Citation: Fan Jin, Xie Zhi-Hai, Teng Xiao-Xiao, Zhang Yu. Determination of methylene blue by resonance light scattering method using silica nanoparticles as probe[J]. Chinese Chemical Letters, ;2017, 28(5): 1104-1110. doi: 10.1016/j.cclet.2016.11.025 shu

Determination of methylene blue by resonance light scattering method using silica nanoparticles as probe

Key Laboratory of Synthetic & Natural Functional Molecular Chemistry of The Ministry of Education, College of Chemistry & Material Science, Northwest University, Xi'an 710127, China

Corresponding author: Xie Zhi-Hai, xiezhihai8@163.com
Received Date: 6 October 2016
Revised Date: 2 November 2016
Accepted Date: 14 November 2016
Available Online: 27 May 2016

Figures(10)

A simple and novel method was developed to determine methylene blue (MB) by resonance light scattering (RLS) using silica nanoparticles (SiO₂NPs) as the probe. It was found that MB could enhance the RLS intensity of SiO₂NPs. Moreover, the increase in RLS intensity was linear with the concentration of MB over the range of 0.01-3.0μg mL^-1. The limit of detection (LOD) was as low as 4.36 ng mL^-1 (3σ) and the relative standard deviation (RSD) was 2.4% (n=6). Under the optimum experimental conditions, this proposed method was successfully applied for the determination of MB in aquaculture samples with recoveries between 96.3% and 107%. Possible mechanisms for the RLS enhancement of SiO₂NPs in the presence of MB were also discussed.
- Methylene blue,
- Silica nanoparticles,
- Aggregation,
- Resonance light scattering,
- Determination
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