Citation: . Preparation of chloro-functionalized reduced graphene oxide by silver-catalyzed radical reaction[J]. Chinese Chemical Letters, ;2017, 28(2): 407-411. doi: 10.1016/j.cclet.2016.10.017 shu

Preparation of chloro-functionalized reduced graphene oxide by silver-catalyzed radical reaction

Received Date: 30 August 2016
Revised Date: 29 September 2016
Accepted Date: 10 October 2016
Available Online: 20 February 2016

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It is well-known that chemical functionalization of graphene has the great significance. We report the development of a new synthesis method of chloro-functionalized reduced graphene oxide (rGOCl). The rGOCl was prepared by radical reaction, and treatment of carboxyl graphene oxide (GOCOOH) with N-chlorosuccinimide (NCS) at 90℃ for 10 h under an atmosphere of nitrogen, using silver nitrate as catalyst. The morphologies and structures of the prepared materials were investigated by field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and the thermal gravimetric. Results indicated that the rGOCl can be readily obtained from graphene oxide (GO) in three steps.
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