Citation: Mei-Hui Yu, Xue Jiang, Song-De Han, Qing-Lun Wang, Xian-He Bu. Stepwise assembly of heterometallic 3d-4f chain exhibiting slow magnetic relaxation[J]. Chinese Chemical Letters, ;2016, 27(03): 317-320. doi: 10.1016/j.cclet.2016.01.001 shu

Stepwise assembly of heterometallic 3d-4f chain exhibiting slow magnetic relaxation

a.
a. School of Materials Science and Engineering, TKL of Metal-and Molecule-Based Material Chemistry and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China;
b.
b. Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Xian-He Bu,
Received Date: 10 July 2015
Available Online: 27 September 2015
Fund Project: This work was supported by the NSF of China (Nos.21031002, 21421001) (Nos.21031002, 21421001)

The self-assembly of polyalcohol ligand 1,1,1-tris(hydroxymethyl)ethane with Dy(NO₃)₃·6H₂O and Cr₃O-Bzo-tBu precursor in the presence of triethylamine step-by-step generated a heterometallic 3d-4f chain. Magnetic investigation of the complex indicates typical slow relaxation of the magnetization at low temperature.
- 3d-4f,
- Chain,
- Stepwise assembly,
- Slow magnetic relaxation
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