Citation: Mei-Hui Yu, Xue Jiang, Song-De Han, Qing-Lun Wang, Xian-He Bu. Stepwise assembly of heterometallic 3d-4f chain exhibiting slow magnetic relaxation[J]. Chinese Chemical Letters, ;2016, 27(03): 317-320. doi: 10.1016/j.cclet.2016.01.001 shu

Stepwise assembly of heterometallic 3d-4f chain exhibiting slow magnetic relaxation

a.
a. School of Materials Science and Engineering, TKL of Metal-and Molecule-Based Material Chemistry and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China;
b.
b. Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Xian-He Bu,
Received Date: 10 July 2015
Available Online: 27 September 2015
Fund Project: This work was supported by the NSF of China (Nos.21031002, 21421001) (Nos.21031002, 21421001)

The self-assembly of polyalcohol ligand 1,1,1-tris(hydroxymethyl)ethane with Dy(NO₃)₃·6H₂O and Cr₃O-Bzo-tBu precursor in the presence of triethylamine step-by-step generated a heterometallic 3d-4f chain. Magnetic investigation of the complex indicates typical slow relaxation of the magnetization at low temperature.
- 3d-4f,
- Chain,
- Stepwise assembly,
- Slow magnetic relaxation
1. [1]
  [1] R.J. Glauber, Time-dependent statistics of the ising model, J. Math. Phys. 4(1963) 294-307.
2. [2]
  [2] A.V. Palii, O.S. Reu, S.M. Ostrovsky, et al., A highly anisotropic cobalt(Ⅱ)-based single-chain magnet:exploration of spin canting in an antiferromagnetic array, J. Am. Chem. Soc. 130(2008) 14729-14738.
3. [3]
  [3] Y.Z. Zheng, W. Xue, M.L. Tong, X.M. Chen, S.L. Zheng, Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2-dicarboxylate analogues, (Ⅰ)norg. Chem. 47(2008) 11202-11211.
4. [4]
  [4] T.F. Liu, D. Fu, S. Gao, et al., An azide-bridged homospin single-chain magnet:[Co(2,20-bithiazoline)(N₃)₂]_n, J. Am. Chem. Soc. 125(2003) 13976-13977.
5. [5]
  [5] E. Coronado, J.R. Galan-Mascarós, C. Martí-Gastaldo, Single chain magnets based on the oxalate ligand, J. Am. Chem. Soc. 130(2008) 14987-14989.
6. [6]
  [6] D. Maspoch, D. Ruiz-Molina, K. Wurst, et al., A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties, Nat. Mater. 2(2003) 190-195.
7. [7]
  [7] J.Z. Lu, D.R. Turner, L.P. Harding, et al., Octapi interactions:self-assembly of a Pdbased[2] catenane driven by eightfold π interactions, J. Am. Chem. Soc. 131(2009) 10372-10373.
8. [8]
  [8] H.L. Sun, Z.M. Wang, S. Gao, Strategies towards single-chain magnets, Coord. Chem. Rev. 254(2010) 1081-1100.
9. [9]
  [9] J.Y. Zhang, K. Wang, X.B. Li, E.Q. Gao, Magnetic coupling and slow relaxation of magnetization in chain-based Mn^Ⅱ, Co^Ⅱ, and Ni^Ⅱ coordination frameworks, (Ⅰ)norg. Chem. 53(2014) 9306-9314.
10. [10]
  [10] Y.Q. Zhang, C.L. Luo, X.B. Wu, B.W. Wang, S. Gao, Magneto-structural correlations in a family of Fe^ⅡRe^(Ⅰ)V(CN)₂ single-chain magnets:density functional theory and Ab initio calculations, (Ⅰ)norg. Chem. 53(2014) 3503-3510.
11. [11]
  [11] E.V. Peresypkina, A.M. Majcher, M. Rams, K.E. Vostrikova, A single chain magnet involving hexacyanoosmate, Chem. Commun. 50(2014) 7150-7153.
12. [12]
  [12] R. Lescouëzec, J. Vaissermann, C. Ruiz-Pé rez, et al., Cyanide-bridged iron(Ⅲ)-cobalt(Ⅱ) double Zigzag ferromagnetic chains:two new molecular magnetic nanowires, Angew. Chem. (Ⅰ)nt. Ed. Engl. 42(2003) 1483-1486.
13. [13]
  [13] X.T. Liu, X.Y. Wang, W.X. Zhang, P. Cui, S. Gao, Weak Ferromagnetism and dynamic magnetic behavior in a single end-to-end azide-bridged nickel(Ⅱ) chain, Adv. Mater. 18(2006) 2852-2856.
14. [14]
  [14] X.J. Li, X.Y. Wang, S. Gao, R. Cao, Two three-dimensional metal-organic frameworks containing one-dimensional hydroxyl/carboxylate mixed bridged metal chains:syntheses, crystal structures, and magnetic properties, (Ⅰ)norg. Chem. 45(2006) 1508-1516.
15. [15]
  [15] J. Tao, H. Maruyama, O. Sato, Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex, J. Am. Chem. Soc. 128(2006) 1790-1791.
16. [16]
  [16] Y.Z. Zheng, M.L. Tong, W.X. Zhang, X.M. Chen, Assembling magnetic nanowires into networks:a layered Co^Ⅱ carboxylate coordination polymer exhibiting singlechain-magnet behavior, Angew. Chem. (Ⅰ)nt. Ed. Engl. 45(2006) 6310-6314.
17. [17]
  [17] C.R. Staples, (Ⅰ).K. Dhawan, M.G. Finnegan, et al., Electronic, magnetic, and redox properties of[MFe₃S₄] clusters (M=Cd, Cu, Cr) in pyrococcus furiosus ferredoxin, (Ⅰ)norg. Chem. 36(1997) 5740-5749.
18. [18]
  [18] K. Katoh, R. Asano, A. Miura, et al., Effect of f-f interactions on quantum tunnelling of the magnetization:mono-and dinuclear Dy(Ⅲ) phthalocyaninato triple-decker single-molecule magnets with the same octacoordination environment, Dalton Trans. 43(2014) 7716-7725.
19. [19]
  [19] Z.L. Wu, J. Dong, W.Y. Ni, et al., pH-induced Dy₄ and Dy₁₀ cluster-based 1D chains with different magnetic relaxation features, Dalton Trans. 43(2014) 16838-16845.
20. [20]
  [20] A.J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K.A. Abboud, G. Christou, Giant single-molecule magnets:a {Mn₈₄} torus and its supramolecular nanotubes, Angew. Chem. (Ⅰ)nt. Ed. Engl. 43(2004) 2117-2121.
21. [21]
  [21] V. Chandrasekhar, P. Bag, M. Speldrich, J. van Leusen, P. Kö gerler, Synthesis, structure, and magnetic properties of a new family of tetra-nuclear {Mn₂^ⅢLn₂}(Ln=Dy, Gd, Tb, Ho) clusters with an arch-type topology:singlemolecule magnetism behavior in the dysprosium and terbium analogues, (Ⅰ)norg. Chem. 52(2013) 5035-5044.
22. [22]
  [22] J.W. Sharples, Y.Z. Zheng, F. Tuna, E.J.L. Mc(Ⅰ)nnesa, D. Collison, Lanthanide discs chill well and relax slowly, Chem. Commun. 47(2011) 7650-7652.
23. [23]
  [23] S.D. Han, X.H. Miao, S.J. Liu, X.H. Bu, Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes, (Ⅰ)norg. Chem. Front. 1(2014) 549-552.
24. [24]
  [24] X.H. Miao, S.D. Han, S.J. Liu, X.H. Bu, Two lanthanide(Ⅲ)-copper(Ⅱ) chains based on[Cu₂Ln₂] clusters exhibiting high stability, magnetocaloric effect and slow magnetic relaxation, Chin. Chem. Lett. 25(2014) 829-834.
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