Citation: Wu Ting, Wang Hai-Ting, Shen Bo, Du Yi-Ping, Wang Xuan, Wang Zhen-Ping, Zhang Chuan-Jing, Miu Wen-Bin. Determination of primary aromatic amines using immobilized nanoparticles based surface-enhanced Raman spectroscopy[J]. Chinese Chemical Letters, ;2016, 27(5): 745-748. doi: 10.1016/j.cclet.2016.01.059 shu

Determination of primary aromatic amines using immobilized nanoparticles based surface-enhanced Raman spectroscopy

a.
Shanghai Key Laboratory of Functional Materials Chemistry, and Research Centre of Analysis and Test, East China University of Science and Technology, Shanghai 200237, China
b.
Technical Center for Industrial Products and Raw Materials Inspection and Testing, Shanghai Entry-Exit Inspection &Inspection and Quarantine Bureau, Shanghai 200135, China

Corresponding author: Wu Ting, wu_ting@ecust.edu.cn
Received Date: 8 May 2015
Revised Date: 18 September 2015
Accepted Date: 11 February 2016
Available Online: 11 May 2016

Figures(2)

Primary aromatic amines (PAAs) are substances with toxicity and suspected human carcinogenicity. A facile method for highly sensitive detection of PAAs using surface-enhanced Raman spectroscopy (SERS) is reported. The immobilization of Au nanoparticles (AuNPs) on the glycidyl methacrylate-ethylene dimethacrylate (GMA-EDMA) materials makes the substrate a closely packed but not aggregated Au NP arrays which provides a prominent SERS enhancement. Four PAAs with different substituent groups, namely, p-toluidine, p-nitroaniline, benzidine and 4,4-methylene-bis-(2-chloroaniline) have been successfully identified and quantified. High sensitivity and good linear relationship between SERS signals and concentrations of PAAs are obtained for all four PAAs.
- Aromatic amines,
- Surface-enhanced Raman spectroscopy,
- (SERS),
- Immobilization,
- Au nanoparticles
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1.
沈阳化工大学材料科学与工程学院沈阳 110142