Citation: Ping-Chuan Shen, Ze-Yan Zhuang, Zu-Jin Zhao, Ben Zhong Tang. Recent advances of folded tetraphenylethene derivatives featuring through-space conjugation[J]. Chinese Chemical Letters, ;2016, 27(8): 1115-1123. doi: 10.1016/j.cclet.2016.06.031 shu

Recent advances of folded tetraphenylethene derivatives featuring through-space conjugation

a.
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
b.
Department of Chemistry, The Hong Kong University of Science and Technology, Hong Kong, China
c.
Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong, China

Corresponding author: Zu-Jin Zhao, applications.mszjzhao@scut.edu.cn;tangbenz@ust.hk
Received Date: 11 May 2016
Revised Date: 8 June 2016
Accepted Date: 13 June 2016
Available Online: 29 August 2016

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Through-space conjugated molecules are interesting building blocks for the construction of functional materials that allow multi-dimensional transport of carrier and energy. However, the well explored through-space conjugated molecules are quite limited, which defers their structure-property correlation establishment and wide-scale application. In this review, we introduce a kind of newly-emerging folded tetraphenylethene derivatives featuring through-space conjugation. Their synthesis, crystal and electronic structures, and optical properties are described, and their representative applications as bipolar charge-transporting materials in organic light-emitting diodes and as single-molecule wires in molecular devices are presented, which are anticipated to provide guidance for the further expansion of through-space conjugated systems.
- Folded molecules,
- Aggregation-enhanced emission,
- Through-space conjugation,
- Single-molecule wire,
- Theoretical calculation
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