Citation: Zhou Chuan, Li Yi-He, Jiang Zhen-Hua, Ahn Kwang-Duk, Hu Tian-Jiao, Wang Qing-Hua, Wang Chun-Hua. Poly[(mercaptopropyl) methylsiloxane] (PMMS)-based antibacterial polymer coatings prepared by a two-step sequential thiol-ene click chemistry[J]. Chinese Chemical Letters, ;2016, 27(5): 685-688. doi: 10.1016/j.cclet.2016.01.010 shu

Poly[(mercaptopropyl) methylsiloxane] (PMMS)-based antibacterial polymer coatings prepared by a two-step sequential thiol-ene click chemistry

a.
Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073, China
b.
State Key Laboratory of NBC Protection for Civilian, Beijing 102205, China
c.
Polymer Research Center, Korea Institute of Science and Technology, Seoul 136-791, Republic of Korea

Corresponding author: Li Yi-He, yhli@nudt.edu.cn
Received Date: 7 September 2015
Revised Date: 31 December 2015
Accepted Date: 26 December 2015
Available Online: 14 May 2016

Figures(5)

Poly[(mercaptopropyl)methylsiloxane] (PMMS)-based antibacterial polymer coatings have been prepared through a two-step sequential thiol-ene click chemistry utilizing 1-allyl-3-decylimidazolium bromide (ADIm) as antibacterial monomer and triallyl cyanurate (TAC) as the crosslinker. These films with different content of ADIm were characterized by thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and pencil hardness. It was found that the mechanical and thermal properties of these films were largely influenced by the content of ADIm in the films. Films with imidazolium bromide groups displayed excellent antimicrobial activity against Staphylococcus aureus with 100% killing efficiency.
- Antibacterial polymer,
- Thiol-ene,
- UV-curing,
- Click chemistry,
- Coatings
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