Citation: Bi Mei-Xiang, Qian Peng, Wang Yu-Kang, Zha Zheng-Gen, Wang Zhi-Yong. Decarboxylative bromination of α, β-unsaturated carboxylic acids via an anodic oxidation[J]. Chinese Chemical Letters, ;2017, 28(6): 1159-1162. doi: 10.1016/j.cclet.2017.04.030 shu

Decarboxylative bromination of α, β-unsaturated carboxylic acids via an anodic oxidation

Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry & Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Zha Zheng-Gen, zgzha@ustc.edu.cn Wang Zhi-Yong, zwang3@ustc.edu.cn
Received Date: 14 February 2017
Revised Date: 19 April 2017
Accepted Date: 25 April 2017
Available Online: 29 June 2017

Figures(3)

A novel bromination of α, β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation. In this method, ammonium bromide was employed as a bromine source and the reaction features transition-metal-free, short time, and no additional supporting electrolyte.
- Decarboxylative bromination,
- α, β-Unsaturated carboxylic acids,
- Ammonium bromide,
- Anodic oxidation,
- Electro-oxidation
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