Citation: Alduhaish Osamah, Li Bin, Arman Hadi, Lin Rui-Biao, Zhao John Cong-Gui, Chen Banglin. A two-dimensional microporous metal-organic framework for highly selective adsorption of carbon dioxide and acetylene[J]. Chinese Chemical Letters, ;2017, 28(8): 1653-1658. doi: 10.1016/j.cclet.2017.04.025 shu

A two-dimensional microporous metal-organic framework for highly selective adsorption of carbon dioxide and acetylene

Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698, USA

Corresponding author: Lin Rui-Biao, ruibiao.lin@utsa.edu Chen Banglin, banglin.chen@utsa.edu
Received Date: 28 February 2017
Revised Date: 2 April 2017
Accepted Date: 12 April 2017
Available Online: 27 August 2017

Figures(5)

Solvothermal reaction of 3-aminoisonicotinic acid (Haina) and Cu(NO₃)₂·2.5H₂O gave a novel twodimensional (2D) microporous metal-organic framework, [Cu(aina)₂(DMF)]·DMF (1, DMF=N, N-dimethylformamide). Single-crystal X-ray crystallographic study of compound 1 revealed that Cu(Ⅱ) ions are linked by aina^- ligands forming square grid-like layers, which stack together via multiple hydrogen bonding interactions. The solvent-free framework of 1a displayed considerable porosity (void=46.5%) with one-dimensional (1D) open channels (4.7 Å×4.8 Å) functionalized by amino groups. Gas sorption measurements of 1 revealed selective carbon dioxide (CO₂) and acetylene (C₂H₂) adsorption over methane (CH₄) and nitrogen (N₂) at ambient temperature.
- Metal-organic frameworks,
- Two-dimensional structure,
- 3-Aminoisonicotinic acid,
- Hydrogen bonding,
- Gas separation,
- Acetylene
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