Citation: Bian Hang, Dong Xiaozhe, Chen Shanshan, Dong Dewen, Zhang Ning. Polymer brushes on hydrogen-terminated silicon substrates via stable Si-C bond[J]. Chinese Chemical Letters, ;2018, 29(1): 171-174. doi: 10.1016/j.cclet.2017.05.011 shu

Polymer brushes on hydrogen-terminated silicon substrates via stable Si-C bond

a.
School of Material Science and Engineering, Jilin Jianzhu University, Changchun 130118, China
b.
Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: Zhang Ning, ning.zhang@ciac.ac.cn
Received Date: 26 April 2017
Revised Date: 10 May 2017
Accepted Date: 11 May 2017
Available Online: 12 January 2017

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We demonstrate a straightforward and efficient method for the creation of polymer brushes on hydrogen-terminated silicon substrates through the UV-induced photopolymerization. The surface grafting polymerization is applicable to a series of monomers, allowing the direct formation of homogeneous polymer coatings ranging from hydrophilic poly(2-isopropenyl-2-oxazoline) (PIPOx), amphiphilic poly(N-isopropyl acrylamide) (PNIPAM), to hydrophobic polystyrene (PS) and poly(4-(1H, 1H, 2H, 2H-perfluorohexyl)oxymethylstyrene) (PPHMS) on Si(100) and Si(111) surfaces via stable Si-C bonds. Polymerization kinetic investigation indicates a linear increase of polymer layer thickness with the polymerization time. Moreover, the as-prepared polymer brushes exhibit superior stability against basic conditions in contrast to those that were formed on silicon substrates via conventional Si-O-C bond.
- Polymer brushes,
- Silicon substrates,
- SIPGP,
- Surface wettability,
- Surface functionalization
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1.
沈阳化工大学材料科学与工程学院沈阳 110142