Citation: Zuo-Bang Sun, Sheng-Yong Li, Zhi-Qiang Liu, Cui-Hua Zhao. Triarylborane π-electron systems with intramolecular charge-transfer transitions[J]. Chinese Chemical Letters, ;2016, 27(8): 1131-1138. doi: 10.1016/j.cclet.2016.06.007 shu

Triarylborane π-electron systems with intramolecular charge-transfer transitions

a.
School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials Ministry of Education, Shandong University, Jinan 250100, China
b.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Corresponding author: Cui-Hua Zhao, chemistry.chzhao@sdu.edu.cn
Received Date: 28 April 2016
Revised Date: 18 May 2016
Accepted Date: 25 May 2016
Available Online: 8 August 2016

Figures(13)

The incorporation of B element into p-conjugated system is an efficient strategy to tune the steric and electronic structure and thus optoelectronic properties of π-electron systems. The vacant p orbital on the tricoordinate B center makes it exhibit several electronic and steric features, such as electron-accepting ability through p-π^* conjugation, the high Lewis acidity to coordinate with Lewis bases, as well as the steric bulk arising from the aryl substituent on the B center to get enough kinetic stability. As a result, the boryl group is a very unique electron acceptor. When an electron-donating amino group is present, the triarylboranes would display intense intramolecular charge transfer transitions, which lead to interesting optoelectronic properties and great utilities. This short review summarizes the recent progress in π-electron systems, which contain both B and N elements and thus display intramolecular charge-transfer transitions. The triarylboranes are introduced based on their structural features, including the linear π-system with boryl and amino groups at the terminal positions, the lateral borylsubstituted π-system with amino groups at the terminal positions, the biphenyl π-system with an amino and a boryl groups at o,o'-positions, nonconjugated U- and V-shaped π-system, macrocylcic π-system with B and N embedded in the ring, B,N-bridged ladder-type π-system, as well as the polycyclic π-system with B embedded in the center.
- Triarylborane,
- Electron-acceptor,
- Electron-donor,
- Charge-transfer
1. [1]
  (a) P.J. Grisdale, J.L.R. Williams, M.E. Glogowski, B.E. Babb, Boron photochemistry. Possible role of bridged intermediates in the photolysis of borate complexes, J. Org. Chem. 36(1971) 544-549; (b) J.C. Doty, B. Babb, P.J. Grisdale, M. Glogowski, J.L.R. Williams, Boron photochemistry: IX. Synthesis and fluorescent properties of dimesityl-phenylboranes, J. Organomet. Chem. 38(1972) 229-236.
2. [2]
  (a) W. Kaim, A. Schulz, p-Phenylenediboranes: mirror images of p-phenylenediamines, Angew. Chem. Int. Ed. 23(1984) 615-616; (b) J. Fiedler, S. Zališ, A. Klein, F.M. Hornung, W. Kaim, Electronic structure of π-conjugated redox systems with borane/borataalkene end groups, Inorg. Chem. 35(1996) 3039-3043.
3. [3]
  (a) C.D. Entwistle, T.B. Marder, Boron chemistry lights the way: optical properties of molecular and polymeric systems, Angew. Chem. Int. Ed. 41(2002) 2927-2931; (b) C.D. Entwistle, T.B. Marder, Applications of three-coordinate organoboron compounds andpolymers in optoelectronics, Chem. Mater. 16(2004) 4574-4585; (c) F. Jäkle, Lewis acidic organoboron polymers, Coord. Chem. Rev. 250(2006) 1107-1121; (d) S. Yamaguchi, A. Wakamiya, Boron as a key component for new π-electron materials, Pure. Appl. Chem. 78(2006) 1413-1424; (e) F. Jäkle, Advances in the synthesis of organoborane polymers for optical, electronic, and sensory applications, Chem. Rev. 110(2010) 3985-4022; (f) C.R. Wade, A.E.J. Broomsgrove, S. Aldridge, F.P. Gabbaï, Fluoride ion complexation and sensing using organoboron compounds, Chem. Rev. 110(2010) 3958-3984; (g) Z.M. Hudson, S.N. Wang, Metal-containing triarylboron compounds for optoelectronic applications, Dalton Trans. 40(2011) 7805-7816; (h) C.H. Zhao, Y.H. Zhao, J.M. Lin, Optoelectronic materials of organoboron π-conjugated systems, Prog. Chem. 21(2009) 2605-2612.
4. [4]
  (a) Z.Yuan,J.C. Collings, N.J.Taylor, et al., Linearandnonlinear optical properties of three-coordinate organoboron compounds, J. Solid State Chem. 154(2000) 5-12; (b) Z. Yuan, C.D. Entwistle, J.C. Collings, et al., Synthesis, crystal structures, linear and nonlinear optical properties, and theoretical studies of (p-R-phenyl)-,(p-Rphenylethynyl)-, and (E)-[2-(p-R-Phenyl) ethenyl] dimesitylboranes and related compounds, Chem. Eur. J. 12(2006) 2758-2771; (c) Z. Yuan, N.J. Taylor, T.B. Marder, et al., Three coordinate phosphorus and boron as π-donor and p-acceptor moieties respectively, in conjugated organic molecules fornonlinearoptics:crystalandmolecular structures ofE-Ph-CH=CH-B(mes)₂, E-4-MeO-C₆H₄-CH=CH-B(mes)₂, and E-Ph₂P-CH=CH-B(mes)₂[mes=2,4,6-Me₃C₆H₂], J. Chem. Soc. Chem. Commun. (1990) 1489-1492; (d) Z. Yuan, N.J. Taylor, R. Ramachandran, T.B. Marder, Third-order nonlinear optical properties of organoboron compounds: molecular structures and second hyperpolarizabilities, Appl. Organomet. Chem. 10(1996) 305-316; (e) Z. Yuan, N.J. Taylor, Y. Sun, et al., Synthesis and second-order nonlinear optical properties of three-coordinate organoboranes with diphenylphosphino and ferrocenyl groups as electron donors: crystal and molecular structures of (E)-D-CH=CHB(mes)₂ and D-C=C-B(mes)₂(D=P(C₆H₅₂, (η-C₅H₅) Fe(η-C₅H₄); mes=2, 4, 6-(CH₃)₃C₆H₂], J. Organomet. Chem. 449(1993) 27-37.
5. [5]
  (a) M. Lequan, R.M. Lequan, K.C. Ching. Trivalent boron as acceptor chromophore in asymmetrically substituted 4,40-biphenyl and azobenzene for non-linear optics, J. Mater. Chem., 1991,1: 997-999; (b) C. Branger, M. Lequan, R.M. Lequan, M. Barzoukas, A. Fort, Boron derivatives containing a bithiophene bridge as new materials for non-linear optics, J. Mater. Chem., 1996,6: 555-558; (c) C. Branger, M. Lequan, R.M. Lequan, M. Large, F. Kajzar, Polyurethanes containing boron chromophores as sidechains for nonlinear optics[J]. Chem. Phys. Lett., 1997,272:265-270. doi: 10.1016/S0009-2614(97)88019-0
6. [6]
  (a) D.X. Cao, Z.Q. Liu, Q. Fang, et al., Blue two-photon excited fluorescence of several D-π-D, A-π-A, and D-π-A compounds featuring dimesitylboryl acceptor, J. Organomet. Chem. 689(2004) 2201-2206; (b) Z.Q. Liu, Q. Fang, D. Wang, et al., Trivalent boron as acceptor in D-π-A chromophores: synthesis, structure and fluorescence following single-and twophoton excitation, Chem. Commun. (2002) 2900-2901.
7. [7]
  J.C. Collings, S.Y. Poon, C. Le Droumaguet. The Synthesis and one-and two-Photon optical properties of dipolar, quadrupolar and octupolar donor-acceptor molecules containing dimesitylboryl groups[J]. Chem. Eur. J., 2009,15:198-208. doi: 10.1002/chem.v15:1
8. [8]
  (a) W.L. Jia, X.D. Feng, D.R. Bai, et al., Mes₂B (p-4, 4'-biphenyl-NPh(1-naphthyl)): a multifunctional molecule for electroluminescent devices, Chem. Mater. 17(2005) 164-170; (b) W.L. Jia, M.J. Moran, Y.Y. Yuan, Z.H. Lu, S.N. Wang, (1-Naphthyl) phenylamino functionalized three-coordinate organoboron compounds: syntheses, structures, and applications in OLEDs, J. Mater. Chem. 15(2005) 3326-3333; (c) W.L. Jia, D.R. Bai, T. McCormick, et al., Three-coordinate organoboron compounds BAr2R (Ar=Mesityl, R=7-Azaindolyl-or 2, 2'-Dipyridylamino-functionalized aryl or thienyl) for electroluminescent devices and supramolecular assembly, Chem. Eur. J. 10(2004) 994-1006; (d) W.L. Jia, D.T. Song, S.N. Wang, Blue luminescent three-coordinate organoboron compounds with a 2, 2'-dipyridylamino functional group, J. Org. Chem. 68(2003) 701-705; (e) F.H. Li, W.L. Jia, S.N. Wang, Y.Q. Zhao, Z.H. Lu, Blue organic light-emitting diodes based on Mes2B[p-4, 4'-biphenyl-NPh (1-naphthyl)], J. Appl. Phys. 103(2008) 034509.
9. [9]
  S.L. Lin, L.H. Chan, R.H. Lee. Highly efficient carbazole-π-dimesitylborane bipolar fluorophores for nondoped blue organic light-emitting diodes[J]. Adv. Mater., 2008,20:3947-3952. doi: 10.1002/adma.v20:20
10. [10]
  Y. Shirota, M. Kinoshita, T. Noda, K. Okumoto, T. Ohara. A novel class of emitting amorphous molecular materials as bipolar radical formants: 2-{4-[Bis(4-methylphenyl)amino]phenyl}-5-(dimesitylboryl)thiophene and 2-{4-[Bis(9,9-dimethylfluorenyl)amino]phenyl}-5-(dimesitylboryl)thiophene[J]. J. Am. Chem. Soc., 2000,122:11021-11022. doi: 10.1021/ja0023332
11. [11]
  K. Suzuki, S. Kubo, K. Shizu. Triarylboron-based fluorescent organic lightemitting diodes with external quantum efficiencies exceeding 20%[J]. Angew. Chem. Int. Ed., 2015,54:15231-15235. doi: 10.1002/anie.201508270
12. [12]
  (a) S. Yamaguchi, T. Shirasaka, S. Akiyama, K. Tamao, Dibenzoborole-containing, π-Electron systems: remarkable fluorescence change based on the "on/off" control of the p_π-π^* conjugation, J. Am. Chem. Soc. 124(2002) 8816-8817; (b) Y. Kubo, M. Yamamoto, M. Ikeda, et al., A colorimetric and ratiometric fluorescent chemosensor with three emission changes: fluoride ion sensing by a triarylborane-porphyrin conjugate, Angew. Chem. Int. Ed. 42(2003) 2036-2040.
13. [13]
  (a) S. Sole, F.P. Gabbai, A bidentate borane as colorimetric fluoride ion sensor, Chem. Commun. 35(2004) 1284-1285; (b) M. Melaimi, F.P. Gabbaï, A heteronuclear bidentate lewis acid as a phosphorescent fluoride sensor, J. Am. Chem. Soc. 127(2005) 9680-9681; (c) C.W. Chiu, F.P. Gabbaï, Fluoride ion capture from water with a cationic borane, J. Am. Chem. Soc. 128(2006) 14248-14249; (d) M.H. Lee, T. Agou, J. Kobayashi, T. Kawashima, F.P. Gabbaï, Fluoride ion complexation by a cationic borane in aqueous solution, Chem. Commun. (2007) 1133-1135.
14. [14]
  (a) A. Sundararaman, M. Victor, R. Varughese, F. Jäkle, A family of main-chain polymeric Lewis acids: synthesis and fluorescent sensing properties of boronmodified polythiophenes, J. Am. Chem. Soc. 127(2005) 13748-13749; (b) K. Parab, K. Venkatasubbaiah, F. Jäkle, Luminescent triarylborane-functionalized polystyrene: synthesis, photophysical characterization, and anion-binding studies, J. Am. Chem. Soc. 128(2006) 12879-12885; (c) H.Y. Li, A. Sundararaman, K. Venkatasubbaiah, F. Jäkle, Organoborane acceptor-substituted polythiophene via side-group borylation, J. Am. Chem. Soc. 129(2007) 5792-5793.
15. [15]
  (a) G.L. Fu, H. Pan, Y.H. Zhao, C.H. Zhao, Solid-state emissive triarylborane-based BODIPY dyes: photophysical properties and fluorescent sensing for fluoride and cyanide ions, Org. Biomol. Chem. 9(2011) 8141-8146; (b) Y.H. Zhao, H. Pan, G.L. Fu, J.M. Lin, C.H. Zhao, A highly emissive cruciform triarylborane as a ratiometric and solid state fluorescence sensor for fluoride ions, Tetrahedron Lett. 52(2011) 3832-3835.
16. [16]
  (a) Z.L. Zhang, R.M. Edkins, J. Nitsch, et al., Optical and electronic properties of airstable organoboron compounds with strongly electron-accepting bis (fluoromesityl) boryl groups, Chem. Sci. 6(2015) 308-321; (b) Z.L. Zhang, R.M. Edkins, J. Nitsch, et al., D-π-A triarylboron compounds with tunable push-pull character achieved by modification of both the donor and acceptor moieties, Chem. Eur. J. 21(2015) 177-190.
17. [17]
  (a) C.H. Zhao, A. Wakamiya, Y. Inukai, S. Yamaguchi, Highly emissive organic solids containing 2, 5-diboryl-1,4-phenylene unit, J. Am. Chem. Soc. 128(2006) 15934-15935; (b) C.H. Zhao, A. Wakamiya, S. Yamaguchi, Highly emissive poly(aryleneethynylene)s containing 2, 5-diboryl-1, 4-phenylene as a building unit, Macromolecules 40(2007) 3898-3900; (c) C.H. Zhao, E. Sakuda, A. Wakamiya, S. Yamaguchi, Highly emissive diborylphenylene-containing bis (phenylethynyl) benzenes: structure-photophysical property correlations and fluoride ion sensing, Chem. Eur. J. 15(2009) 10603- 10612; (d) A. Wakamiya, K. Mori, S. Yamaguchi, 3-Boryl-2, 2'-bithiophene as a versatile core skeleton for full-color highly emissive organic solids, Angew. Chem. Int. Ed. 46(2007) 4273-4276.
18. [18]
  G.L.Fu , H.Y. Zhang, Y.Q. Yan, C.H. Zhao. p-Quaterphenyls laterally substituted with a dimesitylboryl group: a promising class of solid-state blue emitters[J]. J. Org. Chem., 2012,77:1983-1990. doi: 10.1021/jo202574n
19. [19]
  (a) H. Pan, G.L. Fu, Y.H. Zhao, C.H. Zhao, Through-space charge-transfer emitting biphenyls containing a boryl and an amino group at the o,o'-positions, Org. Lett. 13(2011) 4830-4833; (b) C. Wang, Q.W. Xu, W.N. Zhang, Q. Peng, C.H. Zhao, Charge-transfer emission in organoboron-based biphenyls: effect of substitution position and conformation, J. Org. Chem. 80(2015) 10914-10924; (c) Y.Q. Yan, Y.B. Li, J.W. Wang, C.H. Zhao, Effect of the substitution pattern on the intramolecular charge-transfer emissions in organoboron-based biphenyls, diphenylacetylenes, and stilbenes, Chem. Asian. J. 8(2013) 3164-3176; (d) C. Wang, J. Jia, W.N. Zhang, H.Y. Zhang, C.H. Zhao, Triarylboranes with a 2-dimesitylboryl-2'-(N,N-dimethylamino) biphenyl core unit: structure-property correlations and sensing abilities to discriminate between F^- and CN^- ions, Chem. Eur. J. 20(2014) 16590-16601; (e) Q.W. Xu, C. Wang, Z.B. Sun, C.H. Zhao, A highly selective ratiometric bifunctional fluorescence probe for Hg²⁺ and F^- ions, Org. Biomol. Chem. 13(2015) 3032-3039.
20. [20]
  (a) X.Y. Liu, D.R. Bai, S.N. Wang, Charge-transfer emission in nonplanar threecoordinate organoboron compounds for fluorescent sensing of fluoride, Angew. Chem. Int. Ed. 45(2006) 5475-5478; (b) Z.M. Hudson, X.Y. Liu, S.N. Wang, Switchable three-state fluorescence of a nonconjugated donor-acceptor triarylborane, Org. Lett. 13(2011) 300-303; (c) D.R. Bai, X.Y. Liu, S. Wang, Charge-transfer emission involving three-coordinate organoboron: V-shape versus U-shape and impact of the spacer on dual emission and fluorescent sensing, Chem. Eur. J. 13(2007) 5713-5723.
21. [21]
  (a) P.K. Chen, F. Jäkle, Highly luminescent, electron-deficient bora-cyclophanes, J. Am. Chem. Soc. 133(2011) 20142-20145; (b) P.K. Chen, R.A. Lalancette, F. Jäkle, p-Expanded borazine: an ambipolar conjugated B-π-N macrocycle, Angew. Chem. Int. Ed. 51(2012) 7994-7998; (c) P.K. Chen, X.D. Yin, N. Baser-Kirazli, F. Jäkle, Versatile design principles for facile access to unstrained conjugated organoborane macrocycles, Angew. Chem. Int. Ed. 54(2015) 10768-10772.
22. [22]
  (a) D.M. Chen, Q. Qin, Z.B. Sun, Q. Peng, C.H. Zhao, Synthesis and properties of B,Nbridged p-terphenyls, Chem. Commun. 50(2014) 782-784; (b) D.M. Chen, S. Wang, H.X. Li, X.Z. Zhu, C.H. Zhao, Solid-state emissive B,Sbridged p-terphenyls: synthesis, properties, and utility as bifunctional fluorescent sensor for Hg²⁺ and F^- ions, Inorg. Chem 53(2014) 12532-12539.
23. [23]
  (a) Z.G. Zhou, A. Wakamiya, T. Kushida, S. Yamaguchi, Planarized triarylboranes: stabilization by structural constraint and their plane-to-bowl conversion, J. Am. Chem. Soc. 134(2012) 4529-4532; (b) C.D. Dou, S. Saito, K. Matsuo, I. Hisaki, S. Yamaguchi, A boron-containing PAH as a substructure of boron-doped graphene, Angew. Chem. Int. Ed. 51(2012) 12206-12210; (c) S. Saito, K. Matsuo, S. Yamaguchi, Polycyclic, π-Electron system with boron at its center, J. Am. Chem. Soc. 134(2012) 9130-9133.
24. [24]
  T. Hatakeyama, K. Shiren, K. Nakajima. Ultrapure blue thermally activated delayed fluorescence molecules: efficient HOMO-LUMO separation by the multiple resonance effect[J]. Adv. Mater., 2016,28:2777-2781. doi: 10.1002/adma.v28.14
25. [25]
  (a) Y.N. Hong, J.W.Y. Lam, B.Z. Tang, Aggregation-induced emission, Chem. Soc. Rev. 40(2011) 5361-5388; (b) M. Shimizu, T. Hiyama, Organic fluorophores exhibiting highly efficient photoluminescence in the solid state, Chem. Asian. J. 5(2010) 1516-1531; (c) S.P.Anthony,Organicsolid-statefluorescence:strategiesforgeneratingswitchable and tunable fluorescent materials, ChemPlusChem 77(2012) 518-531.
26. [26]
  (a) B. Gong, Hollow Crescents, Helices, and Macrocycles from enforced folding and folding-assisted macrocyclization, Acc. Chem. Res. 41(2008) 1376-1386; (b) D. Ramaiah, P.P. Neelakandan, A.K. Nair, R.R. Avirah, Functional cyclophanes: promising hosts for optical biomolecular recognition, Chem. Soc. Rev. 39(2010) 4158-4168.
27. [27]
  A. Fukazawa, S. Yamaguchi. Ladder π-conjugated materials containing maingroup elements[J]. Chem. Asian. J., 2009,4:1386-1400. doi: 10.1002/asia.v4:9
28. [28]
  (a) H. Uoyama, K. Goushi, K. Shizu, H. Nomura, C. Adachi, Highly efficient organic light-emitting diodes from delayed fluorescence, Nature 492(2012) 234-238; (b) Y. Tao, K. Yuan, T. Chen, et al., Thermally activated delayed fluorescence materials towards the breakthrough of organoelectronics, Adv. Mater. 26(2014) 7931-7958.
1. [1]
  Rong-Nan Yi , Wei-Min He . Electron donor-acceptor complex enabled arylation of dithiocarbamate anions with thianthrenium salts under aqueous micellar conditions. Chinese Chemical Letters, 2024, 35(11): 110194-. doi: 10.1016/j.cclet.2024.110194
2. [2]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2023.100463
3. [3]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
4. [4]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
5. [5]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
6. [6]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
7. [7]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
8. [8]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
9. [9]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
10. [10]
  Qinghong Zhang , Qiao Zhao , Xiaodi Wu , Li Wang , Kairui Shen , Yuchen Hua , Cheng Gao , Yu Zhang , Mei Peng , Kai Zhao . Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones via β-C-C scission enabled by proton-coupled electron transfer. Chinese Chemical Letters, 2025, 36(2): 110167-. doi: 10.1016/j.cclet.2024.110167
11. [11]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
12. [12]
  Jiale Zheng , Mei Chen , Huadong Yuan , Jianmin Luo , Yao Wang , Jianwei Nai , Xinyong Tao , Yujing Liu . Electron-microscopical visualization on the interfacial and crystallographic structures of lithium metal anode. Chinese Chemical Letters, 2024, 35(6): 108812-. doi: 10.1016/j.cclet.2023.108812
13. [13]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
14. [14]
  Chao Ma , Peng Guo , Zhongmin Liu . DNL-16: A new zeolitic layered silicate unraveled by three-dimensional electron diffraction. Chinese Journal of Structural Chemistry, 2024, 43(4): 100235-100235. doi: 10.1016/j.cjsc.2024.100235
15. [15]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
16. [16]
  Wenxiang Ma , Xinyu He , Tianyi Chen , De-Li Ma , Hongzheng Chen , Chang-Zhi Li . Near-infrared non-fused electron acceptors for efficient organic photovoltaics. Chinese Chemical Letters, 2024, 35(4): 109099-. doi: 10.1016/j.cclet.2023.109099
17. [17]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
18. [18]
  Shaonan Liu , Shuixing Dai , Minghua Huang . The impact of ester groups on 1,8-naphthalimide electron transport material in organic solar cells. Chinese Journal of Structural Chemistry, 2024, 43(6): 100277-100277. doi: 10.1016/j.cjsc.2023.100277
19. [19]
  Ruru Li , Qian Liu , Hui Li , Fengbin Sun , Zhurui Shen . Rational design of dual sites induced local electron rearrangement for enhanced photocatalytic oxygen activation. Chinese Chemical Letters, 2024, 35(11): 109679-. doi: 10.1016/j.cclet.2024.109679
20. [20]
  Ming-Zhen Li , Yang Zhang , Kun Li , Ya-Nan Shang , Yi-Zhen Zhang , Yu-Jiao Kan , Zhi-Yang Jiao , Yu-Yuan Han , Xiao-Qiang Cao . In situ regeneration of catalyst for Fenton-like degradation by photogenerated electron transportation: Characterization, performance and mechanism comparison. Chinese Chemical Letters, 2025, 36(1): 109885-. doi: 10.1016/j.cclet.2024.109885

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(749)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142