Citation: Du Ying, Shen Yang-Bin, Zhan Yu-Lu, Ning Fan-Di, Yan Liu-Ming, Zhou Xiao-Chun. Highly active iridium catalyst for hydrogen production from formic acid[J]. Chinese Chemical Letters, ;2017, 28(8): 1746-1750. doi: 10.1016/j.cclet.2017.05.018 shu

Highly active iridium catalyst for hydrogen production from formic acid

Du Ying ^a,b ,
Shen Yang-Bin ^b,c ,
Zhan Yu-Lu ^a,b ,
Ning Fan-Di ^b,d ,
Yan Liu-Ming ^a ,
Zhou Xiao-Chun ^b,,

a.
Department of Chemistry, Shanghai University, Shanghai 200444, China
b.
Division of Advanced Nanomaterials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China
d.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: Zhou Xiao-Chun, xczhou2013@sinano.ac.cn
Received Date: 7 February 2017
Revised Date: 23 March 2017
Accepted Date: 27 April 2017
Available Online: 20 August 2017

Figures(6)

Formic acid (FA) dehydrogenation has attracted a lot of attentions since it is a convenient method for H₂ production. In this work, we designed a self-supporting fuel cell system, in which H₂ from FA is supplied into the fuel cell, and the exhaust heat from the fuel cell supported the FA dehydrogenation. In order to realize the system, we synthesized a highly active and selective homogeneous catalyst IrCp^*Cl₂bpym for FA dehydrogenation. The turnover frequency (TOF) of the catalyst for FA dehydrogenation is as high as 7150 h^-1 at 50 ℃, and is up to 144, 000 h^-1 at 90 ℃. The catalyst also shows excellent catalytic stability for FA dehydrogenation after several cycles of test. The conversion ratio of FA can achieve 93.2%, and no carbon monoxide is detected in the evolved gas. Therefore, the evolved gas could be applied in the proton exchange membrane fuel cell (PEMFC) directly. This is a potential technology for hydrogen storage and generation. The power density of the PEMFC driven by the evolved gas could approximate to that using pure hydrogen.
- Formic acid,
- Hydrogen generation,
- Homogeneous catalyst,
- Catalytic performance,
- Proton exchange membrane fuel cell
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