Citation: Cui Li-Ying, Yan Yu, Zhao Xin-Yu, Yu Cun-Long, Ma Ying, Yang Bai. Controlling coffee ring structure on hydrophobic polymer surface by manipulating wettability with O₂ plasma[J]. Chinese Chemical Letters, ;2017, 28(1): 1-5. doi: 10.1016/j.cclet.2016.07.028 shu

Controlling coffee ring structure on hydrophobic polymer surface by manipulating wettability with O₂ plasma

Cui Li-Ying ^a,b ,
Yan Yu ^b ,
Zhao Xin-Yu ^a ,
Yu Cun-Long ^a ,
Ma Ying ^c ,
Yang Bai ^b,,

a.
College of Resources and Environment, Jilin Agricultural University, Changchun 130118, China
b.
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
c.
School of Materials Science and Engineering, Shenyang Jianzhu University, Shenyang 110168, China

Corresponding author: Yang Bai, byangchem@jlu.edu.cn
Received Date: 12 June 2016
Revised Date: 4 July 2016
Accepted Date: 6 July 2016
Available Online: 29 January 2016

Figures(4)

A simple and novel method is firstly reported for controlling coffee ring structure on polystyrene (PS) film surface by O₂ plasma. O₂ plasma treatment leads to the wettability change of PS surface from hydrophobic to hydrophilic. For hydrophilic PS surface the coffee ring structure is avoided relying on the motion of contact line (CL) while SiO₂ microspheres are left. The motion of the CL is produced based on the viscosity and Marangoni effect with the addition of polymer additives. For hydrophobic PS surface coffee ring structure still persists even with polymer additives because SiO₂ microspheres transfer with the motion of the CL at the beginning of droplet evaporation and accumulate at the droplet edge at late stage with the pinning of the CL. As a result, uniform and macroscale SiO₂ microspheres deposition without coffee ring structure and SiO₂ microspheres deposition with coffee ring structure are controlled by O₂ plasma. This method provides a new way to tune coffee ring structure with smart surface and may be potentially useful for a range of application at material deposition and diagnosing diseases.
- Coffee ring,
- SiO₂ microspheres deposition,
- Drop evaporation,
- O₂ plasma,
- PS surface
1. [1]
  Anyfantakis M., Baigl D.. Dynamic photocontrol of the coffee-ring effect with optically tunable particle stickiness[J]. Angew. Chem. Int. Ed., 2014,53:14077-14081. doi: 10.1002/anie.v53.51
2. [2]
  Xie Z.Y., Li L.L., Liu P.M.. Self-assembled coffee-ring colloidal crystals for structurally colored contact lenses[J]. Small, 2015,11:926-930. doi: 10.1002/smll.v11.8
3. [3]
  Wen J.T., Ho C.M., Lillehoj P.B.. Coffee ring aptasensor for rapid protein detection[J]. Langmuir, 2013,29:8440-8446. doi: 10.1021/la400224a
4. [4]
  Cui L.Y., Li Y.F., Wang J.X.. Fabrication of large-area patterned photonic crystals by ink-jet printing[J]. J. Mater. Chem., 2009,19:5499-5502.
5. [5]
  Deegan R.D., Bakajin O., Dupont T.F.. Capillary flow as the cause of ring stains from dried liquid drops[J]. Nature, 1997,389:827-829. doi: 10.1038/39827
6. [6]
  Wu J.T., Hsu S.L.C., Tsai M.H., Hwang W.S.. Inkjet printing of low-temperature cured silver patterns by using AgNO₃/1-dimethylamino-2-propanol inks on polymer substrates[J]. J. Phys. Chem. C, 2011,115:10940-10945. doi: 10.1021/jp200972y
7. [7]
  Girard F., Antoni M., Faure S., Steinchen A.. Influence of heating temperature and relative humidity in the evaporation of pinned droplets[J]. Colloids Surf. A:Physicochem. Eng. Aspects, 2008,323:36-49. doi: 10.1016/j.colsurfa.2007.12.022
8. [8]
  Park J., Moon J., Shin H., Wang D.K., Park M.. Direct-write fabrication of colloidal photonic crystal microarrays by ink-jet printing[J]. J. Colloid Interface Sci., 2006,298:713-719. doi: 10.1016/j.jcis.2006.01.031
9. [9]
  Yunker P.J., Still T., Lohr M.A., Yodh A.G.. Suppression of the coffee-ring effect by shape-dependent capillary interactions[J]. Nature, 2011,476:308-311. doi: 10.1038/nature10344
10. [10]
  Eral H.B., Augustine D.M., Duits M.H.G., Mugele F.. Suppressing the coffee stain effect:how to control colloidal self-assembly in evaporating drops using electrowetting[J]. Soft Matter, 2011,7:4954-4958. doi: 10.1039/c1sm05183k
11. [11]
  Cui L.Y., Zhang J.H., Zhang X.M.. Suppression of the coffee ring effect by hydrosoluble polymer additives[J]. ACS Appl. Mater. Interfaces, 2012,4:2775-2780. doi: 10.1021/am300423p
12. [12]
  Wang J.X., Zhang Y.Z., Wang S.T., Song Y.L., Jiang L.. Bioinspired colloidal photonic crystals with controllable wettability[J]. Acc. Chem. Res., 2011,44:405-415. doi: 10.1021/ar1001236
13. [13]
  Xu L.Y., Tong F.Q., Lu X.M., Lu K., Lu Q.H.. Multifunctional polypyrene/silica hybrid coatings with stable excimer fluorescence and robust superhydrophobicity derived from electrodeposited polypyrene films[J]. J. Mater. Chem. C, 2015,3:2086-2092. doi: 10.1039/C4TC02653E
14. [14]
  Song W.L.. Adhesion switch on a gecko-foot inspired smart nanocupule surface[J]. Nanoscale, 2014,6:13435-13439. doi: 10.1039/C4NR04090B
15. [15]
  Su B., Guo W., Jiang L.. Learning from nature:binary cooperative complementary nanomaterials[J]. Small, 2015,11:1072-1096. doi: 10.1002/smll.v11.9-10
16. [16]
  Stöber W., Fink A., Bohn E.. Controlled growth of monodisperse silica spheres in the micron size range[J]. J. Colloid Interface Sci., 1968,26:62-69. doi: 10.1016/0021-9797(68)90272-5
17. [17]
  He D.G., He X.X., Wang K.M., Zhao Y.X.. A facile route for shape-selective synthesis of silica nanostructures using poly-L-lysine as template[J]. Chin. Chem. Lett., 2013,24:99-102. doi: 10.1016/j.cclet.2013.01.038
18. [18]
  Wang X., Yang Y.J., Ma Y., Yao J.N.. Controlled synthesis of multi-shelled transition metal oxide hollow structures through one-pot solution route[J]. Chin. Chem. Lett., 2013,24:1-6. doi: 10.1016/j.cclet.2013.01.017
19. [19]
  Sangani A.S., Lu C., Su K., Schwarz J.A.. Capillary force on particles near a drop edge resting on a substrate and a criterion for contact line pinning[J]. Phys. Rev. E, 2009,80011603.
20. [20]
  Kajiya T., Monteux C., Narita T., Lequeux F., Doi M.. Contact-line recession leaving a macroscopic polymer film in the drying droplets of water-poly (N, N-dimethylacrylamide) (PDMA) solution[J]. Langmuir, 2009,25:6934-6939. doi: 10.1021/la900216k
21. [21]
  Kajiya T., Kobayashi W., Okuzono T., Doi M.. Controlling profiles of polymer dots by switching between evaporation and condensation[J]. Langmuir, 2010,26:10429-10432. doi: 10.1021/la1016388
1. [1]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
2. [2]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
3. [3]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
4. [4]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
5. [5]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
6. [6]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
7. [7]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
8. [8]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
9. [9]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
10. [10]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
11. [11]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
12. [12]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533
13. [13]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
14. [14]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274
15. [15]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
16. [16]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
17. [17]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
18. [18]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
19. [19]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
20. [20]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(908)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Controlling coffee ring structure on hydrophobic polymer surface by manipulating wettability with O2 plasma

Metrics

通讯作者: 陈斌, bchen63@163.com

Controlling coffee ring structure on hydrophobic polymer surface by manipulating wettability with O₂ plasma