Citation: Duan Zhi-Qiang, Gao Xin-Bao, Li Tian-Peng, Yao Kai, Xie Xu-Ming. A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu²⁺ coordination for surfaceenhanced Raman scattering[J]. Chinese Chemical Letters, ;2017, 28(3): 521-524. doi: 10.1016/j.cclet.2016.11.031 shu

A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu²⁺ coordination for surfaceenhanced Raman scattering

Duan Zhi-Qiang ^a ,
Gao Xin-Bao ^a,, ,
Li Tian-Peng ^a ,
Yao Kai ^a,b ,
Xie Xu-Ming ^c,,

a.
Shijiazhuang Mechanical Engineering College, Shijiazhuang 050003, China
b.
Department of Graduate Management, Equipment Academy, Beijing 101416, China
c.
Key Laboratory of Advanced Materials (MOE), Department of Chemical Engineering, Tsinghua University, ; Beijing 100084, China

Corresponding author: Gao Xin-Bao, xinbao_gao@163.com Xie Xu-Ming, xxm-dce@mail.tsinghua.edu.cn
Received Date: 12 July 2016
Revised Date: 2 August 2016
Accepted Date: 29 August 2016
Available Online: 5 March 2016

Figures(6)

We report the hierarchical assembly of Au nanoparticles on carboxylized carbon nanotubes (c-CNTs) through Cu²⁺ coordination. This route is facile and green, and can easily control the loading density of Au nanoparticles. The c-CNTs matrix ensures uniform distribution of Au nanoparticles, which is particularly important for the enrichment of hot spots while preventing their serious agglomeration. Moreover, the cCNT matrix also contributes to the electromagnetic enhancement due to its surface plasmon resonance, and the chemical enhancement due to the adsorption of the target molecules. The resulting Au@c-CNT nanohybrids exhibit a remarkable synergy in SERS compared to neat Au nanoparticles.
- Au nanoparticles,
- Carbon nanotubes,
- Coordination,
- Hierarchical assembly,
- Surface-enhanced Raman scattering
1. [1]
  Fleischmann M., Hendra P.J., McQuillan A.J.. Raman spectra of pyridine adsorbed at a silver electrode[J]. Chem. Phys. Lett., 1974,26:163-166. doi: 10.1016/0009-2614(74)85388-1
2. [2]
  Jeanmaire D.L., Van Duyne R.P., Raman spectroelectrochemistry:part I. Heterocyclic Surface. aromatic, and aliphatic amines adsorbed on the anodized silver electrode[J]. J. Electroanal. Chem. Interfacial Electrochem., 1977,84:1-20. doi: 10.1016/S0022-0728(77)80224-6
3. [3]
  Albrecht M.G., Creighton J.A.. Anomalously intense Raman spectra of pyridine at a silver electrode[J]. J. Am. Chem. Soc., 1977,99:5215-5217. doi: 10.1021/ja00457a071
4. [4]
  Zhang Y., Wang L.-M., Tan E.-Z.. Uniform arrays of gold nanoparticles with different surface roughness for surface enhanced Raman scattering[J]. Chem. Lett., 2015,26:1426-1430.
5. [5]
  Ma C.H., Zhang J., Hong Y.C., Wang Y.R., Chen X.. Determination of carbendazim in tea using surface enhanced Raman spectroscopy[J]. Chin. Chem. Lett., 2015,26:1455-1459. doi: 10.1016/j.cclet.2015.10.015
6. [6]
  Wu T., Wang H.T., Shen B., Du Y.P.. Determination of primary aromatic amines using immobilized nanoparticles based surface-enhanced Raman spectroscopy[J]. Chin. Chem. Lett., 2016,27:745-748. doi: 10.1016/j.cclet.2016.01.059
7. [7]
  Huang J., Zhang L.M., Chen B.. Nanocomposites of size-controlled gold nanoparticles and graphene oxide:formation and applications in SERS and catalysis[J]. Nanoscale, 2010,2:2733-2738. doi: 10.1039/c0nr00473a
8. [8]
  Luo P.H., Li C., Shi G.Q.. Synthesis of gold@carbon dots composite nanoparticles for surface enhanced Raman scattering[J]. Phys. Chem. Chem. Phys., 2012,14:7360-7366. doi: 10.1039/c2cp40767a
9. [9]
  He X.N., Gao Y., Mahjouri-Samani M.. Surface-enhanced Raman spectroscopy using gold-coated horizontally aligned carbon nanotubes[J]. Nanotechnology, 2012,23205702. doi: 10.1088/0957-4484/23/20/205702
10. [10]
  Liu Y.T., Feng Q.P., Xie X.M., Ye X.Y.. The production of flexible and transparent conductive films of carbon nanotube/graphene networks coordinated by divalent metal (Cu, Ca or Mg) ions[J]. Carbon, 2011,49:3371-3391. doi: 10.1016/j.carbon.2011.03.055
11. [11]
  Liu Y.T., Dang M., Xie X.M., Wang Z.F., Ye X.Y.. Synergistic effect of Cu²⁺-coordinated carbon nanotube/graphene network on the electrical and mechanical properties of polymer nanocomposites[J]. J. Mater. Chem., 2011,21:18723-18729. doi: 10.1039/c1jm13727a
12. [12]
  Huang W., Wang Y., Luo G.H., Wei F.. 99.9% purity multi-walled carbon nanotubes by vacuum high-temperature annealing[J]. Carbon, 2003,41:2585-2590. doi: 10.1016/S0008-6223(03)00330-0
13. [13]
  Liu Y.-T., Zhao W., Huang Z.Y.. Noncovalentsurface modification of carbon nanotubes for solubility in organic solvents[J]. Carbon, 2006,44:1613-1616. doi: 10.1016/j.carbon.2006.02.034
14. [14]
  Frens G.. Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions[J]. Nat. Phys. Sci., 1973,241:20-22. doi: 10.1038/physci241020a0
15. [15]
  Liu Y.T., Duan Z.Q., Xie X.M., Ye X.Y.. A universal strategy for the hierarchical assembly of functional 0/2D nanohybrids[J]. Chem. Commun., 2013,49:1642-1644. doi: 10.1039/c3cc38567a
16. [16]
  Pan L., Zhu X.D., Xie X.M., Liu Y.T.. Smart hybridization of TiO₂ nanorods and Fe₃O₄ nanoparticles with pristine graphene nanosheets:hierarchically nanoengineered ternary heterostructures for high-rate lithium storage[J]. Adv. Funct. Mater., 2015,25:3341-3350. doi: 10.1002/adfm.v25.22
1. [1]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
2. [2]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
3. [3]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
4. [4]
  Zhimin Sun , Xin-Hui Guo , Yue Zhao , Qing-Yu Meng , Li-Juan Xing , He-Lue Sun . Dynamically switchable porphyrin-based molecular tweezer for on−off fullerene recognition. Chinese Chemical Letters, 2024, 35(6): 109162-. doi: 10.1016/j.cclet.2023.109162
5. [5]
  Ting Pan , Dinghu Zhang , Guomei You , Xiaoxia Wu , Chenguang Zhang , Xinyu Miao , Wenzhi Ren , Yiwei He , Lulu He , Yuanchuan Gong , Jie Lin , Aiguo Wu , Guoliang Shao . PD-L1 targeted iron oxide SERS bioprobe for accurately detecting circulating tumor cells and delineating tumor boundary. Chinese Chemical Letters, 2025, 36(1): 109857-. doi: 10.1016/j.cclet.2024.109857
6. [6]
  Chengde Wang , Liping Huang , Shanshan Wang , Lihao Wu , Yi Wang , Jun Dong . A distinction of gliomas at cellular and tissue level by surface-enhanced Raman scattering spectroscopy. Chinese Chemical Letters, 2024, 35(5): 109383-. doi: 10.1016/j.cclet.2023.109383
7. [7]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
8. [8]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
9. [9]
  Le Zhang , Hui-Yu Xie , Xin Li , Li-Ying Sun , Ying-Feng Han . SOMO-HOMO level conversion in triarylmethyl-cored N-heterocyclic carbene-Au(I) complexes triggered by selecting coordination halogens. Chinese Chemical Letters, 2024, 35(11): 109465-. doi: 10.1016/j.cclet.2023.109465
10. [10]
  Zhengzhong Zhu , Shaojun Hu , Zhi Liu , Lipeng Zhou , Chongbin Tian , Qingfu Sun . A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability. Chinese Chemical Letters, 2025, 36(2): 109641-. doi: 10.1016/j.cclet.2024.109641
11. [11]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
12. [12]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654
13. [13]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305
14. [14]
  Yi Zhou , Wei Zhang , Rong Fu , Jiaxin Dong , Yuxuan Liu , Zihang Song , Han Han , Kang Cai . Self-assembly of two pairs of homochiral M₂L₄ coordination capsules with varied confined space using Tröger's base ligands. Chinese Chemical Letters, 2025, 36(2): 109865-. doi: 10.1016/j.cclet.2024.109865
15. [15]
  Xin Li , Zhen Xu , Donglei Bu , Jinming Cai , Huamei Chen , Qi Chen , Ting Chen , Fang Cheng , Lifeng Chi , Wenjie Dong , Zhenchao Dong , Shixuan Du , Qitang Fan , Xing Fan , Qiang Fu , Song Gao , Jing Guo , Weijun Guo , Yang He , Shimin Hou , Ying Jiang , Huihui Kong , Baojun Li , Dengyuan Li , Jie Li , Qing Li , Ruoning Li , Shuying Li , Yuxuan Lin , Mengxi Liu , Peinian Liu , Yanyan Liu , Jingtao Lü , Chuanxu Ma , Haoyang Pan , JinLiang Pan , Minghu Pan , Xiaohui Qiu , Ziyong Shen , Shijing Tan , Bing Wang , Dong Wang , Li Wang , Lili Wang , Tao Wang , Xiang Wang , Xingyue Wang , Xueyan Wang , Yansong Wang , Yu Wang , Kai Wu , Wei Xu , Na Xue , Linghao Yan , Fan Yang , Zhiyong Yang , Chi Zhang , Xue Zhang , Yang Zhang , Yao Zhang , Xiong Zhou , Junfa Zhu , Yajie Zhang , Feixue Gao , Yongfeng Wang . Recent progress on surface chemistry Ⅰ: Assembly and reaction. Chinese Chemical Letters, 2024, 35(12): 110055-. doi: 10.1016/j.cclet.2024.110055
16. [16]
  Manyu Zhu , Fei Liang , Lie Wu , Zihao Li , Chen Wang , Shule Liu , Xiue Jiang . Revealing the difference of Stark tuning rate between interface and bulk by surface-enhanced infrared absorption spectroscopy. Chinese Chemical Letters, 2025, 36(2): 109962-. doi: 10.1016/j.cclet.2024.109962
17. [17]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
18. [18]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
19. [19]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
20. [20]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(762)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu2+ coordination for surfaceenhanced Raman scattering

Metrics

通讯作者: 陈斌, bchen63@163.com

A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu²⁺ coordination for surfaceenhanced Raman scattering