Citation: Fu Li-Na, Leng Bing, Li Yong-Sheng, Gao Xi-Ke. Photoresponsive n-channel organic field-effect transistors based on a tri-component active layer[J]. Chinese Chemical Letters, ;2018, 29(1): 175-178. doi: 10.1016/j.cclet.2017.05.014 shu

Photoresponsive n-channel organic field-effect transistors based on a tri-component active layer

Fu Li-Na ^a,b ,
Leng Bing ^b,, ,
Li Yong-Sheng ^a,, ,
Gao Xi-Ke ^b,,

a.
Laboratory of Low-Dimensional Materials Chemistry, Key Laboratory for Ultrafine Materials of the Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Corresponding author: Leng Bing, lengbing@sioc.ac.cn Li Yong-Sheng, ysli@ecust.edu.cn Gao Xi-Ke, gaoxk@sioc.ac.cn
Received Date: 6 April 2017
Revised Date: 9 May 2017
Accepted Date: 15 May 2017
Available Online: 18 January 2017

Figures(5)

Introducing photochromic molecules into the active layer of organic field-effect transistors (OFETs) is a direct way to implement a photoresponse nature in OFETs. However, active layer blended photoresponsive transistors based on n-type semiconductors are challenging and rarely studied, which are crucial for multifunctional organic-based logic applications. Herein, we fabricated n-channel photoresponsive OFETs based on a tri-component active layer spin-coated from the mixed solution of an n-type semiconductor (NDI2OD-DTYM2), spiropyran and polystyrene with a weight ratio of 1:1:1. The morphology of the blended films was improved by the introduction of the polymer matrix. Photochromic spiropyran molecules dispersed in the semiconductor layer could switch between the closed-ring state and ionic open-ring state flexibly under the irradiation of different wavelengths of light, and thus change the channel conductivity reversibly and modulate the OFET characteristics. Therefore, under the irradiation of alternate UV and vis light, both the device carrier mobility and current on and off ratio successfully realized a reversible switch.
- Organic field-effect transistors,
- Photoresponse,
- n-Type organic semiconductor,
- Spiropyran,
- Polystyrene
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