Citation: Ren Juan, Wang Yi-Yun, Feng Ru-Xia, Kong Xiang-Lei. Investigation of _L/D-threonine substituted _L-serine octamer ions by mass spectrometry and infrared photodissociation spectroscopy[J]. Chinese Chemical Letters, ;2017, 28(3): 537-540. doi: 10.1016/j.cclet.2016.10.032 shu

Investigation of _L/D-threonine substituted _L-serine octamer ions by mass spectrometry and infrared photodissociation spectroscopy

a.
The State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
b.
Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, ;China

Corresponding author: Kong Xiang-Lei, kongxianglei@nankai.edu.cn
Received Date: 9 August 2016
Revised Date: 16 September 2016
Accepted Date: 30 September 2016
Available Online: 1 March 2016

Figures(3)

Threonine-substituted serine octamer ions were generated by electrospray ionization (ESI) and investigated by mass spectrometry and infrared photodissociation (IRPD) spectroscopy. IRPD spectra of[L-Ser₇+L/D-Thr₁]H⁺ and [L-Ser₆+L/D-Thr₂]H⁺ were obtained in the range of 2700-3600 cm^-1. Chiral differentiation was achieved by comparing their IRPD spectra. The main difference located in the range of 3300-3500 cm^-1. And the results indicate the substitution of L-Ser by D-Thr could weaken the intermolecular H-bonds and loosen the original structures of serine octamers.
- IRPD spectroscopy,
- Threonine,
- Serine octamer,
- Chiral differentiation,
- Mass spectrometry
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Investigation of L/D-threonine substituted L-serine octamer ions by mass spectrometry and infrared photodissociation spectroscopy

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通讯作者: 陈斌, bchen63@163.com

Investigation of _L/D-threonine substituted _L-serine octamer ions by mass spectrometry and infrared photodissociation spectroscopy