Citation: Zhao Shu-Yang, Wang Sheng-Ping, Zhao Yu-Jun, Ma Xin-Bin. An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂[J]. Chinese Chemical Letters, ;2017, 28(1): 65-69. doi: 10.1016/j.cclet.2016.06.003 shu

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂

Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University; Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Corresponding author: Wang Sheng-Ping, spwang@tju.edu.cn
Received Date: 27 April 2016
Revised Date: 14 May 2016
Accepted Date: 23 May 2016
Available Online: 8 January 2016

Figures(5)

The mechanism of dimethyl carbonate (DMC) formation from CO₂ and methanol is investigated using three well-shaped CeO₂ catalysts, nanorod, nanocube and octahedron, which are packed with different crystal planes. In situ Fourier Transform Infrared Spectroscopy (FTIR) is employed to probe each reaction step in the DMC synthesis. The number of -OH groups and the species of CO₂ adsorptions on ceria surface have significant influence on the activity of ceria with different morphologies. Rod-ceria has favorable catalytic activity because of the large amount of -OH groups and the formation of bidentate carbonate species.
- Dimethyl carbonate,
- CeO₂,
- -OH,
- Bidentate carbonate,
- Crystal planes
1. [1]
  Huang M., Fabris S.. CO adsorption and oxidation on ceria surfaces from DFT+U calculations[J]. J. Phys. Chem. C, 2008,112:8643-8648. doi: 10.1021/jp709898r
2. [2]
  Aouissi A., Al-Deyab S.S.. Comparative study between gas phase and liquid phase for the production of DMC from methanol and CO₂[J]. J. Nat. Gas Chem., 2012,21:189-193. doi: 10.1016/S1003-9953(11)60353-8
3. [3]
  Vivier L., Duprez D.. Ceria-based solid catalysts for organic chemistry[J]. Chem. Sus. Chem., 2010,3:654-678. doi: 10.1002/cssc.v3:6
4. [4]
  Tomishige K., Sakaihori T., Ikeda Y., Fujimoto K.. A Novel method of direct synthesis of dimethyl carbonate from methanol and carbon dioxide catalyzed by zirconia[J]. Catal. Lett., 1999,58:225-229. doi: 10.1023/A:1019098405444
5. [5]
  Agarwal S., Lefferts L., Mojet B.L.. Exposed surfaces on shape-controlled ceria nanoparticles revealed through AC-TEM and water-gas shift reactivity[J]. Chem. Sus. Chem., 2013,6:1898-1906. doi: 10.1002/cssc.v6.10
6. [6]
  Qiao Z.A., Wu Z.L., Dai S.. Shape-controlled ceria-based nanostructures for catalysis applications[J]. Chem. Sus. Chem., 2013,6:1821-1833. doi: 10.1002/cssc.v6.10
7. [7]
  Mullins D.R.. The surface chemistry of cerium oxide[J]. Surf. Sci. Rep., 2015,70:42-85. doi: 10.1016/j.surfrep.2014.12.001
8. [8]
  Guan Y.J., Hensen E.J.M., Liu Y.. Template-free synthesis of sphere, rod and prism morphologies of CeO₂ oxidation catalysts[J]. Catal. Lett., 2010,137:28-34. doi: 10.1007/s10562-010-0349-5
9. [9]
  Mai H.X., Sun L.D., Zhang Y.W.. Shape-selective synthesis and oxygen storage behavior of ceria nanopolyhedra, nanorods, and nanocubes[J]. J. Phys. Chem. B, 2005,109:24380-24385. doi: 10.1021/jp055584b
10. [10]
  Zhou K.B., Wang X., Sun X.M., Peng Q., Li Y.D.. Enhanced catalytic activity of ceria nanorods from well-defined reactive crystal planes[J]. J. Catal., 2005,229:206-212. doi: 10.1016/j.jcat.2004.11.004
11. [11]
  Liu X.W., Zhou K.B., Wang L., Wang B.Y., Li Y.D.. Oxygen vacancy clusters promoting reducibility and activity of ceria nanorods[J]. J. Am. Chem. Soc., 2009,131:3140-3141. doi: 10.1021/ja808433d
12. [12]
  Yoshida Y., Arai Y., Kado S., Kunimori K., Tomishige K.. Direct synthesis of organic carbonates from the reaction of CO₂ with methanol and ethanol over CeO₂ catalysts[J]. Catal. Today, 2006,115:95-101. doi: 10.1016/j.cattod.2006.02.027
13. [13]
  Tundo P., Selva M.. The chemistry of dimethyl carbonate[J]. Acc. Chem. Res., 2002,35:706-716. doi: 10.1021/ar010076f
14. [14]
  K.W. La, M.H. Youn, J.S. Chung, S.H. Baeck, I.K. Song, Synthesis of dimethyl carbonate from methanol and carbon dioxide by heteropolyacid/metal oxide catalysts, in:C.K. Rhee (Ed.), Nanocomposites and Nanoporous Materials VⅡ, Trans Tech Publications Ltd, Stafa-Zurich, 2007, pp. 287-290.
15. [15]
  Hofmann H.J., Brandner A., Claus P.. Direct synthesis of dimethyl carbonate by carboxylation of methanol on ceria-based mixed oxides[J]. Chem. Eng. Technol., 2012,35:2140-2146. doi: 10.1002/ceat.v35.12
16. [16]
  Xie S.B., Bell A.T.. An in situ raman study of dimethyl carbonate synthesis from carbon dioxide and methanol over zirconia[J]. Catal. Lett., 2000,70:137-143. doi: 10.1023/A:1018837317910
17. [17]
  Jung K.T., Bell A.T.. An in Situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over zirconia[J]. J. Catal., 2001,204:339-347. doi: 10.1006/jcat.2001.3411
18. [18]
  Aresta M., Dibenedetto A., Pastore C.. Influence of Al₂O₃ on the performance of CeO₂ usd as catalyst in the direct carboxylation of methanol to dimethylcarbonate and the elucidation of the reaction mechanism[J]. J. Catal., 2010,269:44-52. doi: 10.1016/j.jcat.2009.10.014
19. [19]
  Santos B.A.V., Pereira C.S.M., Silva V.M.T.M., Loureiro J.M., Rodrigues A.E.. Kinetic study for the direct synthesis of dimethyl carbonate from methanol and CO₂ over CeO₂ at high Pressure Conditions[J]. Appl. Catal. A:Gen., 2013,455:219-226. doi: 10.1016/j.apcata.2013.02.003
20. [20]
  Wang S.P., Zhou J.J., Zhao S.Y., Zhao Y.J., Ma X.B.. Enhancements of dimethyl carbonate synthesis from methanol and carbon dioxide:the in situ hydrolysis of 2-cyanopyridine and crystal face effect of ceria[J]. Chin. Chem. Lett., 2015,26:1096-1100. doi: 10.1016/j.cclet.2015.05.005
21. [21]
  Wu Z.L., Li M.J., Mullins D.R., Overbury S.H.. Probing the surface sites of CeO₂ nanocrystals with well-defined surface planes via methanol adsorption and desorption[J]. Acs Catal., 2012,2:2224-2234. doi: 10.1021/cs300467p
22. [22]
  Rousseau S., Marie O., Bazin P.. Investigation of methanol oxidation over au/catalysts using operando IR spectroscopy:determination of the active sites, intermediate/spectator species, and reaction mechanism, J[J]. Am. Chem. Soc., 2010,132:10832-10841. doi: 10.1021/ja1028809
23. [23]
  Pozdnyakova O., Teschner D., Wootsch A.. Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part I:oxidation state and surface species on Pt/CeO₂ under reaction conditions[J]. J. Catal., 2006,237:1-16. doi: 10.1016/j.jcat.2005.10.014
24. [24]
  Wu Z.L., Mann A.K.P., Li M.J., Overbury S.H.. Spectroscopic investigation of surfacedependent acid-base property of ceria nanoshapes[J]. J. Phys. Chem. C., 2015,119:7340-7350. doi: 10.1021/acs.jpcc.5b00859
25. [25]
  Binet C., Daturi M., Lavalley J.C.. IR study of polycrystalline ceria properties in oxidised and reduced states[J]. Catal. Today, 1999,50:207-225. doi: 10.1016/S0920-5861(98)00504-5
26. [26]
  Li C., Sakata Y., Arai T.. Carbon monoxide and carbon dioxide adsorption on cerium oxide studied by fourier-transform infrared spectroscopy. Part 1.-formation of carbonate species on dehydroxylated CeO₂, at room temperature[J]. J. Chem. Soc., 1989,85:929-943.
27. [27]
  Vayssilov G.N., Mihaylov M., Petkov P.S., Hadjiivanov K.I., Neyman K.M.. Reassignment of the vibrational spectra of carbonates, formates, and related surface species on ceria:a combined density functional and infrared spectroscopy investigation[J]. J. Phys. Chem. C, 2011,115:23435-23454. doi: 10.1021/jp208050a
28. [28]
  Paier J., Penschke C., Sauer J.. Oxygen defects and surface chemistry of ceria:quantum chemical studies compared to experiment[J]. Chem. Rev., 2013,113:3949-3985. doi: 10.1021/cr3004949
1. [1]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
2. [2]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Zhenjie Yang , Chenyang Hu , Xuan Pang , Xuesi Chen . Sequence design in terpolymerization of ε-caprolactone, CO₂ and cyclohexane oxide: Random ester-carbonate distributions lead to large-span tunability. Chinese Chemical Letters, 2024, 35(5): 109340-. doi: 10.1016/j.cclet.2023.109340
5. [5]
  Xinyu Liu , Jialin Yang , Zonglin He , Jiaoyan Ai , Lina Song , Baohua Liu . Linear polyurethanes with excellent comprehensive properties from poly(ethylene carbonate) diol. Chinese Chemical Letters, 2025, 36(1): 110236-. doi: 10.1016/j.cclet.2024.110236
6. [6]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
7. [7]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
8. [8]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
9. [9]
  Xinyu You , Xin Zhang , Shican Jiang , Yiru Ye , Lin Gu , Hexun Zhou , Pandong Ma , Jamal Ftouni , Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265
10. [10]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
11. [11]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
12. [12]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
13. [13]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
14. [14]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
15. [15]
  Weiping Guo , Ying Zhu , Hong-Hua Cui , Lingyun Li , Yan Yu , Zhong-Zhen Luo , Zhigang Zou . β-Pb₃P₂S₈: A new optical crystal with exceptional birefringence effect. Chinese Chemical Letters, 2025, 36(2): 110256-. doi: 10.1016/j.cclet.2024.110256
16. [16]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
17. [17]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
18. [18]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
19. [19]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
20. [20]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(745)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO2

Metrics

通讯作者: 陈斌, bchen63@163.com

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂