Citation: Ma Yingxue, Lu Lux, Zhang Li, Liu Minghua, Guo Yuan, Lu Zhou. Effect of acidity on morphologies and photodimerization kinetics in Langmuir-Blodgett monolayers of styrylquinoline derivatives[J]. Chinese Chemical Letters, ;2017, 28(6): 1285-1289. doi: 10.1016/j.cclet.2017.05.006 shu

Effect of acidity on morphologies and photodimerization kinetics in Langmuir-Blodgett monolayers of styrylquinoline derivatives

Ma Yingxue ^a,b ,
Lu Lux ^c ,
Zhang Li ^a ,
Liu Minghua ^a ,
Guo Yuan ^a,b ,
Lu Zhou ^a,b,,

a.
Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy Sciences, Beijing 100049, China
c.
National Center for Nanoscience and Technology, Beijing 100190, China

Corresponding author: Lu Zhou, zhoulu@iccas.ac.cn
Received Date: 19 April 2017
Revised Date: 2 May 2017
Accepted Date: 5 May 2017
Available Online: 2 June 2017

Figures(6)

The real-time second harmonic generation was employed to investigate the[2+2] photodimerization of styrylquinoline (SQ) derivatives in Langmuir-Blodgett (LB) monolayers deposited from aqueous subphases with different acidity. It was discovered that the photodimerization rate constant significantly decreased upon the addition of acid. The additional atomic force microscopy measurements revealed that surface morphologies were correlated to the photodimerization kinetics. These experimental results provide direct evidence for the topo-chemical mechanisms of[2+2] photodimerization in LB films. The current study demonstrates that the intermolecular interactions and aggregation structures play important roles in the photochemical properties at surfaces.
- Second harmonic generation,
- Photodimerization,
- Langmuir-Blodgett monolayers,
- Topo-chemical reaction,
- Acidity effect
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