Citation: Cheng Lu, Cao Yu, Ge Rui, Wei Ying-Qiang, Wang Na-Na, Wang Jian-Pu, Huang Wei. Sky-blue perovskite light-emitting diodes based on quasi-two-dimensional layered perovskites[J]. Chinese Chemical Letters, ;2017, 28(1): 29-31. doi: 10.1016/j.cclet.2016.07.001 shu

Sky-blue perovskite light-emitting diodes based on quasi-two-dimensional layered perovskites

Cheng Lu ^a ,
Cao Yu ^a ,
Ge Rui ^a ,
Wei Ying-Qiang ^a ,
Wang Na-Na ^a ,
Wang Jian-Pu ^a,, ,
Huang Wei ^a,b

a.
Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, China
b.
Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: Wang Jian-Pu, iamjpwang@njtech.edu.cn
Received Date: 2 June 2016
Revised Date: 7 June 2016
Accepted Date: 9 June 2016
Available Online: 8 January 2016

Figures(3)

A mixed organic (4-phenylbutylamine, 4-PBA) and inorganic (cesium, Cs) cations are used to deposit quasi-two-dimensional layered perovskites. This layered perovskites exhibit good film coverage as twodimensional perovskites and high emission performance close to three-dimensional organic-inorganic hybrid perovskites. Light-emitting diodes (LEDs) are fabricated by using solution process based on the quasi-two-dimensional layered perovskites. The perovskite LEDs exhibit a sky-blue emission with electroluminescence peak at 491 nm and a low turn on voltage at 2.9 V. The maximum external quantum efficiency reaches 0.015% at brightness of 186 cd/m².
- Perovskite light-emitting diodes,
- Quasi-2D,
- Sky-blue emission,
- Morphology,
- Solution process
1. [1]
  Deschler F., Price M., Pathak S.. High photoluminescence efficiency and optically pumped lasing in solution-processed mixed halide perovskite semiconductors[J]. J. Phys. Chem. Lett., 2014,5:1421-1426. doi: 10.1021/jz5005285
2. [2]
  Tan Z.K., Moghaddam R.S., Lai M.L.. Bright light-emitting diodes based on organometal halide perovskite[J]. Nat. Nanotechnol., 2014,9:687-692. doi: 10.1038/nnano.2014.149
3. [3]
  Wang J., Wang N., Jin Y.. Interfacial control toward efficient and low-voltage perovskite light-emitting diodes[J]. Adv. Mater., 2015,27:2311-2316. doi: 10.1002/adma.v27.14
4. [4]
  Wang N., Si J., Jin Y., Wang J., Huang W.. Solution-processed organic-inorganic hybrid perovskites:a class of dream materials beyond photovoltaic applications[J]. Acta Chim. Sin., 2015,73:171-178. doi: 10.6023/A14100711
5. [5]
  Liu T.H., Chen K., Hu Q.. Fast-growing procedure for perovskite films in planar heterojunction perovskite solar cells[J]. Chin. Chem. Lett., 2015,26:1518-1521. doi: 10.1016/j.cclet.2015.09.022
6. [6]
  Cho H., Jeong S.H., Park M.H.. Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes[J]. Science, 2015,350:1222-1225. doi: 10.1126/science.aad1818
7. [7]
  Li G., Rivarola F.W.R., Davis N.J.L.K.. Highly efficient perovskite nanocrystal light-emitting diodes enabled by a universal crosslinking method[J]. Adv. Mater., 2016,28:3528-3534. doi: 10.1002/adma.201600064
8. [8]
  Sadhanala A., Ahmad S., Zhao B.. Blue-green color tunable solution processable organolead chloride-bromide mixed halide perovskites for optoelectronic applications[J]. Nano Lett., 2015,15:6095-6101. doi: 10.1021/acs.nanolett.5b02369
9. [9]
  Kim Y.H., Cho H., Heo J.H.. Multicolored organic/inorganic hybrid perovskite light-emitting diodes[J]. Adv. Mater., 2015,27:1248-1254. doi: 10.1002/adma.201403751
10. [10]
  Kumawat N.K., Dey A., Narsimhan K.L., Kabra D.. Near infrared to visible electroluminescent diodes based on organometallic halide perovskites:structural and optical investigation[J]. ACS Photon., 2015,2:349-354. doi: 10.1021/acsphotonics.5b00018
11. [11]
  Song J., Li J., Li X.. Quantum dot light-emitting diodes based on inorganic perovskite cesium lead halides (CsPbX₃)[J]. Adv. Mater., 2015,27:7162-7167. doi: 10.1002/adma.201502567
12. [12]
  Qian L., Zheng Y., Choudhury K.R.. Electroluminescence from light-emitting polymer/ZnO nanoparticle heterojunctions at sub-bandgap voltages[J]. Nano Today, 2010,5:384-389. doi: 10.1016/j.nantod.2010.08.010
13. [13]
  Zhou Y., Fuentes-Hernandez C., Shim J.. A universal method to produce low-work function electrodes for organic electronics[J]. Science, 2012,336:327-332. doi: 10.1126/science.1218829
14. [14]
  Dai X., Zhang Z., Jin Y.. Solution-processed, high-performance light-emitting diodes based on quantum dots[J]. Nature, 2014,515:96-99. doi: 10.1038/nature13829
15. [15]
  Smith I.C., Hoke E.T., Solis-Ibarra D., McGehee M.D., Karunadasa H.I.. A layered hybrid perovskite solar-cell absorber with enhanced moisture stability[J]. Angew. Chem. Int. Ed., 2014,53:11232-11235. doi: 10.1002/anie.201406466
16. [16]
  Quan L.N., Yuan M., Comin R.. Ligand-stabilized reduced-dimensionality perovskites[J]. J. Am. Chem. Soc., 2016,138:2649-2655. doi: 10.1021/jacs.5b11740
17. [17]
  Yantara N., Bhaumik S., Yan F.. Inorganic halide perovskites for efficient light-emitting diodes[J]. J. Phys. Chem. Lett., 2015,6:4360-4364. doi: 10.1021/acs.jpclett.5b02011
18. [18]
  Mitzi D.B., Chondroudis K., Kagan C.R.. Organic-inorganic electronics[J]. IBM J. Res. Dev., 2001,45:29-45. doi: 10.1147/rd.451.0029
19. [19]
  Wang N., Cheng L., Si J.. Morphology control of perovskite light-emitting diodes by using amino acid self-assembled monolayers[J]. Appl. Phys. Lett., 2016,108141102. doi: 10.1063/1.4945330
20. [20]
  Trattnig R., Pevzner L., Jäger M.. Bright blue solution processed triple-layer polymer light-emitting diodes realized by thermal layer stabilization and orthogonal solvents[J]. Adv. Funct. Mater., 2013,23:4897-4905. doi: 10.1002/adfm.v23.39
1. [1]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
2. [2]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
3. [3]
  Liwen Wang , Boyang Wang , Siyu Lu , Shubo Lv , Xiaoli Qu . High quantum yield yellow emission carbon dots for the construction of blue light blocking films. Chinese Chemical Letters, 2025, 36(2): 110497-. doi: 10.1016/j.cclet.2024.110497
4. [4]
  Zhongjie Li , Xiangyue Kong , Yuhao Liu , Huayu Qiu , Lingling Zhan , Shouchun Yin . Progress of additives for morphology control in organic photovoltaics. Chinese Chemical Letters, 2024, 35(6): 109378-. doi: 10.1016/j.cclet.2023.109378
5. [5]
  Xiangan Song , Shaogang Shen , Mengyao Lu , Ying Wang , Yong Zhang . Trifluoromethyl enable high-performance single-emitter white organic light-emitting devices based on quinazoline acceptor. Chinese Chemical Letters, 2024, 35(4): 109118-. doi: 10.1016/j.cclet.2023.109118
6. [6]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
7. [7]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
8. [8]
  Xin Lu , Haoran Sun , Xiaomeng Li , Chunrui Li , Jinfeng Wang , Dandan Zhou . C14-HSL limits the mycelial morphology of pathogen Trichosporon cells but enhances their aggregation: Mechanisms and implications. Chinese Chemical Letters, 2024, 35(6): 108936-. doi: 10.1016/j.cclet.2023.108936
9. [9]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
10. [10]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
11. [11]
  Shan Jiang , Lingchen Meng , Wenyue Ma , Qingkai Qi , Wei Zhang , Bin Xu , Leijing Liu , Wenjing Tian . Corrigendum to 'Morphology controllable conjugated network polymers based on AIE-active building block for TNP detection' [Chin. Chem. Lett. 32 (2021) 1037-1040]. Chinese Chemical Letters, 2024, 35(12): 108998-. doi: 10.1016/j.cclet.2023.108998
12. [12]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
13. [13]
  Yuan Liu , Boyang Wang , Yaxin Li , Weidong Li , Siyu Lu . Understanding excitonic behavior and electroluminescence light emitting diode application of carbon dots. Chinese Chemical Letters, 2025, 36(2): 110426-. doi: 10.1016/j.cclet.2024.110426
14. [14]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
15. [15]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
16. [16]
  Xiaodan Wang , Yingnan Liu , Zhibin Liu , Zhongjian Li , Tao Zhang , Yi Cheng , Lecheng Lei , Bin Yang , Yang Hou . Highly efficient electrosynthesis of H₂O₂ in acidic electrolyte on metal-free heteroatoms co-doped carbon nanosheets and simultaneously promoting Fenton process. Chinese Chemical Letters, 2024, 35(7): 108926-. doi: 10.1016/j.cclet.2023.108926
17. [17]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
18. [18]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
19. [19]
  Jiayuan Liang , Xin Mi , Songhao Guo , Hui Luo , Kejun Bu , Tonghuan Fu , Menglin Duan , Yang Wang , Qingyang Hu , Rengen Xiong , Peng Qin , Fuqiang Huang , Xujie Lü . Pressure-induced emission in 0D metal halide (EATMP)SbBr5 by regulating exciton-phonon coupling. Chinese Journal of Structural Chemistry, 2024, 43(7): 100333-100333. doi: 10.1016/j.cjsc.2024.100333
20. [20]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(796)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142