Citation: Hajian Robabeh, Alghour Zahra. Selective oxidation of alcohols with H₂O₂ catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid[J]. Chinese Chemical Letters, ;2017, 28(5): 971-975. doi: 10.1016/j.cclet.2016.12.003 shu

Selective oxidation of alcohols with H₂O₂ catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid

Hajian Robabeh ^, ,
Alghour Zahra

Department of Chemistry, Yazd University, Yazd 89195-741, Iran

Corresponding author: Hajian Robabeh, rhajian@yazd.ac.ir; hajian_r@yahoo.com
Received Date: 13 September 2016
Revised Date: 31 October 2016
Accepted Date: 10 November 2016
Available Online: 9 May 2016

Figures(7)

In this work, acid functionalized multi-wall carbon nanotubes (MWCNTs) were modified with imidazolium-based ionic liquids. The selective oxidation of various alcohols with hydrogen peroxide catalyzed by[PZnMo₂W₉O₃₉]^5-, ZnPOM, supported on ionic liquids-modified with MWCNTs, MWCNTAPIB, is reported. This catalyst[ZnPOM@APIB-MWCNT], was characterized by X-ray diffraction, scanning electron microscopy (SEM) and FT-IR spectroscopic methods. This heterogeneous catalyst exhibited high stability and reusability in the oxidation reaction without loss of its catalytic performance.
- Immobilized ionic liquid,
- [PZnMo₂W₉O₃₉]^5-,
- Hydrogen peroxide,
- Oxidation,
- Alcohol,
- Heterogeneous catalyst
1. [1]
  Hudlicky M.. Oxidations in Organic Chemistry[J]. American Chemical Society, 1990.
2. [2]
  Davis S.E., Ide M.S., Davis R.J.. Selective oxidation of alcohols and aldehydes over supported metal nanoparticles[J]. Green Chem., 2013(15):17-45.
3. [3]
  Tundo P., Romanelli G.P., Vázquez P.G., Aric F.. Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids[J]. Catal. Commun., 2010(11):1181-1184.
4. [4]
  Betz D., Altmann P., Cokoja M., Herrmann W.A., Kühn F.E.. Recent advances in oxidation catalysis using ionic liquids as solvents[J]. Coord. Chem. Rev., 2011(255):1518-1540.
5. [5]
  R. D. Rogers, K. R. Seddon (Eds. ), A. C. S. Symposium Series, Ionic Liquids (Industrial Applications for Green Chemistry), American Chemical Society, 2002.
6. [6]
  Mizuno N., Misono M.. Heterogeneous catalysis[J]. Chem. Rev., 1998(98):199-218.
7. [7]
  Wang S.S., Yang G.Y.. Recent advances in polyoxometalate-catalyzed reactions[J]. Chem. Rev., 2015(115):4893-4962.
8. [8]
  Miras H.N., Yan J., Long D.L., Cronin L.. Engineering polyoxometalates with emergent properties[J]. Chem. Soc. Rev., 2012(41):7403-7430.
9. [9]
  Kikukawa Y., Yamaguchi K., Mizuno N.. Sandwich-type zinc-containing polyoxometalates with a hexaprismane core[{Zn₂W(O)O₃}₂]⁴⁺ synthesized by thermally induced isomerization of a metastable polyoxometalate[J]. Inorg. Chem., 2010(49):8194-8196.
10. [10]
  Mehnert C.P.. Supported ionic liquid catalysis[J]. Chem. Eur. J., 2005(11):50-56.
11. [11]
  Zhao P., Zhang M., Wu Y., Wang J.. Heterogeneous selective oxidation of sulfides with H₂O₂ catalyzed by ionic liquid-based polyoxometalate salts[J]. Ind. Eng. Chem. Res., 2012(51):6641-6647.
12. [12]
  M. S. Dresselhaus, P. Avouris, Introduction to carbon materials research, in: M. S. Dresselhaus, G. Dresselhaus, P. Avouris (Eds. ), Carbon Nanotubes, Springer, Berlin Heidelberg, 2001 pp. 1-9.
13. [13]
  Herrera A.V., Herrera -, González-Curbelo M.Á., Hernández-Borges J., Rodríguez-Delgado M.Á.. Carbon nanotubes applications in separation science:a review[J]. Anal. Chim. Acta, 2012(734):1-30.
14. [14]
  Georgakilas V., Kordatos K., Prato M.. Organic functionalization of carbon nanotubes[J]. J. Am. Chem. Soc., 2002(124):760-761.
15. [15]
  Sun Y.-P., Fu K., Lin Y., Huang W.. Functionalized carbon nanotubes:properties and applications[J]. Acc. Chem. Res., 2002(35):1096-1104.
16. [16]
  Zhang K., Lim J., Choi H.. Amino functionalization and characteristics of multiwalled carbon nanotube/poly(methyl methacrylate) nanocomposite[J]. Diamond Relat. Mater., 2009(18):316-318.
17. [17]
  Sham M.L., Kim J.K.. Surface functionalities of multi-wall carbon nanotubes after UV/ozone and TETA treatments[J]. Carbon, 2006(44):768-777.
18. [18]
  Kawasaki N., Wang H., Nakanishi R.. Nanohybridization of polyoxometalate clusters and single-wall carbon nanotubes:applications in molecular cluster batteries[J]. Angew. Chem., 2011(123):3533-3536.
19. [19]
  Park M.J., Lee J.K., Lee B.S.. Covalent modification of multiwalled carbon nanotubes with imidazolium-based ionic liquids:effect of anions on solubility[J]. Chem. Mater., 2006(18):1546-1551.
20. [20]
  Ji Y., Huang L., Hu J., Streb C., Song Y.F.. Polyoxometalate-functionalized nanocarbon materials for energy conversion. energy storage and sensor systems[J]. Energy Environ. Sci., 2015(8):776-789.
21. [21]
  Mallat T., Baiker A.. Oxidation of alcohols with molecular oxygen on solid catalysts[J]. Chem. Rev., 2004(104):3037-3058.
22. [22]
  Tangestaninejad S., Yadollahi B.. Oxidation of hydrocarbons with hydrogen peroxide catalyzed by zinc containing polyoxometalate[J]. Chem. Lett., 1998(1998):511-512.
1. [1]
  Jia-Cheng Hou , Hong-Tao Ji , Yu-Han Lu , Jia-Sheng Wang , Yao-Dan Xu , Yan-Yan Zeng , Wei-Min He . Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS₂/TEMPO. Chinese Chemical Letters, 2024, 35(8): 109514-. doi: 10.1016/j.cclet.2024.109514
2. [2]
  Yiyue Ding , Qiuxiang Zhang , Lei Zhang , Qilu Yao , Gang Feng , Zhang-Hui Lu . Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid. Chinese Chemical Letters, 2024, 35(7): 109593-. doi: 10.1016/j.cclet.2024.109593
3. [3]
  Yunkang Tong , Haiqiao Huang , Haolan Li , Mingle Li , Wen Sun , Jianjun Du , Jiangli Fan , Lei Wang , Bin Liu , Xiaoqiang Chen , Xiaojun Peng . Cooperative bond scission by HRP/H₂O₂ for targeted prodrug activation. Chinese Chemical Letters, 2024, 35(12): 109663-. doi: 10.1016/j.cclet.2024.109663
4. [4]
  Hao Lv , Zhi Li , Peng Yin , Ping Wan , Mingshan Zhu . Recent progress on non-metallic carbon nitride for the photosynthesis of H₂O₂: Mechanism, modification and in-situ applications. Chinese Chemical Letters, 2025, 36(1): 110457-. doi: 10.1016/j.cclet.2024.110457
5. [5]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
6. [6]
  Daheng Wen , Weiwei Fang , Yongmei Liu , Tao Tu . Valorization of carbon dioxide with alcohols. Chinese Chemical Letters, 2024, 35(7): 109394-. doi: 10.1016/j.cclet.2023.109394
7. [7]
  Zhikang Wu , Guoyong Dai , Qi Li , Zheyu Wei , Shi Ru , Jianda Li , Hongli Jia , Dejin Zang , Mirjana Čolović , Yongge Wei . POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. Chinese Chemical Letters, 2024, 35(8): 109061-. doi: 10.1016/j.cclet.2023.109061
8. [8]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
9. [9]
  Zhaomin Tang , Qian He , Jianren Zhou , Shuang Yan , Li Jiang , Yudong Wang , Chenxing Yao , Huangzhao Wei , Keda Yang , Jiajia Wang . Active-transporting of charge-reversal Cu(Ⅱ)-doped mesoporous silica nanoagents for antitumor chemo/chemodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109742-. doi: 10.1016/j.cclet.2024.109742
10. [10]
  Changzhu Huang , Wei Dai , Shimao Deng , Yixin Tian , Xiaolin Liu , Jia Lin , Hong Chen . A self-cleaning window for high-efficiency photodegradation of indoor formaldehyde. Chinese Chemical Letters, 2024, 35(9): 109429-. doi: 10.1016/j.cclet.2023.109429
11. [11]
  Zhipeng Wan , Hao Xu , Peng Wu . Selective oxidation using in-situ generated hydrogen peroxide over titanosilicates. Chinese Journal of Structural Chemistry, 2024, 43(6): 100298-100298. doi: 10.1016/j.cjsc.2024.100298
12. [12]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
13. [13]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
14. [14]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
15. [15]
  Tong Zhou , Liyi Xie , Chuyu Liu , Xiyan Zheng , Bao Li . Between Sobriety and Intoxication: The Fascinating Journey of Sauce-Flavored Latte. University Chemistry, 2024, 39(9): 55-58. doi: 10.12461/PKU.DXHX202312048
16. [16]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
17. [17]
  Ruonan Guo , Heng Zhang , Changsheng Guo , Ningqing Lv , Beidou Xi , Jian Xu . Degradation of neonicotinoids with different molecular structures in heterogeneous peroxymonosulfate activation system through different oxidation pathways. Chinese Chemical Letters, 2024, 35(9): 109413-. doi: 10.1016/j.cclet.2023.109413
18. [18]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
19. [19]
  Hao-Cong Li , Ming Zhang , Qiyan Lv , Kai Sun , Xiao-Lan Chen , Lingbo Qu , Bing Yu . Homogeneous catalysis and heterogeneous separation: Ionic liquids as recyclable photocatalysts for hydroacylation of olefins. Chinese Chemical Letters, 2025, 36(2): 110579-. doi: 10.1016/j.cclet.2024.110579
20. [20]
  Yanling Yang , Zhenfa Ding , Huimin Wang , Jianhui Li , Yanping Zheng , Hongquan Guo , Li Zhang , Bing Yang , Qingqing Gu , Haifeng Xiong , Yifei Sun . Dynamic tracking of exsolved PdPt alloy/perovskite catalyst for efficient lean methane oxidation. Chinese Chemical Letters, 2024, 35(4): 108585-. doi: 10.1016/j.cclet.2023.108585

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(671)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Selective oxidation of alcohols with H2O2 catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid

Metrics

通讯作者: 陈斌, bchen63@163.com

Selective oxidation of alcohols with H₂O₂ catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid