Citation: Hao Lin, Liu Xing-Li, Wang Jun-Tao, Wang Chun, Wu Qiu-Hua, Wang Zhi. Metal-organic framework derived magnetic nanoporous carbon as an adsorbent for the magnetic solid-phase extraction of chlorophenols from mushroom sample[J]. Chinese Chemical Letters, ;2016, 27(5): 783-788. doi: 10.1016/j.cclet.2016.01.021 shu

Metal-organic framework derived magnetic nanoporous carbon as an adsorbent for the magnetic solid-phase extraction of chlorophenols from mushroom sample

Department of Chemistry, College of Science, Agricultural University of Hebei, Baoding 071001, China

Corresponding author: Wang Zhi, zhiwang2013@aliyun.com
Received Date: 25 July 2015
Revised Date: 27 August 2015
Accepted Date: 5 January 2016
Available Online: 22 May 2016

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In this work, a metal-organic framework derived nanoporous carbon (MOF-5-C) was fabricated and modified with Fe₃O₄ magnetic nanoparticles. The resulting magnetic MOF-5-derived porous carbon (Fe₃O₄@MOF-5-C) was then used for the magnetic solid-phase extraction of chlorophenols (CPs) from mushroom samples prior to high performance liquid chromatography-ultraviolet detection. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and N₂ adsorption were used to characterize the adsorbent. After experimental optimization, the amount of the adsorbent was chosen as 8.0 mg, extraction time as 10 min, sample volume as 50 mL, desorption solvent as 0.4 mL (0.2 mL×2) of alkaline methanol, and sample pH as 6. Under the above optimized conditions, good linearity for the analytes was obtained in the range of 0.8-100.0 ng g^-1 with the correlation coefficients between 0.9923 and 0.9963. The limits of detection (S/N=3) were in the range of 0.25-0.30 ng g^-1, and the relative standard deviations were below 6.8%. The result showed that the Fe₃O₄@MOF-5-C has an excellent adsorption capacity for the analytes.
- Metal-organic frameworks,
- Magnetic nanoporous carbon,
- Magnetic solid-phase extraction,
- Chlorophenols,
- High performance liquid chromatography,
- Mushroom
1. [1]
  Hu Y.L., Huang Z.L., Liao J., Li G.K.. Chemical bonding approach for fabrication of hybrid magnetic metal-organic framework-5:high efficient adsorbents for magnetic enrichment of trace analytes[J]. Anal. Chem., 2013,85:6885-6893.
2. [2]
  Li Q.W., Zhang W.Y., Miljanić O.Š.. Docking in metal-organic frameworks[J]. Science, 2009,325:855-859.
3. [3]
  Zhou H.C., Long J.R., Yaghi O.M.. Introduction to metal-organic frameworks[J]. Chem. Rev., 2012,112:673-674.
4. [4]
  Kaye S.S., Dailly A.D., Yaghi O.M., Long J.R.. Impact of preparation and handling on the hydrogen storage properties of Zn₄O (1,4-benzenedicarboxylate)₃(MOF-5)[J]. J. Am. Chem. Soc., 2007,129:14176-14177.
5. [5]
  Kreno L.E., Leong K., Farha O.K.. Metal-organic framework materials as chemical sensors[J]. Chem. Rev., 2012,112:1105-1125.
6. [6]
  Li J.R., Sculley J., Zhou H.C.. Metal-organic frameworks for separations[J]. Chem. Rev., 2012,112:869-932.
7. [7]
  Liu B., Shioyama H., Jiang H.L., Zhang X.B., Xu Q.. Metal-organic framework (MOF) as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor[J]. Carbon, 2010,48:456-463.
8. [8]
  Jiang H.L., Liu B., Lan Y.Q.. From metal-organic framework to nanoporous carbon:toward a very high surface area and hydrogen uptake[J]. J. Am. Chem. Soc., 2011,133:11854-11857.
9. [9]
  Hao L., Wang C., Wu Q.H.. Metal-organic framework derived magnetic nanoporous carbon:novel adsorbent for magnetic solid-phase extraction[J]. Anal. Chem., 2014,86:12199-12205.
10. [10]
  Chen L., Bai J., Wang C.. One-step solid-state thermolysis of a metal-organic framework:a simple and facile route to large-scale of multiwalled carbon nanotubes[J]. Chem. Commun., 2008,44:1581-1583.
11. [11]
  Hu M., Reboul J., Furukawa S.. Direct carbonization of Al-based porous coordination polymer for synthesis of nanoporous carbon[J]. J. Am. Chem. Soc., 2012,134:2864-2867.
12. [12]
  Chaikittisilp W., Ariga K., Yamauchi Y.. A new family of carbon materials:synthesis of MOF-derived nanoporous carbons and their promising applications[J]. J. Mater. Chem. A, 2013,1:14-19.
13. [13]
  Sun J.K., Xu Q.. Functional materials derived from open framework templates/precursors:synthesis and applications[J]. Energy Environ. Sci., 2014,7:2071-2100.
14. [14]
  Yang S.J., Kim T., Im J.H.. MOF-derived hierarchically porous carbon with exceptional porosity and hydrogen storage capacity[J]. Chem. Mater., 2012,24:464-470.
15. [15]
  Banerjee A., Gokhale R., Bhatnagar S.. MOF derived porous carbon-Fe₃O₄ nanocomposite as a high performance, recyclable environmental superadsorbent[J]. J. Mater. Chem., 2012,22:19694-19699.
16. [16]
  Li R., Yuan Y.P., Qiu L.G., Zhang W., Zhu J.F.. A rational self-sacrificing template route to metal-organic framework nanotubes and reversible vapor-phase detection of nitroaromatic explosives[J]. Small, 2012,8:225-230.
17. [17]
  Li R., Ren X.Q., Feng X.. A highly stable metal- and nitrogen-doped nanocomposite derived from Zn/Ni-ZIF-8 capable of CO₂ capture and separation[J]. Chem. Commun., 2014,50:6894-6897.
18. [18]
  Kim J., McNamara N.D., Her T.H., Hicks J.C.. Carbothermal reduction of Ti-modified IRMOF-3:an adaptable synthetic method to support catalytic nanoparticles on carbon[J]. ACS Appl. Mater. Interfaces, 2013,5:11479-11487.
19. [19]
  Liu J., Wang H., Wu C.. Preparation and characterization of nanoporous carbon-supported platinum as anode electrocatalyst for direct borohydride fuel cell[J]. Int. J. Hydrogen Energy, 2014,39:6729-6736.
20. [20]
  Torad N.L., Hu M., Ishihara S.. Direct synthesis of MOF-derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment[J]. Small, 2014,10:2096-2107.
21. [21]
  Li X.S., Zhu G.T., Luo Y.B., Yuan B.F., Feng Y.Q.. Synthesis and applications of functionalized magnetic materials in sample preparation[J]. TrAC Trends Anal. Chem., 2013,45:233-247.
22. [22]
  Ríos A., Zougagh M., Bouri M.. Magnetic (nano)materials as an useful tool for sample preparation in analytical methods. A review[J]. Anal. Methods, 2013,5:4558-4573.
23. [23]
  Wang C., Ma R.Y., Wu Q.H., Sun M., Wang Z.. Magnetic porous carbon as an adsorbent for the enrichment of chlorophenols from water and peach juice samples[J]. J. Chromatogr. A, 2014,1361:60-66.
24. [24]
  Ghaffari A., Tehrani M.S., Husain S.W., Anbia M., Azar P.A.. Adsorption of chlorophenols from aqueous solution over amino-modified ordered nanoporous silica materials[J]. J. Nanostruct. Chem., 2014,4:114-123.
25. [25]
  Sun M., Cui P.L., Ji S.J.. Octadecyl-modified graphene as an adsorbent for hollow fiber liquid phase microextraction of chlorophenols from honey[J]. Bull. Korean Chem. Soc., 2014,35:1011-1015.
26. [26]
  Petit C., Bandosz T.J.. MOF-graphite oxide composites:combining the uniqueness of graphene layers and metal-organic frameworks[J]. Adv.Mater., 2009,21:4753-4757.
27. [27]
  Wang L., Zang X.H., Wang C., Wang Z.. Graphene oxide as a micro-solid-phase extraction sorbent for the enrichment of parabens from water and vinegar samples[J]. J. Sep. Sci., 2014,37:1656-1662.
28. [28]
  Liu J.F., Liang X., Chi Y.G.. High performance liquid chromatography determination of chlorophenols in water samples after preconcentration by continuous flow liquid membrane extraction on-line coupled with a precolumn[J]. Anal. Chim. Acta, 2003,487:129-135.
29. [29]
  Cai Y.Q., Cai Y.E., Mou S.F., Lu Y.Q.. Multi-walled carbon nanotubes as a solid-phase extraction adsorbent for the determination of chlorophenols in environmental water samples[J]. J. Chromatogr. A, 2005,1081:245-247.
30. [30]
  Wang J.T., Wang W.N., Wu Q.H., Wang C., Wang Z.. Extraction of some chlorophenols from environmental waters using a novel graphene-based magnetic nanocomposite followed by hplc determination[J]. J. Liq. Chromatogr. Relat. Technol., 2014,37:2349-2362.
31. [31]
  Liu Q., Shi J.B., Zeng L.X.. Evaluation of graphene as an advantageous adsorbent for solid-phase extraction with chlorophenols as model analytes[J]. J. Chromatogr. A, 2011,1218:197-204.
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