Citation: Li Qi-Feng, Wang Chao, Lan Xiao-Zheng. Solid-solid phase transition of (1-C₁₄H₂₉NH₃)₂ZnCl₄ in nanopores of silica gel for thermal energy storage[J]. Chinese Chemical Letters, ;2017, 28(1): 49-54. doi: 10.1016/j.cclet.2016.05.024 shu

Solid-solid phase transition of (1-C₁₄H₂₉NH₃)₂ZnCl₄ in nanopores of silica gel for thermal energy storage

College of Chemistry and Materials, Shandong Agricultural University, Taian 271018, China

Corresponding author: Lan Xiao-Zheng, lanxzh@sdau.edu.cn
Received Date: 29 March 2016
Revised Date: 19 May 2016
Accepted Date: 23 May 2016
Available Online: 4 January 2016

Figures(6)

Latent heat storage performance of a layered perovskite-type compound, 1-C₁₄H₂₉NH₃)₂ZnCl₄ (C₁₄Zn), embedded in a series of silica gel (SG) with pore sizes of d=15-200 nm is investigated using differential scanning calorimetry (DSC), and powder X-ray diffractions (XRD). C₁₄Zn in the nanopores of silica gel shows size-dependent phase transition temperature, enthalpy change and supercooling. They have a stable transition temperature and heat capacity at each size in a short-term thermal cycling. Similar Xray diffraction patterns are observed for the nano-sized and the bulk C₁₄Zn. The encapsulation of a phase change material in nanopores is a new way of tuning its thermal energy storage properties for a wider range of temperature regulation.
- Phase change materials,
- C₁₄Zn,
- SG,
- Nanopores,
- Composites
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Solid-solid phase transition of (1-C₁₄H₂₉NH₃)₂ZnCl₄ in nanopores of silica gel for thermal energy storage