Citation: Shou-Jun Guo, Jie Bai, Hai-Ou Liang, Chun-Ping Li. The controllable preparation of electrospun carbon fibers supported Pd nanoparticles catalyst and its application in Suzuki and Heck reactions[J]. Chinese Chemical Letters, ;2016, 27(03): 459-463. doi: 10.1016/j.cclet.2015.12.029 shu

The controllable preparation of electrospun carbon fibers supported Pd nanoparticles catalyst and its application in Suzuki and Heck reactions

1.
Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: Jie Bai,
Received Date: 14 September 2015
Available Online: 9 December 2015
Fund Project: The authors gratefully acknowledge the support of the National Natural Science Foundation of China (No.21266016). (No.21266016)

The palladium nanoparticles/carbon nanofibers (Pd NPs/CNFs) catalyst was prepared by the electrospinning method, the hydrazine hydrate solution reduction in an ice bath environment, the high temperature carbonization. The catalyst was characterized by X-ray diffraction (XRD), fieldemission scanning electron microscope (FE-SEM), and transmission electron microscopy (TEM). The nanofibers are not cross-linked and arranged in order. The surface of Pd NPs/CNFs is smooth, and it can be observed that a large number of particleswere loaded and well-dispersed in carbon fiber matrix, and the particle distribution is uniform. The activity center of catalyst is Pd⁽⁰⁾. The Pd NPs/CNFs exhibited a high efficiency, good reusability and stability in the Suzuki and Heck reactions. It can be used for at least five consecutive runs without significant loss of its catalytic activity. The good recyclability of Pd NPs/CNFs provides a way to greatly reduce the cost of the catalyst.
- Pd NPs/CNFs,
- Electrospinning,
- Carbonization,
- Catalysts
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沈阳化工大学材料科学与工程学院沈阳 110142