Citation: Wang Qi, Wang Chen-Bin, Pang Fu-Qing, Lu Tian, Yin Hong-Quan, Chen Fu-Xue. Synthesis and characterization of functionalized 1, 3-bis(2-alkyltetrazol-5-yl)triazenes[J]. Chinese Chemical Letters, ;2017, 28(8): 1784-1787. doi: 10.1016/j.cclet.2017.04.006 shu

Synthesis and characterization of functionalized 1, 3-bis(2-alkyltetrazol-5-yl)triazenes

School of Chemistry & Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Chen Fu-Xue, fuxue.chen@bit.edu.cn
Received Date: 19 January 2017
Revised Date: 6 April 2017
Accepted Date: 7 April 2017
Available Online: 18 August 2017

Figures(3)

A series of 1, 3-bis(2-alkyltetrazol-5-yl)triazenes have been synthesized in high yields by treatment of sodium nitrite and hydrochloric acid with substituted-5-aminotetrazoles. All compounds were fully characterized using IR spectroscopy, ¹H NMR and ¹³C NMR spectroscopy and high resolution mass spectrometer (HRMS). Most of these triazenes exhibit good detonation performance comparable with TNT and low melting points ranging from 81 ℃ to 106 ℃, which are suitable for melt-cast explosives. Among these compounds, 1, 3-bis(2-azidoethyltetrazol-5-yl)triazene (2g) displays a low melting point (106 ℃), moderate onset decomposition temperature (183 ℃) and good detonation performance (D: 7087 m/s; P: 17.6 GPa).
- Melt-cast explosives,
- Tetrazoles,
- Bis(tetrazolyl)triazenes,
- Nitrogen-rich compounds,
- Detonation parameter
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