Citation: Jiang-Yang Shao, Chang-Jiang Yao, Bin-Bin Cui, Zhong-Liang Gong, Yu-Wu Zhong. Electropolymerized films of redox-active ruthenium complexes for multistate near-infrared electrochromism, ion sensing, and information storage[J]. Chinese Chemical Letters, ;2016, 27(8): 1105-1114. doi: 10.1016/j.cclet.2016.05.018 shu

Electropolymerized films of redox-active ruthenium complexes for multistate near-infrared electrochromism, ion sensing, and information storage

a.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Yu-Wu Zhong, date.zhongyuwu@iccas.ac.cn
Received Date: 24 March 2016
Revised Date: 6 May 2016
Accepted Date: 20 May 2016
Available Online: 27 August 2016

Figures(11)

This paper summarizes our recent progress on the preparations and applications of electropolymerized thin films of redox-active ruthenium complexes. Thin films of vinyl-functionalized diruthenium or ruthenium-amine conjugated complexes are prepared by reductive electropolymerization. The resulting films are useful for multistate near-infrared electrochromism, ion sensing, and mimicking flip-flop and flip-flap-flop logic gates. The oxidative electropolymerization of diruthenium complexes with two distal triarylamine units affords electropolymers with an alternating diruthenium and tetraphenylbenzidine structural unit. The applications of the resulting films in multistate near-infrared electrochromism and resistive memory are discussed.
- Electropolymerization,
- Ruthenium complexes,
- Electrochromism,
- Thin films,
- Molecular memory
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沈阳化工大学材料科学与工程学院沈阳 110142