Citation: Song Wei, Zhang Hai-Juan, Liu Ying-Hua, Ren Cui-Ling, Chen Hong-Li. A new fluorescence probing strategy for the detection of parathion-methyl based on N-doped carbon dots and methyl parathion hydrolase[J]. Chinese Chemical Letters, ;2017, 28(8): 1675-1680. doi: 10.1016/j.cclet.2017.05.001 shu

A new fluorescence probing strategy for the detection of parathion-methyl based on N-doped carbon dots and methyl parathion hydrolase

Song Wei ^a,b ,
Zhang Hai-Juan ^c ,
Liu Ying-Hua ^a,b ,
Ren Cui-Ling ^a,b,, ,
Chen Hong-Li ^a,b

a.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
b.
Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Lanzhou 730000, China
c.
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Corresponding author: Ren Cui-Ling, rencl@lzu.edu.cn
Received Date: 25 February 2017
Revised Date: 17 April 2017
Accepted Date: 4 May 2017
Available Online: 6 August 2017

Figures(6)

A new facile fluorescence probing strategy, which was based on N-doped carbon dots (NCDs) and methyl parathion hydrolase (MPH), was developed for the determination of parathion-methyl (PM). The fluorescence intensity of NCDs-MPH system was proportional to PM concentration in the range of 2.38-73.78 μmol/L, with a detection limit of 0.338 μmol/L. Moreover, the present simple and facile method could be used to determine methyl parathion in environmental and agricultural samples successfully. Furthermore, the detection mechanism of this system is inner filter effect and molecular interactions between NCDs and p-nitrophenol, which is the hydrolysis product of PM catalyzed by methyl parathion hydrolase.
- N-doped carbon dots,
- Parathion-methyl,
- Methyl parathion hydrolase,
- Inner filter effect,
- Fluorescence
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