Citation: Basha Mai A., Abd El-Rahman Mohamed K., Bebawy Lories I., Salem Maissa Y.. Novel potentiometric application for the determination of amprolium HCl in its single and combined dosage form and in chicken liver[J]. Chinese Chemical Letters, ;2017, 28(3): 612-618. doi: 10.1016/j.cclet.2016.11.012 shu

Novel potentiometric application for the determination of amprolium HCl in its single and combined dosage form and in chicken liver

a.
National Organization of Drug Control and Research (NODCAR), Cairo 29, Egypt
b.
Analytical Chemistry Department, Faculty of Pharmacy, Cairo University, Cairo 11562, Egypt

Corresponding author: Basha Mai A., mamo1134@yahoo.com
Received Date: 27 July 2016
Revised Date: 19 October 2016
Accepted Date: 4 November 2016
Available Online: 19 March 2016

Figures(7)

Three novel amprolium HCl (AMP)-selective electrodes were investigated with 2-nitrophenyl octylether as a plasticiser in a polymeric matrix of polyvinyl chloride (PVC). Sensor Ⅰ was fabricated using potassium tetrakis (4-chlorophenyl) borate (TpClPB) as a cationic exchanger without incorporation of an ionophore. Sensor Ⅱ used 2-hydroxy propyl β-cyclodextrin as an ionophore while sensor Ⅲ used p-tert-butylcalix[8] arene as an ionophore. The three proposed sensors showed Nernestian response slopes of 29.2±0.8, 29.3±0.6 and 30.2±0.4 mV/decade over the concentration range from 10-6 to 10-2 mol L^-1, respectively. The proposed sensors displayed useful analytical characteristics for the determination of AMP in bulk powder, different pharmaceutical formulations, and chicken liver and in the presence of ethopabate. The proposed method was validated according to ICH guidelines for its linearity, accuracy, precision and robustness.
- Amprolium HCl,
- Cationic exchanger,
- Ionophore,
- Ion selective electrodes,
- Ethopabate,
- Chicken liver
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