Citation: Jian-Chang Gui, Zhi-Qiang Yan, Yuan Peng, Ji-Gao Yi, Da-Yang Zhou, Dan Su, Zhi-Hui Zhong, Guo-Wei Gao, Wan-Hua Wu, Cheng Yang. Enhanced head-to-head photodimers in the photocyclodimerization of anthracenecarboxylic acid with a cationic pillar[6]arene[J]. Chinese Chemical Letters, ;2016, 27(7): 1017-1021. doi: 10.1016/j.cclet.2016.04.021 shu

Enhanced head-to-head photodimers in the photocyclodimerization of anthracenecarboxylic acid with a cationic pillar[6]arene

Jian-Chang Gui ^a,1 ,
Zhi-Qiang Yan ^a,1 ,
Yuan Peng ^b ,
Ji-Gao Yi ^a ,
Da-Yang Zhou ^c ,
Dan Su ^a ,
Zhi-Hui Zhong ^a ,
Guo-Wei Gao ^a ,
Wan-Hua Wu ^a ,
Cheng Yang ^a,,

a.
Key Laboratory of Green Chemistry & Technology, College of Chemistry, State Key Laboratory of Biotherapy, West China Medical Center and State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610064, China
b.
Chengdu Environmental Monitoring Center, Chengdu 610042, China
c.
Comprehensive Analysis Center, ISIR, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 5670047, Japan

Corresponding author: Cheng Yang, yangchengyc@scu.edu.cn
Received Date: 21 March 2016
Revised Date: 7 April 2016
Accepted Date: 14 April 2016
Available Online: 11 July 2016

Figures(6)

The complexation behaviors of anthracenecarboxylic acid and water-soluble cationic pillararenes have been investigated by ¹H NMR, UV-vis and ITC methods. The cationic pillar[6]arene was found to stepwise form 1:1 and 1:2 complexes, having a large K₁ and a relatively small K₂ values. Photocyclodimerization of AC within the pillar[6]arene improved the yield of the head-to-head photodimers. Up to 4.97 HH/HT ratio has been reached by optimizing the reaction conditions.
- Pillar[6]arene,
- Photocyclodimerization,
- Anthracenecarboxylic acid,
- Supramolecular complexation
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