Citation: Chi Shuai-Jie, Chen Liang, Li Hong-Xiang, Liu Jian-Gang, Yu Xin-Hong, Han Yan-Chun. To improve alignment of isoindigo-based conjugated polymer film by controlling contact line receding velocity[J]. Chinese Chemical Letters, ;2017, 28(8): 1663-1669. doi: 10.1016/j.cclet.2017.05.021 shu

To improve alignment of isoindigo-based conjugated polymer film by controlling contact line receding velocity

Chi Shuai-Jie ^a,b ,
Chen Liang ^a,b ,
Li Hong-Xiang ^a,b ,
Liu Jian-Gang ^a,, ,
Yu Xin-Hong ^a ,
Han Yan-Chun ^a,,

a.
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of the Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Liu Jian-Gang, niitawh@ciac.ac.cn Han Yan-Chun, ychan@ciac.ac.cn
Received Date: 8 January 2017
Revised Date: 19 April 2017
Accepted Date: 27 April 2017
Available Online: 25 August 2017

Figures(9)

The macroscopic alignment of conjugated polymers with low grain boundary is essential to carrier transport. During film forming process, the match between contact line receding velocity and the critical alignment velocity is essential to get the alignment polymer film. In this paper, the contact line receding velocity of a D-A conjugated polymer film, isoindigo and bithiophene (ⅡDDT-C3), was adjusted by solvent vapor content and film-formation temperature. Only when solvent vapor content was 0.3 mL and the film-formation temperature was 90℃, the contact line receding velocity was in accordance with the critical alignment velocity, and the highest degree of alignment was attained in the ⅡDDT-C3 film, with the dichroic ratio up to 4.08. Fibers were aligned parallel with the direction of the contact line receding and the molecules of ⅡDDT-C3 adopted an edge-on orientation with the backbone parallel with the direction of fiber long axis. The π-π stacking distance between adjacent molecules was 3.63 Å.
- ⅡD-based conjugated polymers Alignment,
- Contact line receding velocity,
- Critical alignment velocity
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