Citation: Meng Xian-Hua, Jiang Zhi-Bo, Guo Qing-Lan, Shi Jian-Gong. A minor arcutine-type C₂₀-diterpenoid alkaloid iminium constituent of "fu zi"[J]. Chinese Chemical Letters, ;2017, 28(3): 588-592. doi: 10.1016/j.cclet.2016.11.010 shu

A minor arcutine-type C₂₀-diterpenoid alkaloid iminium constituent of "fu zi"

State Key Laboratory of Bioactive Substance and Function of Natural Medicines, Institute of Materia Medica, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing, 100050, China

Corresponding author: Shi Jian-Gong, shijg@imm.ac.cn
Received Date: 2 September 2016
Revised Date: 14 October 2016
Accepted Date: 1 November 2016
Available Online: 18 March 2016

Figures(3)

A rare arcutine-type C₂₀-diterpenoid alkaloid, named aconicarmicharcutinium A and obtained as hydroxide (1) and trifluoroacetate (1a), was characterized as a minor constituent of "fu zi" (the lateral roots of Aconitum carmichaelii). The structures of 1 and 1a were elucidated by comprehensive analysis of spectroscopic data including ¹⁹F and 2D NMR experiments. Compounds 1 and 1a represent the first examples of the arcutine-type C20-diterpenoid alkaloid iminium.
- Aconitum carmichaelii,
- Ranunculaceae,
- Arcutine-type C₂₀-diterpenoid alkaloid,
- iminium,
- Aconicarmicharcutinium A
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沈阳化工大学材料科学与工程学院沈阳 110142

A minor arcutine-type C20-diterpenoid alkaloid iminium constituent of "fu zi"

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通讯作者: 陈斌, bchen63@163.com

A minor arcutine-type C₂₀-diterpenoid alkaloid iminium constituent of "fu zi"