Citation: iang LeiX, Yang Kai, Song Qiu-Ling. Pd-catalyzed ortho-olefination of aromatic acetyl esters[J]. Chinese Chemical Letters, ;2017, 28(3): 517-520. doi: 10.1016/j.cclet.2016.11.023 shu

Pd-catalyzed ortho-olefination of aromatic acetyl esters

iang LeiX ^a,b ,
Yang Kai ^a ,
Song Qiu-Ling ^a,,

a.
Institute of Next Generation Matter Transformation, College of Chemical Engineering at Huaqiao University, Xiamen 361021, China
b.
Institute of Pharmacy and Pharmacology, Learning Key Laboratory for Pharmacoproteomics University of South China, Hengyang 421001, China

Corresponding author: Song Qiu-Ling, qsong@hqu.edu.cn
Received Date: 8 October 2016
Revised Date: 3 November 2016
Accepted Date: 7 November 2016
Available Online: 22 March 2016

Figures(5)

A Pd (Ⅱ)-catalyzed ortho-olefination of aromatic acetic esters is described which features with an excellent funcitional group tolerance, good yields, mild reaction conditions, good scalability as well as high chemo-and regio-selectivity.
- ortho-Olefination,
- Aromatic acetyl ester,
- Pd catalyst,
- C-H activation,
- Weak coordination
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