016) 1099-1104. doi: 10.1038/nchem.2588
18. [18]
  C.A. Martin, D. Ding, J.K. Sørensen, et al., J. Am. Chem. Soc. 130(2008) 13198-13199. doi: 10.1021/ja804699a
19. [19]
  Y. Kim, T. Pietsch, A. Erbe, W. Belzig, E. Scheer, Nano Lett. 11(2011) 3734-3738. doi: 10.1021/nl201777m
20. [20]
  C. Bruot, J. Hihath, N. Tao, Nat. Nanotechnol. 7(2012) 35-40. doi: 10.1038/nnano.2011.212
21. [21]
  Y. Yang, J. Liu, S. Feng, et al., Nano Res. 9(2016) 560-570. doi: 10.1007/s12274-015-0937-1
22. [22]
  J.T. Zheng, R.W. Yan, J.H. Tian, et al., Electrochim. Acta 200(2016) 268-275. doi: 10.1016/j.electacta.2016.03.129
23. [23]
  L.Y. Hsu, B.Y. Jin, Chem. Phys. 355(2009) 177-182. doi: 10.1016/j.chemphys.2008.12.015
24. [24]
  W. Hong, D.Z. Manrique, P. Moreno-García, et al., J. Am. Chem. Soc. 134(2012) 2292-2304. doi: 10.1021/ja209844r
25. [25]
  M. Kiguchi, H. Nakamura, Y. Takahashi, T. Takahashi, T. Ohto, J. Phys. Chem. C 114(2010) 22254-22261. doi: 10.1021/jp1095079
26. [26]
  S.Y. Quek, M. Kamenetska, M.L. Steigerwald, et al., Nat. Nanotechnol. 4(2009) 230-234. doi: 10.1038/nnano.2009.10
27. [27]
  A.I. Yanson, G.R. Bollinger, H.E. van den Brom, N. Agrait, J.M. van Ruitenbeek, Nature 395(1998) 783-785. doi: 10.1038/27405
28. [28]
  M.A. Reed, C. Zhou, C.J. Muller, T.P. Burgin, J.M. Tour, Science 278(1997) 252-254. doi: 10.1126/science.278.5336.252
29. [29]
  L. Venkataraman, J.E. Klare, I.W. Tam, et al., Nano Lett. 6(2006) 458-462. doi: 10.1021/nl052373+
30. [30]
  J.P. Bergfield, C.A. Stafford, Nano Lett. 9(2009) 3072-3076. doi: 10.1021/nl901554s
31. [31]
  Y. Tsuji, A. Staykov, K. Yoshizawa, J. Am. Chem. Soc. 133(2011) 5955-5965. doi: 10.1021/ja111021e
32. [32]
  G.C. Solomon, D.Q. Andrews, R.H. Goldsmith, et al., J. Am. Chem. Soc. 130(2008) 17301-17308. doi: 10.1021/ja8044053
1. [1]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
2. [2]
  Xinyi Luo , Ke Wang , Yingying Xue , Xiaobao Cao , Jianhua Zhou , Jiasi Wang . Digital PCR-free technologies for absolute quantitation of nucleic acids at single-molecule level. Chinese Chemical Letters, 2025, 36(2): 109924-. doi: 10.1016/j.cclet.2024.109924
3. [3]
  Hao Wang , Meng-Qi Pan , Ya-Fei Wang , Chao Chen , Jian Xu , Yuan-Yuan Gao , Chuan-Song Qi , Wei Li , Xian-He Bu . Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes. Chinese Chemical Letters, 2024, 35(10): 109581-. doi: 10.1016/j.cclet.2024.109581
4. [4]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
5. [5]
  Caihong Mao , Yanfeng He , Xiaohan Wang , Yan Cai , Xiaobo Hu . Synthesis and molecular recognition characteristics of a tetrapodal benzene cage. Chinese Chemical Letters, 2024, 35(8): 109362-. doi: 10.1016/j.cclet.2023.109362
6. [6]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
7. [7]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
8. [8]
  Yu Hong , Yuqian Jiang , Chenhuan Yuan , Decai Wang , Yimeng Sun , Jian Jiang . Unraveling temperature-dependent supramolecular polymorphism of naphthalimide-substituted benzene-1,3,5-tricarboxamide derivatives. Chinese Chemical Letters, 2024, 35(12): 109909-. doi: 10.1016/j.cclet.2024.109909
9. [9]
  Ruonan Guo , Heng Zhang , Changsheng Guo , Ningqing Lv , Beidou Xi , Jian Xu . Degradation of neonicotinoids with different molecular structures in heterogeneous peroxymonosulfate activation system through different oxidation pathways. Chinese Chemical Letters, 2024, 35(9): 109413-. doi: 10.1016/j.cclet.2023.109413
10. [10]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
11. [11]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
12. [12]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
13. [13]
  Yuqing Wang , Zhemin Li , Qingjun Lu , Qizhao Li , Jiaxin Luo , Chengjie Li , Yongshu Xie . Solar cells based on doubly concerted companion dyes with the efficiencies modulated by inserting an ethynyl group at different positions. Chinese Chemical Letters, 2024, 35(5): 109093-. doi: 10.1016/j.cclet.2023.109093
14. [14]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
15. [15]
  Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS₂ on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717
16. [16]
  Xiaoning Li , Quanyu Shi , Meng Li , Ningxin Song , Yumeng Xiao , Huining Xiao , Tony D. James , Lei Feng . Functionalization of cellulose carbon dots with different elements (N, B and S) for mercury ion detection and anti-counterfeit applications. Chinese Chemical Letters, 2024, 35(7): 109021-. doi: 10.1016/j.cclet.2023.109021
17. [17]
  Kun Liu , Yulin Cong , Xiongfeng Luo , Meicun Yao , Zhiyong Xie , Hao Li . Utilizing bivalent aptamers as first DNA agonist to activate RTKs heterodimer of different families. Chinese Chemical Letters, 2025, 36(1): 109839-. doi: 10.1016/j.cclet.2024.109839
18. [18]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
19. [19]
  Boran Cheng , Lei Cao , Chen Li , Fang-Yi Huo , Qian-Fang Meng , Ganglin Tong , Xuan Wu , Lin-Lin Bu , Lang Rao , Shubin Wang . Fluorine-doped carbon quantum dots with deep-red emission for hypochlorite determination and cancer cell imaging. Chinese Chemical Letters, 2024, 35(6): 108969-. doi: 10.1016/j.cclet.2023.108969
20. [20]
  Peide Zhu , Yangjia Liu , Yaoyao Tang , Siqi Zhu , Xinyang Liu , Lei Yin , Quan Liu , Zhiqiang Yu , Quan Xu , Dixian Luo , Juncheng Wang . Bi-doped carbon quantum dots functionalized liposomes with fluorescence visualization imaging for tumor diagnosis and treatment. Chinese Chemical Letters, 2024, 35(4): 108689-. doi: 10.1016/j.cclet.2023.108689

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(697)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142