Citation: Yin Bangshao, Liang Xu, Zhu Weihua, Xu Ling, Zhou Mingbo, Song Jianxin. β to β Terpyridylene-bridged porphyrin nanorings[J]. Chinese Chemical Letters, ;2018, 29(1): 99-101. doi: 10.1016/j.cclet.2017.05.003 shu

β to β Terpyridylene-bridged porphyrin nanorings

Yin Bangshao ^a ,
Liang Xu ^b ,
Zhu Weihua ^b ,
Xu Ling ^a ,
Zhou Mingbo ^a ,
Song Jianxin ^a,,

a.
Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research(Ministry of Education of China), Key Laboratory of the Assembly and Application of Organic Functional Molecules, Hunan Normal University, Changsha 410081, China
b.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: Song Jianxin, jxsong@hunnu.edu.cn; jxsong@hotmail.com
Received Date: 28 February 2017
Revised Date: 1 April 2017
Accepted Date: 5 May 2017
Available Online: 11 January 2017

Figures(4)

6, 6"-Terpyridylene bridged cyclic porphyrin dimer 2Ni, trimer 3Ni, tetramer 4Ni and pentamer 5Ni were obtained through Suzuki-Miyaura coupling reaction of β, β'-diboryl Ni(Ⅱ) porphyrin with 6, 6"-dibromo-2, 2':6', 2"-terpyridine. Free base porphyrin nanorings 2H-5H were obtained by demetallation of 2Ni-5Ni with sulfuric acid in CHCl₃ and then were converted into 2Zn-5Zn upon treatment with Zn(OAc)₂ in quantitative yields, respectively. All of these newly synthesized porphyrin nanorings were characterized by high-resolution mass spectrometry and ¹H NMR spectroscopy. The photophysical properties of porphyrin nanoring were examined by UV-vis and fluorescence spectra. The electrochemical properties of 2Ni-5Ni were investigated by cyclic voltammetry and differential pulse voltammetry. The UV-vis absorption spectra and fluorescence spectra of these cyclic porphyrin arrays indicate that there exist unique electronic interactions between the constituent porphyrin units in each ring. Electrochemical analysis shows that the trimer 3Ni exhibit different redox behavior, which indicate that the porphyrin units in 3Ni are presumably more coplanar than in other cyclic porphyrin arrays.
- Crossing-coupling,
- Terpyridine,
- Nanoring,
- Porphyrin,
- Photophysical properties
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