Citation: Liu Jing, Chen Qi-Wei, Wu Kai. On-surface construction of low-dimensional nanostructures with terminal alkynes: Linking strategies and controlling methodologies[J]. Chinese Chemical Letters, ;2017, 28(8): 1631-1639. doi: 10.1016/j.cclet.2017.04.022 shu

On-surface construction of low-dimensional nanostructures with terminal alkynes: Linking strategies and controlling methodologies

Liu Jing ^a,b,, ,
Chen Qi-Wei ^b ,
Wu Kai ^b,,

a.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China
b.
BNLMS, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Liu Jing, jingliu-pku@hotmail.com Wu Kai, kaiwu@pku.edu.cn
Received Date: 10 January 2017
Revised Date: 20 March 2017
Accepted Date: 17 April 2017
Available Online: 23 August 2017

Figures(9)

Bottom-up approach to constructing low-dimensional nanostructures on surfaces with terminal alkynes has drawn great interest because of its potential applications in fabricating advanced functional nanomaterials. The diversity of the achieved products manifests rich chemistry of terminal alkynes and hence careful linking strategies and proper controlling methodologies are required for selective preparations of high-quality target nanoarchitectures. This review summarizes various on-surface linking strategies for terminal alkynes, including non-bonding interactions as well as organometallic and covalent bonds, and presents examples to show effective control of surface assemblies and reactions of terminal alkynes by variations of the precursor structures, substrates and activation modes. Systematic studies of the on-surface linkage of terminal alkynes may help efficient and predictable preparations of surface nanomaterials and further understanding of surface chemistry.
- Terminal alkynes,
- On-surface reactions,
- Surface assemblies,
- Scanning tunneling microscopy,
- Low-dimensional nanostructures
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