Citation: Xue-Qing Hou, Yan-Tao Sun, Lei Liu, Shi-Tao Wang, Rui-Li Geng, Xiang-Feng Shao. Bowl-shaped conjugated polycycles[J]. Chinese Chemical Letters, ;2016, 27(8): 1166-1174. doi: 10.1016/j.cclet.2016.06.028 shu

Bowl-shaped conjugated polycycles

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Corresponding author: Xiang-Feng Shao,
Received Date: 3 May 2016
Revised Date: 6 June 2016
Accepted Date: 29 June 2016
Available Online: 27 August 2016

Figures(17)

The conjugated polycycles show excellent optical and electrical properties that are suitable for application in various organic electronics. While most of attentions have been paid to polycycles having planar π-conjugated system, the curved polycycles seem amazing due to their unique physical and chemical features. The non-planar conjugated polycycles have been created with the geometries of bracelet, saddle, bowl, Möbius band, helicenes, etc. Among them, the bowl-shaped one is of growing interest owing to the multidiscipline applications such as synthetic intermediates for end-cap of carbon nanotube, coordination with metal ions, encapsulation of fullerenes, and fabrication of electronic devices. In this paper, we summarize the recent advances on the chemistry of the bowl-shaped conjugated polycycles, particularly on their synthesis and the further chemical modifications toward organic functional materials.
- Conjugated polycycle,
- Curved π-system,
- Bucky bowl,
- Heteroatom doping,
- Electronic structure
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沈阳化工大学材料科学与工程学院沈阳 110142