Citation: Lin Shu-Wei, Qian Wen-Hu, Huo Hong-Jing, Li Bao-Zong, Li Yi, Yang Yong-Gang. Preparation of optical active single-handed helical barium titanate nanotubes and characterization of dielectric properties[J]. Chinese Chemical Letters, ;2017, 28(5): 1111-1113. doi: 10.1016/j.cclet.2016.12.030 shu

Preparation of optical active single-handed helical barium titanate nanotubes and characterization of dielectric properties

Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Corresponding author: Yang Yong-Gang, ygyang@suda.edu.cn
Received Date: 17 November 2016
Revised Date: 6 December 2016
Accepted Date: 15 December 2016
Available Online: 9 May 2017

Figures(4)

Left and right-handed helical barium titanate nanotubes are prepared with the impregnation of Ba(OH)2 into single-handed helical titania nanotubes. Wide angle X-ray diffraction pattern and transmission electron microscopy image indicate that they are constructed by nanoparticles with a partially crystalline structure. The diffuse reflectance circular dichroism spectra indicate that they exhibit optical activity which was proposed to originate from chiral defects on the inner surfaces of the nanotubes. Both the dielectric constant and tanδ decrease with increasing the frequency. At 10 and 100 Hz, one dielectric constant peak at 9.6℃ and one tanδ peak at 5.0℃ are observed at -120℃ to 180℃.
- Dielectrics,
- Barium titanate,
- Optical materials and properties,
- Templating approach,
- Nanoparticles
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