Citation: Li Huanmin, Xie Xu-Ming. Polyolefin-functionalized graphene oxide and its GO/HDPE nanocomposite with excellent mechanical properties[J]. Chinese Chemical Letters, ;2018, 29(1): 161-165. doi: 10.1016/j.cclet.2017.06.001 shu

Polyolefin-functionalized graphene oxide and its GO/HDPE nanocomposite with excellent mechanical properties

Li Huanmin ,
Xie Xu-Ming ^,

Laboratory of Advanced Materials(MOE), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Xie Xu-Ming, xxm-dce@mail.tsinghua.edu.cn
Received Date: 28 March 2017
Revised Date: 24 April 2017
Accepted Date: 2 June 2017
Available Online: 3 January 2017

Figures(5)

To prepare GO/Polyolefin nanocomposites with enhanced mechanical, electrical, or thermal properties is still a challenge due to the poor interfacial adhesion between GO and non-polar polyolefins. In this study, we report an effective strategy for the polyolefin-functionalized graphene oxide (fGO) using two-step methods GO was firstly modified by using glycidyl methacrylate (GMA) and styrene (St) dual monomers grafting method, thus GO-g-(GMA-co-St) with numerous epoxide groups is obtained. Then through the reaction between the epoxide group of GMA and anhydride group of maleic anhydrides (MAH) of the prepared HDPE-g-(MAH-co-St), GO-g-HDPE-g-(MAH-co-St) could be obtained. The successful preparation of the GO-g-HDPE-g-(MAH-co-St) was confirmed by AFM, TEM, FTIR, XRD, DSC, and TGA characterization. The results show the grafting ratios of the poly(GMA-co-St) and HDPE-g-(MAH-co-St) being up to 50.4 wt% and 70.4 wt%, respectively. The functionalized GO shows homogeneous dispersion in the nanocomposites with HDPE, and the stress at break and strain at break of the nanocomposite is increased by 28.7% and 130% respectively with only 0.2 wt% fGO loading. The approach of the polyolefin-functionalized GO paves a new way to develop not only polyolefin/graphene nanocomposites but also excellent nanocomposites of polyolefin/engineering plastic blends with graphene.
- Graphene oxide,
- Polyolefin-functionalized,
- Homogeneous dispersion
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