Citation: Liu Liwei, Xiao Wende, Mao Jinhai, Zhang Haigang, Jiang Yuhang, Zhou Haitao, Yang Kai, Gao Hongjun. Densely packed overlayer of iron phthalocyanine molecules grown on single-layer graphene[J]. Chinese Chemical Letters, ;2018, 29(1): 183-186. doi: 10.1016/j.cclet.2017.06.012 shu

Densely packed overlayer of iron phthalocyanine molecules grown on single-layer graphene

Liu Liwei ^a ,
Xiao Wende ^a,b,, ,
Mao Jinhai ^a ,
Zhang Haigang ^a ,
Jiang Yuhang ^a ,
Zhou Haitao ^a ,
Yang Kai ^a ,
Gao Hongjun ^a,,

a.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
b.
Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Xiao Wende, wdxiao@bit.edu.cn Gao Hongjun, hjgao@iphy.ac.cn
Received Date: 17 March 2017
Revised Date: 24 April 2017
Accepted Date: 7 June 2017
Available Online: 9 January 2017

Figures(4)

The formation of densely packed overlayer of iron phthalocyanine (FePc) molecules on single-layer graphene (SLG) epitaxially grown on Ru(0001) is studied by means of low temperature scanning tunneling microscopy. We show that the FePc molecules form single molecular arrays, ordered honeycomb lattice, Kagome lattice and square lattice with increasing molecular coverage. The densely packed square lattice of the molecular layer is modulated by the moiré pattern of SLG/Ru(0001). The superposition of the square lattice of the molecular layer on the hexagonal lattice of SLG moiré pattern leads to the formation of a larger strip moiré pattern. This coverage-dependent self-assembling behavior of FePc on SLG/Ru(0001) is mainly driven by the inhomogeneous electronic structure of graphene moiré pattern, due to spatial-dependent interfacial charge transfer between SLG and Ru(0001) substrate.
- Self-assembly,
- Coverage-dependent,
- Metal phthalocyanine,
- Graphene,
- Scanning tunneling microscopy
1. [1]
  J.V. Barth, G. Costantini, K. Kern, Nature 437(2005) 671-679. doi: 10.1038/nature04166
2. [2]
  C. Joachim, J.K. Gimzewski, A. Aviram, Nature 408(2000) 541-548. doi: 10.1038/35046000
3. [3]
  T. Yokoyama, S. Yokoyama, T. Kamikado, Y. Okuno, S. Mashiko, Nature 413(2001) 619-621. doi: 10.1038/35098059
4. [4]
  H.J. Gao, L. Gao, Prog. Surf. Sci. 85(2010) 28-91. doi: 10.1016/j.progsurf.2009.10.001
5. [5]
  K.J. Franke, G. Schulze, J.I. Pascual, Science 332(2011) 940-944. doi: 10.1126/science.1202204
6. [6]
  Y.S. Fu, S.H. Ji, X. Chen, et al., Phys. Rev. Lett. 99(2007) 256601. doi: 10.1103/PhysRevLett.99.256601
7. [7]
  L. Gao, W. Ji, Y.B. Hu, et al., Phys. Rev. Lett. 99(2007) 106402. doi: 10.1103/PhysRevLett.99.106402
8. [8]
  J. Mao, H. Zhang, Y. Jiang, et al., J. Am. Chem. Soc. 131(2009) 14136-14137. doi: 10.1021/ja904907z
9. [9]
  Y.F. Wang, J. Kroger, R. Berndt, W.A. Hofer, J. Am. Chem. Soc. 131(2009) 3639-3643. doi: 10.1021/ja807876c
10. [10]
  A.D. Zhao, Q.X. Li, L. Chen, et al., Science 309(2005) 1542-1544. doi: 10.1126/science.1113449
11. [11]
  L. Gao, Q. Liu, Y.Y. Zhang, et al., Phys. Rev. Lett. 101(2008) 197209. doi: 10.1103/PhysRevLett.101.197209
12. [12]
  J.M. Gottfried, Surf. Sci. Rep. 70(2015) 259-379. doi: 10.1016/j.surfrep.2015.04.001
13. [13]
  W. Auwarter, D. Ecija, F. Klappenberger, J.V. Barth, Nat. Chem. 7(2015) 105-120. doi: 10.1038/nchem.2159
14. [14]
  J. Ahlund, J. Schnadt, K. Nilson, et al., Surf. Sci. 601(2007) 3661-3667. doi: 10.1016/j.susc.2007.06.008
15. [15]
  Z.H. Cheng, L. Gao, Z.T. Deng, et al., J. Phys. Chem. C 111(2007) 2656-2660. doi: 10.1021/jp0660738
16. [16]
  H. Karacuban, M. Lange, J. Schaffert, et al., Surf. Sci. 603(2009) L39-L43. doi: 10.1016/j.susc.2009.01.029
17. [17]
  X. Lu, K.W. Hipps, X.D. Wang, U. Mazur, J. Am. Chem. Soc. 118(1996) 7197-7202. doi: 10.1021/ja960874e
18. [18]
  A. Scarfato, S.H. Chang, S. Kuck, et al., Surf. Sci. 602(2008) 677-683. doi: 10.1016/j.susc.2007.11.011
19. [19]
  L. Liu, K. Yang, Y. Jiang, et al., Sci. Rep. 3(2013) 1210. doi: 10.1038/srep01210
20. [20]
  L. Liu, K. Yang, Y. Jiang, et al., Phys. Rev. Lett. 114(2015) 126601.
21. [21]
  H. Dil, J. Lobo-Checa, R. Laskowski, et al., Science 319(2008) 1824-1826. doi: 10.1126/science.1154179
22. [22]
  L. Liu, T. Dienel, R. Widmer, O. Gröning, ACS Nano 9(2015) 10125-10132. doi: 10.1021/acsnano.5b03741
23. [23]
  I.P. Hong, N. Li, Y.J. Zhang, et al., Chem. Commun. 52(2016) 10338-10341. doi: 10.1039/C6CC03359H
24. [24]
  K.S. Novoselov, A.K. Geim, S.V. Morozov, et al., Science 306(2004) 666-669. doi: 10.1126/science.1102896
25. [25]
  Y. Pan, H.G. Zhang, D.X. Shi, et al., Adv. Mater. 21(2009) 2777. doi: 10.1002/adma.200800761
26. [26]
  H. Zhang, W.D. Xiao, J. Mao, et al., J. Phys. Chem. C 116(2012) 11091-11095. doi: 10.1021/jp3020244
27. [27]
  H.G. Zhang, J.T. Sun, T. Low, et al., Phys. Rev. B 84(2011) 245436. doi: 10.1103/PhysRevB.84.245436
28. [28]
  Y. Pan, D.X. Shi, H.J. Gao, Chin. Phys. 16(2007) 3151-3153. doi: 10.1088/1009-1963/16/11/001
29. [29]
  H.G. Zhang, H. Hu, Y. Pan, et al., J. Phys.:Condens. Matter 22(2010) 302001. doi: 10.1088/0953-8984/22/30/302001
30. [30]
  W. Dou, S. Huang, R.Q. Zhang, C.S. Lee, J. Chem. Phys. 134(2011) 094705. doi: 10.1063/1.3561398
31. [31]
  M. Bazarnik, J. Brede, R. Decker, R. Wiesendanger, ACS Nano 7(2013) 11341-11349. doi: 10.1021/nn405172q
32. [32]
  P. Jarvinen, S.K. Hamalainen, K. Banerjee, et al., Nano Lett. 13(2013) 3199-3204. doi: 10.1021/nl401265f
33. [33]
  K. Yang, W.D. Xiao, Y.H. Jiang, et al., J. Phys. Chem. C 116(2012) 14052-14056. doi: 10.1021/jp304068a
1. [1]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
2. [2]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
3. [3]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
4. [4]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
5. [5]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
6. [6]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
7. [7]
  Jingqi Xin , Shupeng Han , Meichen Zheng , Chenfeng Xu , Zhongxi Huang , Bin Wang , Changmin Yu , Feifei An , Yu Ren . A nitroreductase-responsive nanoprobe with homogeneous composition and high loading for preoperative non-invasive tumor imaging and intraoperative guidance. Chinese Chemical Letters, 2024, 35(7): 109165-. doi: 10.1016/j.cclet.2023.109165
8. [8]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
9. [9]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
10. [10]
  Xian Yan , Huawei Xie , Gao Wu , Fang-Xing Xiao . Boosted solar water oxidation steered by atomically precise alloy nanocluster. Chinese Chemical Letters, 2025, 36(1): 110279-. doi: 10.1016/j.cclet.2024.110279
11. [11]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805
12. [12]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
13. [13]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
14. [14]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
15. [15]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
16. [16]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060
17. [17]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
18. [18]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
19. [19]
  Wei Su , Xiaoyan Luo , Peiyuan Li , Ying Zhang , Chenxiang Lin , Kang Wang , Jianzhuang Jiang . Phthalocyanine self-assembled nanoparticles for type Ⅰ photodynamic antibacterial therapy. Chinese Chemical Letters, 2024, 35(12): 109522-. doi: 10.1016/j.cclet.2024.109522
20. [20]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(664)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142