Citation: Niu Yan-Hong, Yang Song, Li Ji-Kun, Xu Yan-Qing, Hu Chang-Wen. Design and synthesis of hybrid solids based on the tetravanadate core toward improved catalytic properties[J]. Chinese Chemical Letters, ;2016, 27(5): 649-654. doi: 10.1016/j.cclet.2016.01.007 shu

Design and synthesis of hybrid solids based on the tetravanadate core toward improved catalytic properties

Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Xu Yan-Qing, xyq@bit.edu.cn Hu Chang-Wen, cwhu@bit.edu.cn
Received Date: 26 October 2015
Revised Date: 14 December 2015
Accepted Date: 30 December 2015
Available Online: 13 May 2016

Figures(4)

Five inorganic-organic hybrid vanadates based on tetravanadate cores, transition metals and N-donor ligands have been designed and synthesized under hydrothermal conditions, namely, [Zn(eIM)₃]₂V₄O₁₂(1),[Zn(pIM)₃]₂V₄O₁₂·H₂O(2),[Zn(ipIM)₃]₂V₄O₁₂(3),[Co(eIM)₃]₂V₄O₁₂·H₂O(4),[Cu(eIM)₂(H₂O)]₂V₄O₁₂(5) (eIM=1-ethylimidazole, pIM=1-propylimidazole, ipIM=isopropylimidazole). All compounds were fully characterized by single-crystal XRD, powder XRD, elemental analysis, TGA, and FT-IR spectroscopy. The hybrid zinc vanadates (1-3) and cobalt vanadate (4) exhibit interesting 2D folded structures and the hybrid copper vanadate (5) presents a 1D chain configuration. All compounds can catalyze olefin epoxidation reactions when using TBHP (TBHP=tert-butyl hydroperoxide) as an oxidant in acetonitrile. The introduction of transition metal ions into tetravanadate cores not only improved the catalytic activity but also fulfilled the heterogeneous catalytic behavior. 1-5 all exhibit extraordinary efficiency in converting olefins to the corresponding epoxides with high conversion and selectivity (particularly, conv. up to 97.1%, sele. up to 100% for 1). Leaching test was also carried out to prove the heterogeneous behavior.
- Hybrid,
- Tetrvanadate core,
- Heterogeneous catalysts,
- Olefin epoxidation
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